Silica-coated dual-tube zirconia induction furnace for high-strength optical-fibre production

The dual-wall zirconia induction furnace consists of an inner susceptor tube and an outer insulation tube. The centre piece of the inner tube is coated with a thin silica film. The performance of the newly designed furnace was evaluated in terms of the strength of drawn fibres. The proof test of 47 km length of fibre demonstrated superb strength results, yielding the average survival length at 1·4 GN/m2 (200 klb in?2) to be ~8 km.     

Effects of spin inaccuracy on PMD reduction in spun fibers

Spinning a fiber is the most viable and used technique to reduce polarization mode dispersion (PMD). Many papers have shown that by properly tuning the spin parameters, the differential group delay (DGD) of spun fibers can be greatly reduced. However, the precision with which these optimal profiles are practically implemented may be a problem. In this paper, we perform a statistical analysis of the effects that spin inaccuracy may have on fiber PMD, quantifying how the random uncertainty on spin parameters impairs the DGD. Some preliminary experimental results about spin-induced PMD reduction are also reported.     

STEELEX: A coupled expert system for integrated design of steel structures

Most expert systems developed so far are concerned with symbolic processing of a knowledge base. Solution of complex engineering problems often requires substantial numerical processing in addition to symbolic processing of heuristics and experiential knowledge. In this paper, we present STEELEX, a prototype knowledge-based expert system for integrated design of building structures consisting of moment-resisting steel frames. STEELEX is a coupled system in which AI symbolic processing is combined with conventional numerical processing. STEELEX produces the final detailed design including the beam-column connections ready for fabrication. In addition, it can explain the basis of design and the principles behind the design specification. STEELEX has been developed using a domain-specific tool called SDL (for Structural Design Language). Implemented in the INTERLISP environment, SDL provides a design problem-solving environment using a hierarchical cooperating specialists paradigm. STEELEX has a debugging facility and provides a multiwindow graphics interface for drawing isometric as well as orthographic views of the steel frame and beam-column connections.     

An enzyme immunoanalytical system based on sequential cross-flow chromatography

A new enzyme immunoanalytical concept that can be used for point-of-care testing has been investigated. Enzyme as a tracer requires a separate reaction step for signal generation, which follows the completion of immune complex formation with analyte (e.g., Hepatitis B surface antigen) in a sample. This has been a major factor limiting its utilization within the laboratory. We carried out such sequential processes employing chromatographic analysis, using two crosswise-arranged membrane pads in vertical and horizontal directions. The vertically arranged pads were the same as those in the usual format for pregnancy testing, for instance, with the exception of the use of horseradish peroxidase (HRP) as tracer. By placing the horizontally arranged pads on each lateral side of the signal generation pad in the vertical arrangement, they were employed to supply substrate to the enzyme present in the immune complexes. The substrate flow was initiated after the antigen-antibody bindings to produce a signal, which was typically a color change in proportion to the analyte concentration. Under optimal conditions, the use of HRP labeling increased the detection capability of the assay approximately 30 times compared to that of gold colloids. Potential advantages of using the concept investigated are (1) provision of a rapid and simple immunoassay, (2) satisfaction of a clinical need for highly sensitive determination of analyte, and (3) utilization of relatively inexpensive, portable quantitation means.     

Time-dependent X-ray absorption spectroscopic (XAS) study on the transformation of zinc basic salt into bis(N-oxopyridine-2-thionato) zinc (II)

Solid transchelation reaction was established for the synthesis of bis(N-oxopyridine-2-thionato) zinc (II), commonly known as zinc pyrithione (ZPT), to control particle size using zinc basic salt (ZBS) and aqueous sodium pyrithione solution. Distinguished from ZPT particles prepared by usual precipitation reaction, the obtained ZPT nanoparticles exhibited very narrow size distribution. X-ray absorption spectroscopy (XAS) at Zn K-edge was systematically examined to elucidate time-dependent local structural evolution during solid transchelation reaction. X-ray absorption near edge structure (XANES) analysis clearly revealed that local environment around zinc atoms transformed into pentahedron as reaction proceeded. Based on quantitative X-ray diffraction and XANES analysis, we made structural models. Theoretical XAS spectrum calculated with FEFF code could reproduce experimental one, suggesting that XAS analysis could be very powerful tool to probe phase transformation. Furthermore, according to extended X-ray absorption fine structure (EXAFS) fitting results, Zn-O distance in reaction products gradually increased from 1.96 to 2.07 angstroms, suggesting that zinc atoms bounded with oxygen ones in ZBS were transchelated with pyrithione ligands. This study could be a strong evidence for the usefulness of XAS to study time-dependent structural transformation of nanocrystalline materials.     

Zr K-edge XAS study on ZrO<Subscript>2</Subscript>-pillared aluminosilicate

The ZrO₂-pillared clay with high acidic property has been prepared by reacting 1 wt% colloidal suspension of Na⁺-montmorillonite with 1 N aqueous solution of ZrOCl₂·8H₂O and by subsequent heating. The evolution of local structure around zirconium of the intercalant stabilized in-between aluminosilicate layers upon intercalating, drying, and pillaring condition has been systematically studied by X-ray absorption spectroscopy, and compared to those of reference compounds such as ZrO₂, and ZrOCl₂ · 8H₂O and its 1 N aqueous solution. The intercalated zirconium species was identified as the Zr-tetramer, [Zr₄(OH)₁₄(H₂O)₁₀]²⁺, with an average molecular volume of 10 × 10 Å² and a thickness of 4.5 Å. Also it becomes more condensed upon drying and eventually transforms to a zirconium oxide pillar upon calcination.     

Expanding an existing multiple choice test with a mixed format test: simulation study on sample size and item recovery in concurrent calibration

When a new set of mixed format items is augmented with a previous old multiple-choice (MC) test, those mixed format items should be linked to the existing old MC test. This study used simulation to investigate sample size effect on recovery of known item parameter from the concurrent calibration in the context of horizontal equating, where the new mixed format tests are equated to the existing MC test which acts as the common linking items. In the partial credit model following the Andrich style parameterization, item location and item step parameters were differentially affected by the sample size. Item location parameters were recovered better than item step parameters at the individual item, the sub-test, and the total test level. This study also shows the outward bias for the item location parameter estimated by the maximum likelihood estimator.     

Ultrastructural investigation of intact orbital implant surfaces using atomic force microscopy

This study examined the surface nanostructures of three orbital implants: nonporous poly(methyl methacrylate) (PMMA), porous aluminum oxide and porous polyethylene. The morphological characteristics of the orbital implants surfaces were observed by atomic force microscopy (AFM). The AFM topography, phase shift and deflection images of the intact implant samples were obtained. The surface of the nonporous PMMA implant showed severe scratches and debris. The surface of the aluminum oxide implant showed a porous structure with varying densities and sizes. The PMMA implant showed nodule nanostructures, 215.56 ± 52.34 nm in size, and the aluminum oxide implant showed crystal structures, 730.22 ± 341.02 nm in size. The nonporous PMMA implant showed the lowest roughness compared with other implant biomaterials, followed by the porous aluminum oxide implant. The porous polyethylene implant showed the highest roughness and severe surface irregularities. Overall, the surface roughness of orbital implants might be associated with the rate of complications and cell adhesion. SCANNING 33: 211–221, 2011. © 2011 Wiley Periodicals, Inc.     

Enzyme-linked immuno-strip biosensor to detect Escherichia coli O157:H7

A strip-based biosensor using the enzyme-linked immunosorbent assay technique was fabricated to detect Escherichia coli O157:H7. Two types of antibody specified to E. coli O157:H7 were used to form sandwich-binding complexes. To fabricate an immuno-strip, capture antibody (monoclonal antibody) was immobilized onto signal generation pad and polyclonal antibody conjugated with horseradish peroxidase (HRP) was utilized as detection antibody. Four different functional membranes have been used to fabricate immuno-chromatographic assay strip. A sample application pad was a glass fiber membrane pre-treated with polyvinyl alcohol. A conjugate release pad was fabricated using a glass membrane. A signal generation pad was made on nitrocellulose membrane. Finally, a cellulose membrane was used as an absorption pad. Under optimal conditions of analysis, a color signal in proportion to the E. coli O157:H7 concentration was measured using a detector. The measurement range was 1.8x10(3)-1.8x10(8)CFU/mL.