Wire rod coating process of gas diffusion layers fabrication for proton exchange membrane fuel cells

Gas diffusion layers (GDLs) were fabricated using non-woven carbon paper as a macro-porous layer substrate developed by Hollingsworth & Vose Company. A commercially viable coating process was developed using wire rod for coating micro-porous layer by a single pass. The thickness as well as carbon loading in the micro-porous layer was controlled by selecting appropriate wire thickness of the wire rod. Slurry compositions with solid loading as high as 10 wt.% using nano-chain and nano-fiber type carbons were developed using dispersion agents to provide cohesive and homogenous micro-porous layer without any mud-cracking. The surface morphology, wetting characteristics and pore size distribution of the wire rod coated GDLs were examined using FESEM, Goniometer and Hg porosimetry, respectively. The GDLs were evaluated in single cell PEMFC under various operating conditions (temperature and RH) using hydrogen and air as reactants. It was observed that the wire rod coated micro-porous layer with 10 wt.% nano-fibrous carbon based GDLs showed the highest fuel cell performance at 85 °C using H₂ and air at 50% RH, compared to all other compositions.     

A simple finite-difference frequency-domain (FDFD) algorithm for analysis of switching noise in printed circuit boards and packages

Simultaneous switching noise (SSN) compromises the integrity of the power distribution structure on multilayer printed circuit boards (PCB). Several methods have been used to investigate SSN. These methods ranged from simple lumped circuit models to full-wave (dynamic) three-dimensional Maxwell equations simulators. In this work, we present an efficient and simple finite-difference frequency-domain (FDFD) based algorithm that can simulate, with high accuracy, the capacity of a PCB board to introduce SSN. The FDFD code developed here also allows for simulation of real-world decoupling capacitors that are typically used to mitigate SSN effects at sub 1 GHz frequencies. Furthermore, the algorithm is capable of including lumped circuit elements having user-specified complex impedance. Numerical results are presented for several test boards and packages, with and without decoupling capacitors. Validation of the FDFD code is demonstrated through comparison with other algorithms and laboratory measurements.     

Sub-50 nm P-channel FinFET

High-performance PMOSFETs with sub-50-nm gate-length are reported. A self-aligned double-gate MOSFET structure (FinFET) is used to suppress the short-channel effects. This vertical double-gate SOI MOSFET features: 1) a transistor channel which is formed on the vertical surfaces of an ultrathin Si fin and controlled by gate electrodes formed on both sides of the fin; 2) two gates which are self-aligned to each other and to the source/drain (S/D) regions; 3) raised S/D regions; and 4) a short (50 nm) Si fin to maintain quasi-planar topology for ease of fabrication. The 45-nm gate-length p-channel FinFET showed an I_dsat of 820 μA/μm at V_ds=V_gs=1.2 V and T _ox=2.5 mm. Devices showed good performance down to a gate-length of 18 nm. Excellent short-channel behavior was observed. The fin thickness (corresponding to twice the body thickness) is found to be critical for suppressing the short-channel effects. Simulations indicate that the FinFET structure can work down to 10 nm gate length. Thus, the FinFET is a very promising structure for scaling CMOS beyond 50 nm     

High resolution estimation for sub-gaussian stable signals in a linear array model

The authors describe a high resolution subspace fitting (HRE) algorithm for robust estimation of direction of arrival (DOA) in the uniform linear array model with heavy-tailed signals and noise. Electromagnetic disturbances on telephone lines, atmospheric noise and underwater acoustic noise often exhibit heavy-tailed behaviour with differing characteristics. Although statistical models under Gaussian assumptions of signals and noise have been extensively investigated in the literature, there is limited research on robust methods in the non-Gaussian setting. A general model with sub-Gaussian alpha-stable signals is described, which includes the isotropic alpha-stable, and independent and dependent Gaussian models as special cases. It is shown that the HRE algorithm provides strongly consistent estimates of the DOAs. In addition, Monte Carlo simulation studies show that the proposed algorithm works extremely well for closely spaced targets, and outperforms the multiple signal classification-type algorithms for strongly dependent signals, both in the stable and the Gaussian cases     

A cross-layer design: energy efficient multilevel dynamic feedback scheduling in wireless sensor networks using deadline aware active time quantum for environmental monitoring

Recently, Packet scheduling plays a vital role in Wireless Sensor Networks (WSNs). The major key challenges include delay, packet dropping, energy consumption and lifetime due to constraints in energy and computing resources. All the research works on packet scheduling scheme in WSN uses only First Come First Served (FCFS) and Dynamic Multilevel Priority (DMP) schemes. FCFS works based on packet arrival time, it leads to starvation and high processing overhead for real-time packets. DMP works in multilevel with dynamic priority reduces the transmission overhead and bandwidth; it consumes more resources for real-time task leads to deadlock. To solve these problems, this work presents Multilevel Dynamic Feedback Scheduling (MDFS) algorithm. The sensor node classifies the emergency and normal data into three different ready queues named as high, medium and low priority, respectively. The queues are connected with a feedback mechanism; each packet from the sensor node has its own time quantum value based on the deadline. The updated time quantum value is compared with the boundary value of the queues, depends on the updated value the data packets are moved between queues with help of feedback mechanism. The simulation result proves that the projected MDFS outperforms in WSN environment.     

Maximum likelihood estimation of constellation vectors for blindseparation of co-channel BPSK signals and its performance analysis

In this paper, we present a method for blind separation of co-channel BPSK signals arriving at an antenna array. This method consists of two parts: the maximum likelihood constellation estimation and assignment. We show that at high SNR, the maximum likelihood constellation estimation is well approximated by the smallest distance clustering algorithm, which we proposed earlier on heuristic grounds. We observe that both these methods for estimating the constellation vectors perform very well at high SNR and nearly attain Cramer-Rao bounds. Using this fact and noting that the assignment algorithm causes negligible error at high SNR, we derive upper bounds on the probability of bit error for the above method at high SNR. These upper bounds fall very rapidly with increasing SNR, showing that our constellation estimation-assignment approach is very efficient. Simulation results are given to demonstrate the usefulness of the bounds     

An n-unit standby redundant system with r repair facilities and preventive maintenance

Identifying suitable regeneration points the availability and reliability of an n-unit warm standby system with r repair facilities, in which the operating online unit is subjected to preventive maintenance are obtained. A numerical example is provided to illustrate the results obtained. Based on the numerical result, an optimal PM policy is also derived.     

Synthesis of PEO-based di-block glycopolymers at various pendant spacer lengths of glucose moiety and their in-vitro biocompatibility with MC3T3 osteoblast cells

Di-block copolymers of poly(ethylene oxide) (PEO) and glycopolymers at three different pendant spacer lengths of glucose moiety were synthesized by deacetylation of pendant moieties of 2,3,4,6-tetra-O-acetyl-d-glucopyranosides which were prepared by reversible addition-fragmentation chain-transfer (RAFT) process. The water soluble deacetylated copolymers, PEO-b-poly(acryl-d-glucopyranoside) (PEO-b-PAG, 2a), PEO-b-poly[4′-(acryloxy)butyl-d-glucopyranoside] (PEO-b-PABG, 2b), and PEO-b-poly[6′-(acryloxy)hexyl-d-glucopyranoside] (PEO-b-PAHG, 2c) were characterized in comparison with acetylated copolymers by spectroscopic and gel permeation chromatography methods. In order to assess the biocompatibility of these three di-block copolymers, the adhesion (%), viability (%), and proliferation assays were carried out in MC3T3 cells in-vitro at different concentrations from 10 nM to 1000 μM. Qualitative analysis of cell cytoskeletal organization was obtained by immunostaining with talin and integrin α5. It was clearly indicative of well spreading of cells in the presence of all glycopolymers at lower concentrations but with an increase in the concentration (10 and 100 μM) showed significant change in the cell surface morphologies, despite having good cell adhesion and viability as compared to the control conditions. The use of di-block glycolpolymers at?≤?100 μM of the concentration showed very good osteoblast cells adhesion and viability response; however at higher concentrations (1000 μM) of glycopolymers > 80% of cells lost their viability.     

Studies on photo-crosslinkable polyphosphoramide esters containing divanillylidene cycloalkanone units

Two series of photo-crosslinkable polyphosphoramide esters were synthesized from 2,5-bis(4-hydroxy-3-methoxy benzylidene)cyclopentanone and 2,6-bis(4-hydroxy-3-methoxy benzylidene)cyclohexanone with various N-arylphosphoramide dichlorides by interfacial polycondensation using hexadecyl trimethylammonium bromide as phase transfer catalyst at ambient temperature. The resulting polymers were characterized by inherent viscosity, Fourier transform infra-red, ¹H and ¹³C nuclear magnetic resonance spectroscopy. The thermal stability of the polymers synthesized was evaluated by thermogravimetric analysis. These polymers were studied for their photo-chemical reactions. The divanillylidene cycloakanone groups in the polymer chain function as photo-active centres. Crosslinking proceeds via 2π + 2π cycloaddition reaction of the divanillylidene cycloalkanone moieties. The rate of crosslinking decreases with increase in the size of the cycloalkanone ring, while the thermal stability increases with increase in the size of the cycloalkanone ring.