Influence of surface treatment on properties of Cocos nucifera L. Var typica fiber reinforced polymer composites

Natural fibers are a powerful competitor in the polymer composite market due to their availability, sustainability, obtainability, cost, and biodegradability. The surface of natural fibers was changed to increase mechanical qualities, hydrophobicity, and bonding with polymer matrix. This study exposes the influence of several surface treatments of coconut tree peduncle fibers (CTPFs) on the thermomechanical and water absorption properties of CTPF-reinforced polymer composites. The CTPFs were treated with sodium hydroxide, benzoyl peroxide, potassium permanganate and stearic acid at a constant 40 wt% and individually reinforced in an unsaturated polyester resin matrix containing 60 wt% CTPFs. Chemically treated CTPFs improved reinforcement-matrix adhesion and enhanced composite mechanical characteristics. In addition, the scanning electron microscope fractographical study of stressed composite specimens shows improved reinforcement-matrix bonding. Moreover, the treated CTPFs have a higher cellulose wt%, which improves the composites crystalline nature, hydrophobicity and thermal stability. The potassium permanganate treated CTPF composite's maximum tensile strength of 128 MPa, flexural strength of 119 MPa, impact strength of 9.9 J/cm², hardness value of 99 HRRW and thermal stability up to 193°C make them appropriate for lightweight mobility and structural applications.     

Comparative Evaluation of Hot-Air and Superheated-Steam Impinging Stream Drying as Novel Alternatives for Paddy Drying

An investigation was conducted on impinging stream drying of moist paddy using hot air and superheated steam as the drying media. Drying experiments were divided into two parts: namely, one-pass and two-pass drying. The volumetric water evaporation rate, volumetric heat transfer coefficient, and specific energy consumption of the drying system at various conditions were assessed; in the case of superheated-steam drying, the effect of steam recycle was also assessed. The quality of dried paddy was evaluated in terms of color, head rice yield, and degree of starch gelatinization. In the case of one-pass drying, an increase in the drying temperature led to a significant increase in the volumetric water evaporation rate and volumetric heat transfer coefficient. On the other hand, in the case of two-pass drying, an increase in the drying temperature led to a significant decrease in the volumetric heat transfer coefficient; the volumetric water evaporation rate was not significantly affected, however. The specific energy consumption decreased with an increase in the drying temperature. At the same temperature, using superheated steam as the drying medium led to lower specific energy consumption; higher level of steam recycle also led to more energy conservation. The color of the dried paddy was not affected by the change in the drying temperature; superheated-steam-dried paddy was redder and more yellow than the hot-air-dried paddy. An increase in the drying temperature led to decreased percentage of head rice yield. Superheated-steam drying helped enhance the level of starch gelatinization in comparison with hot-air drying at the same temperature. Nevertheless, drying at the highest tested temperature led to a lower level of starch gelatinization.     

Polystyrene–fluorohectorite nanocomposites prepared by melt mixing with and without latex precompounding: Structure and mechanical properties

Sodium fluorohectorite (FH) was dispersed in polystyrene (PS) by direct melt blending with and without a master batch composed of PS and FH and produced by latex compounding. FH was not intercalated by PS when it was prepared by direct melt compounding. In contrast, FH was well dispersed (mostly intercalated) in PS via the PS‐latex‐mediated predispersion of FH following the master‐batch route. The dispersion of FH was studied with transmission and scanning electron microscopy and X‐ray diffraction techniques and discussed. The nanocomposites produced by the master‐batch technique outperformed the directly melt‐compounded microcomposites with respect to stiffness, strength, and ductility according to dynamic mechanical analysis and static tensile tests. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007     

Structure and properties of poly(ethylene oxide)‐organo clay nanocomposite prepared via melt mixing

Poly(ethylene oxide) (PEO)/organo clay nanocomposites were prepared by melt‐mixing using a laboratory kneader followed by compression molding. The nanocomposites were characterized by X‐ray diffraction, atomic force microscopy, and scanning electron microscopy. Their crystallization behavior in hot stage was investigated by polarized optical microscopy (POM). A decrease in size and regularity were observed as a result of incorporation of clay into the PEO matrix. The dynamic viscoelastic behavior of PEO/organo clay nanocomposites was assessed using a strain‐controlled parallel plate rheometer. The effects of clay concentration and the processing temperature on the rheological properties of the nanocomposites were extensively studied. A significant increase in the viscosity and storage modulus of the nanocomposites was found with the increasing clay content. The flow activation energy decreased with the incorporation of clay. The reinforcing effect of the organoclay was determined in dynamic mechanical analysis and tensile testing. POLYM. ENG. SCI., 2009. © 2008 Society of Plastics Engineers     

Experimental investigation and statistical analysis of additively manufactured onyx-carbon fiber reinforced composites

Availability of additive manufacturing has influenced the scientific community to improve on production and versatility of the components created with several associated technologies. Adding multiple substances through superimposing levels is considered as a part of three-dimensional (3D) printing innovations to produce required products. These technologies are experiencing an increase in development nowadays. It requires frequently adding substance and has capacity to fabricate extremely complex geometrical shapes. However, the fundamental issues with this advancement include alteration of capacity to create special products with usefulness and properties at an economically viable price. In this study, significant procedural parameters: layer designs/ patterns (hexagonal, rectangular and triangular) and infill densities (30%, 40%, and 50%) were considered to investigate into their effects on mechanical behaviors off fused deposition modeling or 3D-printed onyx-carbon fiber reinforced composite specimens, using a high-end 3D printing machine. Mechanical (tensile and impact) properties of the printed specimens were conclusively analyzed. From the results obtained, it was observed that better qualities were achieved with an increased infill density, and rectangular-shaped design exhibited an optimum or maximum tensile strength and energy absorption rate, when compared with other counterparts. The measurable relapse conditions were viably evolved to anticipate the real mechanical qualities with an accuracy of 96.4%. In comparison with other patterns, this was more closely predicted in the rectangular design, using regression models. The modeled linear regression helps to define the association of two dependent variables linked with properties of the dissimilar composite material natures. The models can further predict response of the quantities before and also guide practical applications.     

Comparing phenanthrene degradation by alginate‐encapsulated and free Pseudomonas sp. UG14Lr cells in heavy metal contaminated soils

BACKGROUND: Many polycyclic aromatic hydrocarbon (PAH) contaminated sites also contain high levels of toxic heavy metals. The presence of heavy metals can adversely affect PAH biodegradation. Encapsulation of bacterial cells has been shown to improve survival and activity of cells under various environmental stresses. This study examined if encapsulation of a phenanthrene‐mineralizing bacterial strain could improve its survival and phenanthrene degradation in heavy metal contaminated soils. RESULTS: Alginate encapsulation did not improve survival and phenanthrene degradation by Pseudomonas sp. UG14Lr in heavy metal contaminated soil. Phenanthrene degradation by, and survival of, free cells and alginate‐encapsulated cells were similar in soil contaminated with 5 mg kg^?1 dry soil of As, Cd, or Pb. The number of UG14Lr cells decreased to undetectable level when the concentration of each heavy metal was increased to 100 mg kg^?1 dry soil. UG14Lr, when inoculated as free cells, survived the best and they were detected over 60 days of incubation in soil. Cells in both wet and dry alginate beads survived less well than free cells at the higher metal concentrations. Correspondingly, phenanthrene degradation in soil inoculated with free UG14Lr was better than that in soil inoculated with alginate‐encapsulated cells. CONCLUSION: Alginate encapsulation adversely affected the survival and phenanthrene degradation ability of UG14Lr cells in heavy metal contaminated soil. It is postulated that alginate may have concentrated the metals which in turn increased the toxicity to UG14Lr cells. The results are of interest to those interested in the use of encapsulation technology to formulate microbial cells for bioremediation purposes. Copyright © 2009 Society of Chemical Industry     

Response of reinforced concrete piles including soil–pile interaction effects

This paper discusses the importance of modeling soil–pile interaction in the response of reinforced concrete (RC) piles. A displacement-based, RC beam–column fiber model with distributed lateral deformable supports is presented first. The formulation is general and applies to both monotonic and cyclic loads. The proposed model is simple, computationally efficient and capable of representing the salient features of the soil–pile interaction, including dragging force and gap formation along the pile–soil interfaces as well as hysteretic responses of piles and surrounding soils. Two applications are presented to illustrate the model characteristics, to show the model capabilities, and to discuss the importance of modeling the pile–soil system. The first application deals with a single end-bearing pile embedded in a cohesionless soil. The proposed beam–column model is used to investigate the effects of different model parameters on the pile–soil response, including pile length, pile diameter, and pile and soil nonlinearities. The second application validates the accuracy of the proposed model with the experimental results of a cyclic test on a RC pile/shaft system where the influence of the pile–soil interaction is essential. Results from the correlation studies indicate that the proposed model can represent well both global and local responses of the pile–soil system. The effects of the interfacial characteristics between pile and soil on the system response are also studied.     

Correlation between beam on Winkler-Pasternak foundation and beam on elastic substrate medium with inclusion of microstructure and surface effects

A novel beam-elastic substrate element with inclusion of microstructure and surface energy effects is proposed in this paper. The modified couple stress theory is employed to account for the microstructure-dependent effect of the beam bulk material while Gurtin-Murdoch surface theory is used to capture the surface energy-dependent size effect. Interaction mechanism between the beam and the surrounding substrate medium is represented by the Winkler foundation model. The governing differential equilibrium and compatibility equations of the beam-elastic substrate system are consistently derived based on virtual displacement and virtual force principles, respectively. Both essential and natural boundary conditions of the system are also obtained. Two modified Tonti’s diagrams are presented to provide the big picture of both displacement-based and force-based formulations of the system. Due to similarity between the current problem and the one related to the beam on Winkler-Pasternak foundation, the so-called “natural” beam-Winkler-Pasternak foundation element coined by the authors is employed to perform two numerical simulations to study the characteristics and behaviors of a beam-substrate system with inclusion of microstructure and surface effects.     

Performance evaluation of a 10 kWp PV power system prototype for isolated building in Thailand

This paper describes the design and testing of a 10 kW_p photovoltaic (PV) system and summarizes its performance results after the first 6 months of operation. This system functions as a stand-alone power system that is used to supply electricity for isolated buildings and is designed for integration with a micro-grid system (MGS), which is the future concept for a renewable energy-based power network system for Thailand. The system is comprised of the following components. An array with three different types of PV modules consisting amorphous thin film of 3672 W, polycrystalline solar cell of 3600 W and hybrid solar cell of 2880 W, making up a total peak power of 10.152 kW. In addition, there are three grid-connected inverters of 3.5 kW each, three bi-directional inverters of 3.5 kW each and an energy storage system of 100 kWh. After the first 6 months of system operation, it was found that all the components and the overall system had worked effectively. In total, the system had generated about 7852 kWh and the average electricity production per day was 43.6 kWh. The average efficiency of amorphous thin film panel, polycrystalline panel, hybrid solar cell panel and entire PV panel system was 6.26%, 10.48%, 13.78% and 8.82%, respectively. From the analysis of the daily energy production, daily energy consumption and energy storage, the results seem to indicate that there was some mismatching between energy supply and demand in the system. However, this can be overcome by integrating the system to a micro-grid network whereby the energy from the system can be diverted to other loads when there is a surplus and additional energy can be drawn from external sources and fed to the system when the internal supply is insufficient.     

Glass Fiber/Polyphthalamide Composites for 3D-Molded Interconnect Devices Application: Structure and Properties

The research work was to demonstrate the feasibility of a three-dimensional molded interconnect devices concept using the injection-molding technique and to investigate the effects of weld/meld line types on the structure and properties. Two different polymers based on polyphthalamide/glass fiber composites (PA6 T/X and PA10 T/X composites) were produced by injection molding at the different processing conditions. A mold was designed in such a way that a weld and meld line can be produced at different angles by changing an insert inside the mold. The mechanical properties such as stiffness, tensile strength, and flexural strength were determined in tensile and flexural tests, respectively. The adhesive strength and electrical resistance were studied with the pull-off process and four-point measurement, respectively, and are discussed. The dispersion of the glass fiber and types of meld/weld line were inspected using scanning electron microscopy. The results were in-line with the expectation of a reduction in mechanical properties in areas where weld/meld lines occurred. The results of tensile tests clearly showed that the weld and meld lines showed a considerable influence on mechanical properties. It was found that the tensile and flexural strength of polyphthalamide/glass fiber composites with weld line type decreased approximately 58 and 62%, respectively, compared to the composites without the weld line. On the other hand, the effects of injection time and mold temperature on the tensile strength were marginal.