Effect of nanoparticle shapes on irreversibility analysis of nanofluid in a microchannel with individual effects of radiative heat flux,velocity slip and convective heating

In this study, the flow of a nanoliquid in a microchannel is examined. Two distinct metallic nanoparticles, titanium and silver, are used in this study. The slip regime and convective boundary are considered to compute the momentum and energy balance equation. The mathematical expressions are made dimensionless by using nondimensional quantities. A numerical approach called Runge‐Kutta‐Fehlberg scheme is employed to obtain the solution. Effects of the internal heat source and radiative flux on fluid model are examined. The upshots of the pertinent flow parameter and the physical features are visualized through graphical elucidations. The effect of flow constraints on the second law analysis for the described physical phenomenon is predicted. Conclusion indicates that lowering of temperature of the nanofluid is obtained by higher values of nanoparticle volume fraction. The causes of irreversibility in a thermal system is explored in this investigation. The results indicate that nonspherical nanoparticles has higher thermal conductivity ratio as compared with spherical nanoparticles. Minimization of entropy can be attained through increasing volume fraction of titanium and silver nanoparticles. Besides, it is emphasized that entropy generation is high in case of disc‐shaped nanoparticles, followed by needle and sphere shapes.     

Consumer Attention to an Over‐the‐counter Warning in Four Different Styles of Design

The study consisted of three objectives: (a) to test the relative prominence and conspicuousness of a warning required by US law to be conspicuous; (b) to explore whether or not the conspicuousness of the said warning can be enhanced graphically; and (c) to develop preliminary data for power analysis that would guide decisions related to sample size in future studies. Seventeen subjects viewed four over‐the‐counter drug packages (each with a different style of warning) along with five other products while wearing an eye tracking device. Four styles of warning were used on the over‐the‐counter drug packages: no outline and no fill, outline and no fill, no outline and fill, and outline and fill. The surface area and the placement of the warnings were held constant across all four designs and were consistent with those on commercially available products. Collected data were broken into five zones: warning, brand name, strength, product benefit and net weight. Despite the fact that US law requires it to be conspicuous, the tested warning was significantly less noticeable than the brand name (objective one) for all dependent variables analyzed (α = 0.05). No significant difference was indicated for the varied warning designs (objective two). This could be because not much can be done to enhance prominence when constrained to the limited space that is typically used for such warnings or because of the limited sample size. Power calculations suggest that a sample size of nearly 200 subjects would be required to detect a 2.5 s mean difference at 80% confidence (objective three). Copyright © 2011 John Wiley & Sons, Ltd.     

Magnetic properties of sulfate glasses doped with transition metal ions

Magnetic susceptibility measurements on ZnSO₄K₂SO₄ glasses containing high concentrations of Mn²⁺, Co²⁺ or Ni²⁺ ions suggest the presence of weak ferromagnetic interaction.     

Satellite remote sensing of fine particulate matter (PM2.5) air quality over Beijing using MODIS

Fine particulate matter (aerodynamic diameters of less than 2.5 µm, PM_2.5) air pollution has become one of the major environmental challenges, causing severe environmental issues in urban visibility, climate, and public health. In this study, ground-level PM_2.5 concentrations, air-quality categories (AQCs), and health risk categories (HRCs) over Beijing, China, have been estimated based on mid-visible column aerosol optical depth (AOD) measurements extracted from Moderate Resolution Imaging Spectroradiometer (MODIS) data on board both Terra and Aqua satellites. Our results indicate that the MODIS AOD retrievals at 550 nm (AOD₅₅₀) match hourly aerosol robotic network (AERONET) measurements with correlation coefficients (r) of 0.950 for Terra and 0.895 for Aqua. The relationship between ground-level PM_2.5 and MODIS AOD₅₅₀ from March 2012 to February 2013 showed correlation coefficients of 0.69, 0.60, and 0.73 for spring, summer, and autumn, respectively. The atmospheric boundary layer height and relative humidity (RH) adjustments improved the AOD–PM_2.5 relationship in summer months. The estimates of daily average PM_2.5 from satellite measurements were used to predict both AQCs and HRCs, which are well matched with observations. Satellite remote sensing of atmospheric aerosols continues to show great potential for estimating ground-level PM_2.5 concentrations and can be further used to monitor the atmospheric environment in China.     

Shape-It-Up: Hand gesture based creative expression of 3D shapes using intelligent generalized cylinders

We present a novel interaction system, “Shape-It-Up”, for creative expression of 3D shapes through the naturalistic integration of human hand gestures with a modeling scheme dubbed intelligent generalized cylinders (IGC). To achieve this naturalistic integration, we propose a novel paradigm of shape–gesture–context interplay (SGCI) wherein the interpretation of gestures in the spatial context of a 3D shape directly deduces the designer’s intent and the subsequent modeling operations. Our key contributions towards SGCI are threefold. Firstly, we introduce a novel representation (IGC) of generalized cylinders as a function of the spatial hand gestures (postures and motion) during the creation process. This representation allows for fast creation of shapes while retaining their aesthetic features like symmetry and smoothness. Secondly, we define the spatial contexts of IGCs as proximity functions of their representational components, namely cross-sections and the skeleton with respect to the hands. Finally, we define a natural association of modification and manipulation of the IGCs by combining the hand gestures with the spatial context. Using SGCI, we implement intuitive hand-driven shape modifications through skeletal bending, sectional deformation and sectional scaling schemes. The implemented prototype involves human skeletal tracking and hand posture classification using the depth data provided by a low-cost depth sensing camera (Kinect?). With Shape-It-Up, our goal is to make the designer an integral part of the shape modeling process during early design, in contrast to the case for current CAD tools which segregate 3D sweep geometries into procedural 2D inputs in a non-intuitive and onerous process requiring extensive training. We conclusively demonstrate the modeling of a wide variety of 3D shapes within a few seconds.     

Electronic spectra of VO2+ in some tutton salts

Optical absorption spectra of VO²⁺ in ammonium magnesium sulphate hexahydrate, potassium magnesium sulphate hexahydrate and potassium zinc sulphate hexahydrate single crystals have been studied. The observed bands in all three crystals have been attributed to the VO²⁺ ion in C_4v symmetry. The octahedral and tetragonal field parameters and the molecular orbital coefficients have been evaluated.     

Molecular relaxation in cross-linked poly(ethylene glycol) and poly(propylene glycol) diacrylate networks by dielectric spectroscopy

The molecular relaxation characteristics of rubbery amorphous crosslinked networks based on poly(ethylene glycol) diacrylate [PEGDA] and poly(propylene glycol) diacrylate [PPGDA] have been investigated using broadband dielectric spectroscopy. Dielectric spectra measured across the sub-glass transition region indicate the emergence of an intermediate “fast” relaxation in the highly crosslinked networks that appears to correspond to a subset of segmental motions that are more local and less cooperative as compared to those associated with the glass transition. This process, which is similar to a distinct sub-T_g relaxation detected in poly(ethylene oxide) [PEO], may be a general feature in systems with a sufficient level of chemical or physical constraint, as it is observed in the crosslinked networks, crystalline PEO, and PEO-based nanocomposites.     

Amino‐functionalised mesoporous silica microspheres for immobilisation of Candida antarctica lipase B – application towards greener production of 2,5‐furandicarboxylic acid

In the present study, amino‐functionalised mesoporous silica microspheres were utilised as support for the covalent immobilisation of Candida antarctica lipase B (CaLB) for the subsequent production of 2,5‐furandicarboxylic acid (FDCA) from 2,5‐diformylfuran (DFF). Under the optimised operating conditions of pH 6.5, particle/enzyme ratio of 1.25:1.0 and glutaraldehyde concentration of 4 mM, a maximum CaLB immobilisation yield of 82.4% on silica microspheres was obtained in 12.25 h. The immobilised CaLB was used for the synthesis of alkyl esters, which were utilised along with hydrogen peroxide for FDCA synthesis. The biocatalytic conversion of 30 mM DFF dictated a 77–79% FDCA in 48 h at 30°C; where the turnover number and turnover frequency of immobilised CaLB were 6220.73 mol mol⁻¹ and 129.59 h⁻¹, respectively, for ethyl acetate, against 6297.65 mol mol⁻¹ and 131.2 h⁻¹, respectively, for ethyl butyrate. Upon examining the operational stability, the immobilised CaLB exhibited high stability till five cycles of FDCA production.Inspec keywords: mesoporous materials, organic compounds, biotechnology, silicon compounds, renewable materials, catalysis, catalysts, enzymes, thermal stability, biofuelOther keywords: FDCA production, amino‐functionalised mesoporous silica microspheres, greener production, 2,5‐furandicarboxylic acid, covalent immobilisation, 2,5‐diformylfuran, CaLB immobilisation, Candida antarctica lipase B immobilisation, ethyl butyrate, time 48.0 hour, temperature 30.0 degC, time 12.25 hour     

Chemically reactive and radiative flow of ferro-aluminum (AA7075) hybrid nanofluid past a stretching cylinder

The present investigation throws light on the heat transfer behavior of hybridized (ferro-aluminum alloy [AA7075]) nanofluid. In addition to that, influences of thermal radiation, magnetic effect, and chemical reaction are also considered for the exploration. Here, the flow is deliberated due to a porous stretching cylinder. The equations that portray the fluid flow are transfused to simple ordinary differential equations by applying similarity elements. Then, the procured equations have been solved by adopting the Runge–Kutta–Fehlberg 4th–5th order tool. The extracted solution are exported to plot graphs for velocity, thermal, and solutal profiles with the concerned parameters, and using these plots, the discussion has been produced for the behavior of all flow fields. The behavior of the thermal profile shows substantial enhancement with an increase in the solid volume fraction of hybrid nanofluid. The velocity and concentration panel de-escalates for larger values of Reynolds number. A significant discussion on the skin friction drag, Nusselt number, and Sherwood number has been produced.