A new alloy design concept for austenitic stainless steel with tungsten modification for bipolar plate application in PEMFC

The feasibility of a new alloy design concept utilizing the principle of ‘tungsten bronze effect’ is critically evaluated for the development of metallic bipolar plates for proton exchange membrane fuel cell (PEMFC). An austenitic stainless steel (ASS) is modified with W and La to improve the stability of the passive film in an acidic environment as well as to reduce the contact resistance by the tungsten bronze effect. The experimental ASS containing W and La was evaluated in a simulated PEMFC environment of H₃PO₄ and H₂SO₄ solutions at 80 °C, and the electrical property was evaluated by performing a contact resistance test. The test results show that the ASS modified with W and La has good passive film stability for corrosion resistance and low contact resistance. The X-ray photoelectron spectroscopy (XPS) analysis clearly suggests the possibility of the tungsten bronze effect from the change in valency state of W⁶⁺ to W⁵⁺ in the passive film formed on the modified ASS. The feasibility of a new alloy design concept utilizing the ‘tungsten bronze effect’ is well demonstrated; however, more study is highly required for the development of metallic bipolar plates of PEMFC.     

经食道心房调搏的放射性核素心血管造影

本文应用反符合电路剔除调搏脉冲干扰的方法,制成经食道心房调搏心电心音门电路触发装置,用于经食道心房调搏的核素心血管造影。参考Tzivoni标准,当逐级增加调搏心率至140次/min或亚极量心率后发现:冠心病人有调搏后EF降低;急性心肌梗塞病人EF减低更为明显,并呈室壁反向运动。因此,心房调搏核素心血管造影有助于冠心病,特别是心肌梗塞的诊断。     

岗位体验式教学法在雷达装备实践教学中的应用

针对雷达装备实践教学中演示式教学法对于学员能力的拓展和装备的综合运用等方面存在的问题,将岗位体验式教学法运用于雷达装备实践教学中.首先分析岗位体验式教学法的基本内涵;然后提出前期准备、场景设置、教学实施、交流研讨和总结讲评等5个方面的具体实施方法,进行实例分析;最后给出岗位体验式教学法的实施效果.教学实践结果验证了该方法的有效性.     

NIT-Ph-p-BEN氮氧自由基的制备及催化降解性

以对醛基苯甲酸为原料，通过醛酸与2,3-二甲基-2,3-二羟胺基丁烷缩合，再经NaIO4氧化最终制得4-(4,4,5,5-四甲基-1,3-二氧化物)咪唑基-1-苯甲酸（NIT-Ph-p-BEN氮氧自由基）。采用FTIR、UV、ERP（电子顺磁共振波谱仪）和元素分析等对其结构进行表征；通过催化降解废水中有机染料甲基橙、甲基蓝和罗丹明B对其催化活性进行了评估。结果表明，当甲基橙、甲基蓝和罗丹明B浓度为15 mg/L，NIT-Ph-p-BEN质量浓度为0.15 g/L，H2O2浓度为30 mmol/L时，NIT-Ph-p-BEN对甲基橙有更好的催化降解性，仅在1 h内甲基橙的降解率达到94.26%。此外，反应机理表明，H2O2有助于实现NIT-Ph-p-BEN自由基的再生和循环利用。     

Hydrodynamic characteristics of a FCC regenerator

The hydrodynamic and gas mixing characteristics have been determined in a FCC regenerator (0.48 m I.D.x3.4 m high) with FCC particles. Solids holdup in the dense bed decreases with increasing gas velocity, but it increases in the freeboard region. The bubble/void fraction increases with an increase along the bed height at a given gas velocity and increases with increasing gas velocity at a constant bed height. Backmixed tracer gas at the wall region is higher than that at the center region of the bed. The gas backmixing coefficient decreases with increasing gas velocity.     

农作物秸秆增强氟石膏复合材料的微观结构研究

将玉米秸秆加入改性后的氟石膏中，研究改性剂、玉米秸秆对氟石膏复合材料结构性能的影响；并用苯丙乳液对玉米秸秆纤维进行表面处理，用以改善基体材料和增强材料的界面结合状况，由此显著提高制品性能。     

A kinetic model for polystyrene (PS) pyrolysis reaction

A mathematical model for the pyrolysis reaction of polystyrene (PS) in a semi-batch reactor has been presented. The thermal degradation of PS was flexibly modeled by a combination of random and specific chain-end scissions. Numerical simulation was used to investigate the effect of operating conditions on the PS products spectrum, the results of which were validated by the experimental data. It was found that as the reaction temperature increased (decreased), the monomer fraction in the products became lower (higher) while the trimer higher (lower). No significant variation in the product composition was, however, observed while constant temperature was maintained. These results indicate the reaction temperature is an effective manipulated variable for the control of products composition of PS pyrolysis. The calculation of the optimum temperature trajectories through the optimization study can thus be of interest for achieving productivity enhancement in plastics pyrolysis processes. This paper is dedicated to Professor Dong Sup Doh on the occasion of his retirement from Korea University.     

气体控制参数对气体辅助成型产品翘曲的影响

从气体辅助注射成型工艺的角度探讨了气体的延迟时间和第一段压力这两个关键的参数对槽的影响进而对产品翘曲变形的影响，结果表明：虽然通过使用气体辅助注射成型技术能改善产品变形，但并不能完全消除变形；造成产品变形的原因和机理十分复杂，只有进行从设计到工艺的全方位考察才能有效的控制变形，气体手指效应也是造成产品变形的一个重要因素，工艺上可以通过调整延迟时间和气体压力来减小产品的变形量。