Synthetic resin. XI. Preparation and characterization of resins derived from picoline and lutidine/aromatic hydroxy,amino, and chloro compounds/formaldehyde

A number of resin copolymers have been prepared by condensing α-picoline, γ-picoline, and lutidine separately with hydroxy acetophenone, hydroxy, amino, chloro benzoic acids, and toluic acid in the presence of sodium hydroxide and succinic acid as catalyst. The resins were characterized by infrared spectra of the characteristic groups. The solubility parameters were calculated from Small's group's contribution. The antifungal activity of the resins have also been investigated.     

A new high accuracy method for two-dimensional biharmonic equation with nonlinear third derivative terms: application to Navier–Stokes equations of motion

In this paper, we propose a new compact fourth-order accurate method for solving the two-dimensional fourth-order elliptic boundary value problem with third-order nonlinear derivative terms. We use only 9-point single computational cell in the scheme. The proposed method is then employed to solve Navier–Stokes equations of motion in terms of streamfunction–velocity formulation, and the lid-driven square cavity problem. We describe the derivation of the method in details and also discuss how our streamfunction–velocity formulation is able to handle boundary conditions in terms of normal derivatives. Numerical results show that the proposed method enables us to obtain oscillation-free high accuracy solution.     

Strain Rate Effects on Dynamic Fractures in Fine‐grained Granitic Rock

The effect of dynamic strain rates on failure responses of a fine‐grained granitic rock is studied experimentally and theoretically. Theoretical investigation employs a model incorporating dynamic fracture criterion with damage mechanics theory. Experimental investigation is conducted using split Hopkinson pressure bar device. In order to investigate the effects of microstructure on dynamic fracture failure under different loading rates, fragment debris of each tested specimen is collected and analyzed. It is found through the debris analysis that the granitic rock breaks down into the fragment debris in grain size scales and the effect of strain rates on the formation of fragment debris appears to be related to the microstructure of the rock. It is also found that dynamic inertia induced by the dynamic loading can reduce the effect of friction confinement generated by the contact between the cylindrical specimen and two split Hopkinson pressure bars on the dynamic responses of the specimen. Theoretical evaluations agree with the corresponding experimental observations.     

Artificial neural network based system identification and model predictive control of a flotation column

The paper describes the design of a neural network based model predictive controller for controlling the interface level in a flotation column. For the system identification, the tailings valve opening is subjected to a pseudo-random ternary signal and response of the interface level is recorded over a period of time. The data so generated is used to develop a dynamic feed forward neural network model. The model uses two past values and one present value of the tailings valve opening as well as interface level as inputs and predicts the future interface level. This model is used for the design of a model predictive controller to control the interface level. The controller was tested both for liquid–gas system as well as liquid–gas–solid system and was found to perform very satisfactorily. The performance of the controller was compared with that of a conventional PI controller for a two-phase system and was found to be better.     

A new region aware invisible robust blind watermarking approach

Multimedia Tools and Applications - The multimedia revolution has made a strong impact on our society. The explosive growth of Internet access to this digital information has generated new...     

Effect of thiourea during nickel electrodeposition from acidic sulfate solutions

The effect of thiourea on the cathodic current efficiency (CE), deposit quality, crystallographic orientations, surface morphology, and polarization behavior of the cathode was investigated during nickel electrodeposition from acidic sulfate solutions for 2 hours at 60 °C. A slight decrease of 3 to 4 pct in the CE was observed, when the concentration of thiourea was increased from 2 to 40 mg dm⁻³. The nickel deposit quality deteriorated significantly at higher thiourea concentrations; the surface morphology deteriorated and the contamination of the nickel deposits increased. The presence of thiourea affected the peak intensities of the crystal planes. Cyclic voltammetric studies on nickel deposition at 25 °C revealed depolarization behavior of the cathode at lower thiourea concentrations, ≤10 mg dm⁻³; however, a mixed behavior is observed at higher thiourea concentrations. These changes were also observed in the exchange current density (i ₀) values.     

Barium hexaferrite magnet by topotactic reaction method

A new topotactic sintering method using Fe₂O₃ (obtained from FeO · OH) and BaCO₃ is developed for preparing cheaper grain oriented barium hexaferrite. Fe₂O₃ and BaCO₃ (precipitate grade) are wet mixed in a ball mill in stoichiometric proportion. The mixed slurry is then dried at 110° C for about 12h. The dried powder mixture containing moisture as a binder is uniaxially compacted at 5×10⁶–10×10⁶ kg m^–2 pressure. The green compacts are air sintered in the temperature range 1100–1300° C for 1 H. The best results of the sintered ferrite show maximum energy product (BH) _max in the range 7–10 kTAm^–1. The bulk of commercial requirements for toy magnets etc. may be met by this method of production which eliminates steps like calcination and cost intensive wet magnetic compaction.     

An evidence-based review of the effectiveness of cognitive behavioral therapy for psychosocial issues post-spinal cord injury.

Study Design: Systematic review. Objective: To examine the evidence supporting the effectiveness of cognitive behavioral therapy (CBT) for improving psychosocial outcomes in individuals with spinal cord injury (SCI). Method: Electronic databases (MEDLINE, CINAHL, EMBASE, and PsycINFO) were searched for studies published between 1990 and October 2010. Randomized control trials (RCTs) and nonrandomized control trials (non-RCTs) utilizing a CBT intervention to improve psychosocial outcomes (depressive symptomatology, anxiety, coping, and adjustment to disability) in outpatient persons with SCI were included for review. Levels of evidence were assigned to each study using a modified Sackett scale. Effect size calculations for the interventions were provided where possible. Results: Nine studies met the inclusion criteria. The studies reviewed included two RCTs, six prospective controlled trials (PCTs) and one cohort study. All studies examined at least two groups. There is Level 1 and Level 2 evidence supporting the use of specialized CBT protocols in persons with SCI for improving outcomes related to depression, anxiety, adjustment, and coping. Conclusions: CBT holds promise as an effective approach for persons with SCI experiencing depression, anxiety, adjustment, and coping problems. As CBT may involve many different components, it is important in the future to determine which of these elements alone or in combination is most effective in treating the emotional consequences of SCI. (PsycINFO Database Record (c) 2011 APA, all rights reserved)