The influence of phosphate on the properties of clay bricks

The fabrication, properties and composition of heated phosphate-bonded clay bricks are reported. The strength of phosphate-bonded clay bodies is shown to be related to the equilibrium pH of the clay mix. The highest strengths were obtained for mixes with equilibrium pH 7 fired at 500°C which gave a modulus of rupture 60% higher than the unmodified clay heated under similar conditions but at 800°C firing temperature. The phosphate-bonded products were also of low porosity and improved dimensional stability. An insight into the probable mechanism of strength development of the heated product has been obtained from XRD, SEM and DSC studies. The results show that the properties of the phosphate-bonded clay bodies are critically affected by new mineral phases resulting from the reactions of phosphates with clay which subsequently undergo physico-chemical changes above 550°C.     

Study of the nozzle flow in a cross-flow turbine

An investigation of the flow inside the nozzle of a Cross-Flow turbine, which is a hydraulic turbine where the rectangular water jet issuing from the nozzle crosses the rotor blades twice, is presented here. Part of the investigation consisted in the experimental measurement of the static pressure distribution on the inside walls of two different nozzle configurations, both with the nozzle mounted alone and in the presence of a rotor. The tests performed in the presence of a rotor included the measurement of efficiency and covered a wide range of working conditions around the best efficiency point. The analysis of the results obtained in this way give us an indication of the influence of the turbine non-dimensional volume flow rate on the flow inside the nozzle and the way it affects the reaction degree of the machine and its efficiency level. Although most of the tests were carried out with a 25-blade rotor, one of the analysed nozzle configurations (that with an inside vane) was also tested with a 10-blade rotor, permitting the assessment of the effect the number of blades has on the flow in the nozzle.The flow inside the nozzle with no inside vane was numerically analysed using a method based on a Schwarz-Christoffel conformal transformation of variables. The numerical results show a fair agreement with the experimental data collected when the rotor was not present. A qualitative discussion of some of the losses occurring in the nozzle is advanced based on the computer results, and its conclusions are used for explaining the poor performance of the nozzle with no inside vane.     

Efficient third-harmonic generation of a picosecond laser pulsewith time delay

A new configuration based on the polarization-mismatching scheme with time delay for efficient frequency tripling conversion is proposed in this paper. The calculated results showed that the requirement for the efficient frequency tripling conversion of a 1-ps laser pulse is not only the optimization of peak intensity of the second-harmonic pulse, but also the optimization of the pulse duration ratio and temporal difference between the o-polarization second-harmonic pulse and the e-polarization first-harmonic pulse due to group-velocity mismatch among the interacting pulses. With the proposed scheme the group velocity mismatch can be compensated. Overall energy conversion efficiency increases from 55% to 75% under the optimized conditions at the intensity of 6 GW/cm². The temporal shape of the third-harmonic pulse with 1 ps pulse duration has no subpulses. The optimization of the efficient frequency tripling conversion for intensities of over 75 GW/cm² is also described. The results showed that the maximum tripling energy conversion efficiency is close to 80% with the optimized doubler and tripler     

Modeling electromigration lifetime under bidirectional currentstress

Electromigration reliability of interconnect under bidirectional current stress has been studied in a wide frequency range (mHz to 200 MHz). Experimental results show that the AC lifetime rises with the stress current frequency. The current density exponent and the activation energy of AC lifetime are found to be twice that of DC lifetime. Pure AC current stress failure at extremely high current density is believed to result from thermal migration of metal at hot/cold transition points     

Application of evolutionary programming to transient andsubtransient parameter estimation

This paper presents an artificial intelligence approach of using evolutionary programming to estimate the transient and subtransient parameters of a generator under normal operation. The estimation using evolutionary programming is compared with that using a corrected extended Kalman filter. The comparisons with both simulation and micromachine test results show that evolutionary programming is robust to search the real values of parameters even when the data are highly contaminated by noise, while with the extended Kalman filter, the estimation tends to diverge with such data     

Geochemical characteristics of the Yufuin outflow plume, Beppu hydrothermal system, Japan

Thermal water at Yufuin (Kyushu Island, Japan) is tapped through about 820 shallow wells and used mainly for hot-spring bathing purposes. Chemical and isotopic data for fluids from wells and fumaroles in Yufuin and Beppu indicate that the thermal activity at Yufuin represents a dilute, westward-flowing hydrothermal outflow plume from the Beppu hydrothermal system. Two other (eastward-flowing) outflow plumes have long been recognized at Beppu, but the Yufuin outflow plume is first recognized here. The Yufuin outflow plume is apparently a mixture of two end-member fluids: (1) deep high-temperature (250–300°C) fluid from the Beppu system having high chloride concentration (1400–1600 mg/L) and a δ¹⁸O value near −6.0%, and (2) meteoric water having low chloride concentration (≤7 mg/L) and a δ¹⁸O value near −9.2%.A permeable conduit for the vertical and lateral transport of deep fluid from the Beppu system is provided by the Yufuin Fault zone, which extends westward from the southern flank of Mt. Tsurumi volcano to the town of Yufuin. Stable isotope ratios and chloride concentrations for shallow groundwaters near the eastern end of the fault, at an elevation near 700 m, are consistent with those required for the low-chloride meteoric end-member of the Yufuin thermal waters. Recharge of this meteoric water, as well as mixing with the Beppu deep fluid, may occur along the Yufuin Fault. Enthalpy-chloride relations indicate additional conductive heating of the Yufuin waters, in the amount of 350–500 kJ/kg beyond that which can be accounted for by mixing between Beppu deep fluid and meteoric water. This could be a result of conductive heating with convection to a depth of 1–2 km. Estimates of the magnitude of the heat source for the Beppu hydrothermal system should take into account the heat being discharged at Yufuin.     

Nickel/microcapsules composite electrocoatings; the synthesis of water-containing microcapsules and preparation of the coatings

Composite coatings, the product of electrolytic codeposition of solid particles in a metallic matrix have been developed and utilized in industry as wear resistant coatings. The work described in this paper concerns the development of water-containing metallic coatings prepared by the electrolytic codeposition of water-containing microcapsules from nickel Watts plating baths under pulse reversed current conditions. The water-containing polystyrene microcapsules employed in the codeposition experiments were produced by the complex emulsion/solvent evaporation technique. The influence of the use of two types of stabilizers on the size and the surface chemistry of the microcapsules is discussed. The microcapsules prepared in both cases are rigid spheres with compact walls and a smooth surface. The different stabilizers showed a significant influence on the dispersability of the capsules in the plating solution and their codeposition behaviour. The codeposition experiments carried out with the use of a rotating disc electrode revealed the influence of the plating parameters on the incorporation procedure and on the quality of the composite electrodeposits.     

Experimental and numerical investigation of fracture in double-edge notched steel plates

Double-edge notched (DENT) steel plates were pulled until complete fracture and several experimental observations were made (using profilometry and scanning electron microscopy). The essential work of fracture (EWF) model was found to be well verified. Numerical simulations—up to the maximum load only—of some experiments were performed using the finite element method (FEM), and incorporating geometric and material non-linearities (large deformation elasto-plasticity). Some experimental measurements were compared with the corresponding numerical computations and excellent agreement was found.