Fe3Si基合金的制备及应用研究进展

Ｆｅ３Ｓｉ基合金具有优异的软磁性能,不仅有希望硅钢片（在高频信息领域）,而且还广泛用作音几视频磁头材料和卡片阅读器用磁头材料。本文综述了Ｆｅ３Ｓｉ基合金的制备工艺及应用,并结合我们的研究工作,分析了其研究现状,简要论述了其发展前景。     

A post-growth processing methodology to achieve barium strontium titanate thin films with low dielectric loss and high tunability for reconfigurable tunable devices

Ba_0.60Sr_0.40TiO₃ (BST) thin films, grown via RF-sputtering and the metalorganic solution deposition (MOSD) techniques, were post-growth annealed via conventional thermal annealing (CTA) and UV-photon irradiation annealing. With respect to the conventional thermal annealed films the UV-photon irradiation annealed films possessed improved structural properties and dielectric response. The optimization of the UV-photon irradiation annealing process parameters (using RF-sputtered BST films) was achieved via a detailed set of iso-thermal/chronal annealing experiments. The optimized UV-process parameters, applied to MOSD synthesized BST films revealed further enhanced dielectric response, i.e., 23% reduction in tan δ with sustained tunability of 42%. The improvements in the material properties of the UV-photon irradiation annealed BST thin films are attributed to stoichiometry and structural changes enabled through the UV-photon irradiation annealing process.     

Facile fabrication of NiO<Subscript><Emphasis Type="Italic">x</Emphasis></Subscript>H<Subscript><Emphasis Type="Italic">y</Emphasis></Subscript> films and their unique electrochromic properties

The electrochromic (EC) NiO _x H _y films were fabricated through a facile sol–gel method. The formation of high quality NiO _x H _y films came from adding the xerogel back into the sol and prolonging the annealing time at gradually increasing temperature up to 250 °C. Scanning electron microscopy and atomic force microscopy characterizations indicated films were compact, homogenous, and smooth. Glance angle X-ray diffraction investigation testified NiO _x H _y films were of poor crystallization. The Fourier transform infrared, and thermogravimetry and differential thermal analysis showed that films contained the mixture of NiO, Ni(OH)₂, NiOOH, water, and organic substance. With the increasing of the xerogel ratio, the optical absorbance and reflectance of films had larger differences between the colored and bleached state, respectively. The film with the xerogel ratio of 1:5 showed excellent EC properties with a transmittance contrast as high as 60.88% at λ = 560 nm, which was higher than other sol–gel nickel oxide films reported.     

Hopping conductivity of metal-dielectric nanocomposites produced by means of magnetron sputtering with the application of oxygen and argon ions

Testing of electrical properties of nanocomposites (Co_0,45Fe_0,45Zr_0,1)_x + (Al₂O₃)_1+x within the concentration range of 0.30 < x < 0.65, produced by means of magnetron sputtering of a target composed of stripes of metallic alloy and dielectric, has been carried out. It has been found that the studied materials contain metallic nanoparticles of a diameter ranging from 6 to 10 nm. Alternating current conduction at x < 0.50 is realized by hopping mechanism while at x > 0.50 metallic conductivity is observed.The obtained results have been analyzed using a model of hopping conductivity in the egime developed earlier. This analysis allowed to extract dependences of activation energy ΔE_τ and times τ in a hopping regime after isochronous (15 min) thermal annealings within the range from 293 K to 673 K.     

In vitro apatite formation on organic–inorganic hybrids in the CaO–SiO<Subscript>2</Subscript>–PO<Subscript>5/2</Subscript>–poly(tetramethylene oxide) system

The osteoconduction potential of artificial materials is usually evaluated in vitro by apatite formation in a simulated body fluid (SBF) proposed by Kokubo and his colleagues. This paper reports the compositional dependence of apatite formation on organic–inorganic hybrids in the CaO–SiO₂–PO_5/2–poly(tetramethylene oxide) system, initiated from tetraethoxysilane (TEOS), triethyl phosphate (OP(OEt)₃), calcium chloride (CaCl₂) and poly(tetramethylene oxide)(PTMO) modified with alkoxysilane. Formation of an apatite layer was observed on the surface of the organic–inorganic hybrids with molar ratios of TEOS/OP(OEt)₃ ranging from 100/0 to 20/80. The rate of apatite formation remarkably decreased when the hybrids were synthesized with TEOS/OP(OEt)₃ ratios of 40/60 or less. Hybrids without TEOS showed no apatite formation in SBF for up to 14 days. Addition of small amounts of OP(OEt)₃ to TEOS in the hybrids led to the high dissolution of calcium and silicate, while addition of large amounts of OP(OEt)₃ decreased the dissolution of calcium and silicate ions and resulted in reduced apatite formation regardless of the dissolution of phosphate ions from the hybrids.     

Enhancing mechanical and fracture properties of sandwich composites using nanoparticle reinforcement

Polyurethane (PU) foam is reinforced with SiC nanoparticles to develop core materials for sandwich composites. Isocyanate component (Part A) of PU foam was dispersed with SiC nanoparticles, and then mixed with polyol (Part B) to manufacture nanophased core materials. Nanoparticle reinforcement varied from 0.1 to 2.0 wt% of the total polymer. Both pristine and silane functionalized SiC nanoparticles were used in the investigation. Nanophased foams were tested in compression and flexure to determine the mechanical properties. Fracture toughnesses K _IC and G _IC were determined using the SENB test. Sandwich panels were fabricated and tested for face-core debond fracture toughness using the tilted sandwich debond test. The study has revealed that reinforcement of the foam by pristine nanoparticles substantially enhances mechanical properties but degrades fracture toughness. This loss in fracture toughness, however, may be recovered with the use of functionalized nanoparticles. Small concentrations (0.1–0.2 wt%) of functionalized nanoparticles provided large improvement in debond fracture toughness of sandwich specimens.     

Removal of Pb(II) ions from aqueous solution by adsorption using bael leaves (Aegle marmelos)

Biosorption of Pb(II) on bael leaves (Aegle marmelos) was investigated for the removal of Pb(II) from aqueous solution using different doses of adsorbent, initial pH, and contact time. The maximum Pb loading capacity of the bael leaves was 104 mg g^?1 at 50 mg L^?1 initial Pb(II) concentration at pH 5.1. SEM and FT-IR studies indicated that the adsorption of Pb(II) occurs inside the wall of the hollow tubes present in the bael leaves and carboxylic acid, thioester and sulphonamide groups are involved in the process. The sorption process was best described by pseudo second order kinetics. Among Freundlich and Langmuir isotherms, the latter had a better fit with the experimental data. The activation energy E_a confirmed that the nature of adsorption was physisorption. Bael leaves can selectively remove Pb(II) in the presence of other metal ions. This was demonstrated by removing Pb from the effluent of exhausted batteries.     

Secure Data Transfer Using Multi Layer Security Protocol with Energy Power Consumption AODV in Wireless Sensor Networks

Wireless Personal Communications - Nonnegative Matrix Factorization (NMF) has been becoming an important method for feature dimension reduction in recent years since it can represent data with...     

Dry etching of GaN using chemically assisted Ion beam etching with HCI and H2/Cl2

The dry etching characteristics of GaN were investigated using chemically assisted ion beam etching (CAIBE) with HCI and H₂/Cl₂ gas. Etch rates using CAIBE/HC1 were investigated as a function of Ar ion beam energy and substrate temperature. These results were compared to CAIBE/C1₂. Etch rates were also investigated for CAIBE/H₂/Cl₂ for various ratios of H₂:C1₂. Highly anisotropic submicron lines are demonstrated using CAIBE/HC1. Auger electron spectroscopy was used to investigate surface stoichiometric changes of samples etched with CAIBE/HC1, CAIBE/H₂/Cl₂,, and CAIBE/C1₂. The diffusion of deuterium into GaN during etching was also investigated using secondary ion mass spectrometry.