Organochlorines in egg samples from Norwegian birds of prey: congener-, isomer- and enantiomer specific considerations

The content of chlorinated persistent organic pollutants was determined in a total of 44 egg samples from 8 different raptor species collected throughout Norway in the period 1991-1997. The content of 8 chlorinated bornanes, 9 chlorinated pesticides, and 15 polychlorinated biphenyl congeners (PCB) were determined. The highest average concentrations for PCB were found for eggs from White-tailed Sea Eagle and Peregrine Falcon (average sum PCB concentration: 8.9 and 9.1 microg/g wet weight (w.w.), respectively). Merlin and Sparrowhawk eggs were the highest contaminated with chlorinated pesticides (average sum pesticide concentration: 3.0 and 4.3 microg/g w.w.). For the first time, the content of chlorobornanes was determined in Norwegian birds of prey eggs. However, only minor contamination compared to PCBs and conventional chlorinated pesticides was found. The highest sum concentration was determined for White-tailed Sea Eagle eggs (0.09 microg/g w.w.). No chlorobornane contamination was found in Osprey and Merlin eggs. No spatial and regional specific trends or pattern distribution were found for organochlorine contamination in the egg samples analysed. In order to gain information about enantiomer specific bioaccumulation and biotransformation capacity of the organism, enantioselective analyses was performed for the chiral contaminants trans-chlordane, oxy-chlordane and the chlorobornane B9-1679 (Parlar #50). Indications for species-dependent deviation from the racemic distribution (enantiomeric ratio = 1) were found. Peregrine Falcon and Merlin eggs were characterised with an extremely high enantiomeric excess of the (-)-trans-chlordane (enantiomeric ratio (ER) <0.01). For Golden Eagle, Goshawk and Sparrowhawk eggs, the ERs were between 0.1 and 0.22 demonstrating also here that the (-)-trans-chlordane was the most abundant enantiomer. For the distribution of oxy-chlordane and B9-1679 enantiomers no species-dependent differences were found. For all species the ER values between 0.3 and 0.8 were determined. Thus, also for oxy-chlordane and B9-1679, the (-)-enantiomers are the most dominating stereoisomers in the birds of prey eggs analysed.     

Application of GaN-based ultraviolet-C light emitting diodes--UV LEDs--for water disinfection

GaN-based ultraviolet-C (UV-C) light emitting diodes (LEDs) are of great interest for water disinfection. They offer significant advantages compared to conventional mercury lamps due to their compact form factor, low power requirements, high efficiency, non-toxicity, and overall robustness. However, despite the significant progress in the performance of semiconductor based UV LEDs that has been achieved in recent years, these devices still suffer from low emission power and relatively short lifetimes. Even the best UV LEDs exhibit external quantum efficiencies of only 1-2%.The objective of this study was to investigate the suitability of GaN-based UV LEDs for water disinfection. The investigation included the evaluation of the performance characteristics of UV LEDs at different operating conditions as well as the design of a UV LED module in view of the requirements for water treatment applications. Bioanalytical testing was conducted using Bacillus subtilis spores as test organism and UV LED modules with emission wavelengths of 269 nm and 282 nm.The results demonstrate the functionality of the developed UV LED disinfection modules. GaN-based UV LEDs effectively inactivated B. subtilis spores during static and flow-through tests applying varying water qualities. The 269 nm LEDs reached a higher level of inactivation than the 282 nm LEDs for the same applied fluence. The lower inactivation achieved by the 282 nm LEDs was compensated by their higher photon flux. First flow-through tests indicate a linear correlation between inactivation and fluence, demonstrating a well designed flow-through reactor. With improved light output and reduced costs, GaN-based UV LEDs can provide a promising alternative for decentralised and mobile water disinfection systems.     

Toxic metals in the atmosphere in Lahore, Pakistan

Aerosol mass (PM₁₀ and PM_2.5) and detailed elemental composition were measured in monthly composites during the calendar year of 2007 at a site in Lahore, Pakistan. Elemental analysis revealed extremely high concentrations of Pb (4.4 μg m^− 3), Zn (12 μg m^− 3), Cd (0.077 μg m^− 3), and several other toxic metals. A significant fraction of the concentration of Pb (84%), Zn (98%), and Cd (90%) was contained in the fine particulate fraction (PM_2.5 and smaller); in addition, Zn and Cd were largely (≥ 60%) water soluble. The 2007 annual average PM₁₀ mass concentration was 340 μg m^− 3, which is well above the WHO guideline of 20 μg m^− 3. Dust sources were found to contribute on average (maximum) 41% (70%) of PM₁₀ mass and 14% (29%) of PM_2.5 mass on a monthly basis. Seasonally, concentrations were found to be lowest during the monsoon season (July-September). Principle component analysis identified seven factors, which combined explained 91% of the variance of the measured components of PM₁₀. These factors included three industrial sources, re-suspended soil, mobile sources, and two regional secondary aerosol sources likely from coal and/or biomass burning. The majority of the Pb was found to be associated with one industrial source, along with a number of other toxic metals including As and Cr. Cadmium, another toxic metal, was found at concentrations 16 times higher than the maximum exposure level recommended by the World Health Organization, and was concentrated in one industrial source that was also associated with Zn. These results highlight the importance of focusing control strategies not only on reducing PM mass concentration, but also on the reduction of toxic components of the PM as well, to most effectively protect human health and the environment.     

Measurement of the intrinsic process zone in rock using acoustic emission

Laboratory specimens with a smooth boundary (no notch) were fabricated from four different rock types (grain sizes from 0.1–10 mm) and were tested in three-point bending. The locations of acoustic emission that occurred around peak load were used to characterize the dimensions of the region of localized microcracking, the so-called intrinsic process zone. The size of this zone was found to vary significantly between the rock types, but was not found to vary significantly for different size beams of the same material. An approximately linear relation was found between the width of the intrinsic process zone and the logarithm of the grain size. An explanation of size effect evolves naturally by considering the intrinsic process zone as a material characteristic. Two different models were used to analyze stress at failure. The first treated the intrinsic process zone as a mathematical crack, an infinite stress raiser, from which a K_IC value was calculated. The second model assumed the intrinsic process zone was a cohesive notch, a finite stress raiser, from which the theoretical tensile strength was defined. The second method seemed somewhat better at predicting size effect on nominal peak stress.     

Job accessibility impacts of intensive and multiple land-use scenarios for the Netherlands’ Randstad Area

This paper examines job accessibility impacts of intensive and multiple land-use scenarios in the Netherlands’ Randstad Area for the period 1996–2030. The scenarios involve a heavy increase in the density and diversity of activities around railway stations. Accessibility impacts are examined using location-based accessibility measures and utility-based accessibility benefit measures within a high-resolution land-use/transport interaction modelling framework, taking into account the regional demand for economic activities and possible market responses. It is concluded that extreme concentrations of economic activities at central urban locations well served by public transport are not to be preferred over less heavy concentrations of economic activities at more locations. Heavy concentrations of new firms may firstly repel existing firms in the neighbourhood and secondly result in decreasing marginal returns of accessibility benefits for public transport users.     

Development of passive viscoelastic damper to attenuate excessive floor vibrations

Recent changes in the construction of building floors have included the use of light material composite systems and long span floor systems. Although these changes have many advantages, such floor systems can suffer from excessive vibration due to human activities. This problem is exacerbated in office buildings due to the reduction in inherent damping associated with modern fit outs. Excessive floor vibrations are often realised after the completion of construction or following structural modifications and normally arise due to inadequate knowledge of the damping values in the design process. Thus rectification measures are normally required to reduce floor accelerations. This paper proposes a new innovative passive viscoelastic damper to reduce floor vibrations. This damper can be easily tuned to the fundamental frequency of the floor and can be designed to achieve various damping values. The paper discusses the analytical development of the damper with experimental results presented on a prototype to demonstrate its effectiveness.     

Technique for measuring metallic salt effects upon the indigenous heterotrophic microflora of a natural water

The effects of several concentrations of the metallic salts Ag₂SO₄, NaAsO₃, BaCl₂2H₂O, CdCl₂2.5 H₂O, CrCl₂6H₂O, CuCl₂, HgCl₂, NaCl, NiCl₂6H₂O, PbCl₂ and ZnCl₂ upon the indigenous heterotrophic microflora of a natural water were studied. Effects of these salts upon the heterotrophic activity of the microbes were assayed using the heterotrophic technique whereas lethal effects upon the heterotrophic bacteria were determined using nutrient agar plate counts. The heterotrophic activity method is based upon the uptake and mineralization of a radioactively labeled metabolite (in these experiments ¹⁴C-glucose) by the indigenous aquatic microbes and data analysis is by Michaelis—Menten enzyme kinetics equations. Concentrations of metallic salts which resulted in bacterial death also caused erratic uptake and mineralization rates of ¹⁴C-glucose whereas sub-lethal concentrations, as determined by nutrient agar plate counts, caused a non-competitive inhibition of maximum heterotrophic activity and markedly increased the turnover time of the glucose substrate.     

Earthquake analysis of isotropic asymmetric multistory buildings

Isotropic multistory buildings are the ones characterized by the property: all load‐resisting planar frames have proportional lateral stiffness matrices. In the present paper it is proved that the modal analysis of an N‐story isotropic asymmetric, torsionally coupled, building (a problem of order 3N) can be separated into two independent sub‐problems: (a) a sub‐problem that corresponds to a single‐story asymmetric, torsionally coupled, building (a problem of order 3); and (b) a sub‐problem that corresponds to an N‐story, torsionally uncoupled, planar frame (a problem of order N). It is also demonstrated that the orientation of peak modal seismic forces of the building is independent of the orientation of seismic excitation, which affects only their size. The separation provides a better insight into the structural behavior of asymmetric multistory buildings under earthquake ground motion. Copyright © 2006 John Wiley & Sons, Ltd.     

Experimental studies on the weatherability of the capivara dam basalts,rio paranapanema,brazil

The weatherability of the basalts in the Capivara Dam site, Rio Paranapanema, São Paulo State, Brazil, has been studied by means of saturation-drying tests. A great number of samples have disaggre — gated intensively with production of fines. The behavior of these rocks is related to their petrography, especially to their content in expansive clay minerals. These studies were performed in order to obtain data for the utilization of this material as rock fill, including ripraps.