Determinations of rare earth element abundance and U-Pb age of zircons using multispot laser ablation-inductively coupled plasma mass spectrometry

We have developed a new calibration technique for multielement determination and U-Pb dating of zircon samples using laser ablation-inductively coupled plasma mass spectrometry (ICPMS) coupled with galvanometric optics. With the galvanometric optics, laser ablation of two or more sample materials could be achieved in very short time intervals (~10 ms). The resulting sample aerosols released from different ablation pits or different solid samples were mixed and homogenized within the sample cell and then transported into the ICP ion source. Multiple spot laser ablation enables spiking of analytes or internal standard elements directly into the solid samples, and therefore the standard addition calibration method can be applied for the determination of trace elements in solid samples. In this study, we have measured the rare earth element (REE) abundances of two zircon samples (Nancy 91500 and Pre?ovice) based on the standard addition technique, using a direct spiking of analytes through a multispot laser ablation of the glass standard material (NIST SRM612). The resulting REE abundance data show good agreement with previously reported values within analytical uncertainties achieved in this study (10% for most elements). Our experiments demonstrated that nonspectroscopic interferences on 14 REEs could be significantly reduced by the standard addition technique employed here. Another advantage of galvanometric devices is the accumulation of sample aerosol released from multiple spots. In this study we have measured the U-Pb age of a zircon sample (LMR) using an accumulation of sample aerosols released from 10 separate ablation pits of low diameters (~8 μm). The resulting (238)U-(206)Pb age data for the LMR zircons was 369 ± 64 Ma, which is in good agreement with previously reported age data (367.6 ± 1.5 Ma). (1) The data obtained here clearly demonstrate that the multiple spot laser ablation-ICPMS technique can become a powerful approach for elemental and isotopic ratio measurements in solid materials.     

Fabrication of heterostructures of halogen-bridged quasi-one-dimensional mixed-valence transition metal complexes

Single-heterostructure crystals of a series of halogen-bridged quasi-one- dimensional mixed-valence transition metal complexes (HMMCs) were fabricated by selective coordination epitaxial growth (SCE growth). The overgrowth crystals of the HMMC were grown on the columnar crystals of the substrate HMMC in solution. The single-heterostructure crystals were epitaxially grown only when the two HMMCs had similar crystal structures. If their crystal structures were different, no heterostructure crystal was grown. This result suggests that the degree of mismatch between the crystal structures of the substrate and the overgrowth is the predominant factor which determines the SCE growth of the HMMCs.     

Cerebral glucose metabolism in patients with frontotemporal dementia

Frontotemporal dementia (FTD) is a dementia syndrome characterized by peculiar behavioral changes arising from frontotemporal involvement and distinct from Alzheimer's disease (AD). The purpose of this study was to elucidate the specific patterns in cerebral glucose metabolism in patients with FTD and to compare them with the patterns in patients with AD and normal elderly subjects using fluorodeoxyglucose (FDG) and PET. METHODS: Twenty-one patients with a clinical diagnosis of FTD [mean age 67.0 +/- 7.0 yr, Mini Mental State Examination (MMSE) score 18.7 +/- 5.7], 21 age-, sex- and dementia-severity-matched patients with probable AD (mean age 66.9 +/- 7.1 yr, MMSE score 20.2 +/- 5.5) and 21 age- and sex-matched normal control subjects (mean age 66.8 +/- 5.7 yr) were studied. The cerebral metabolic rate for glucose (CMRglc) was measured with FDG and PET. Absolute measures of regional CMRglc were compared among the three groups. One-way ANOVA and the posthoc Tukey HSD test were used for statistical analyses. RESULTS: In the FTD group, CMRglc was preserved only in the left cerebellum, right sensorimotor area and occipital lobes. The CMRglc was significantly lower in the FTD group as opposed to the AD group in the hippocampi, orbital gyri, anterior temporal lobes, anterior cingulate gyri, basal ganglia, thalami, middle and superior frontal gyri and left inferior frontal gyrus. CONCLUSION: Although metabolic abnormality in FTD is predominant in the frontal and anterior temporal lobes and the subcortical structures, it is more widespread than has been previously stressed. These findings document an FTD-specific cerebral involvement and facilitate differential diagnosis of degenerative dementias.     

A fourth-order bandpass Δ-Σ modulator usingsecond-order bandpass noise-shaping dynamic element matching

This paper describes a multibit bandpass ΔΣ modulator (DSM) for a frequency-interleaved analog-to-digital (A/D) converter (ADC). A frequency-interleaved ADC using low oversampling ratio (OSR) DSMs is an attractive approach for broadband and high resolution A/D conversion. A multibit DSM is suitable for low-oversampling operation; however, the overall resolution of a multibit DSM is restricted by the accuracy of the internal D/A converter (DAC). Some methods have been reported for improving the internal DAC accuracy of a low-pass DSM, but no bandpass-shaping technique applicable to a bandpass DSM has been implemented, although some methods have been proposed by using simulation. This paper proposes a multibit bandpass DSM with bandpass noise-shaping dynamic element matching (BPNSDEM), which enables bandpass shaping to mismatch error of the internal DAC, and presents its implementation. The modulator was implemented in a 0.25-μm CMOS technology. It operates at a 2.5-V power supply and achieves a signal-to-noise ratio of 77.4 dB over a 250-kHz bandwidth centered at 566 kHz     

9H-xanthene-2,7-diols as antioxidants for autoxidation of linoleic acid

The antioxidant activities of 9H-xanthene-2,7-diols and α-tocopherol were studied during the oxidation of linoleic acid in a homogeneous solution and in an aqueous micelle dispersion. The antioxidant activities of 9H-xanthene-2,7-diols for both systems were 1.0–2.4 times greater relative to α-tocopherol. In addition, the 1,3,4,5,6,8-hexamethylxanthene-2,7-diol showed less cytotoxicity toward human fibroblasts than did 2,6-di-t-butyl-4-methylphenol.     

Phase-slip centers of superconducting indium bridges with variable thickness in a magnetic field

We have measured current-voltage (I–V) curves in magnetic fieldsH, for indium variable-thickness bridges whose strips were quasi-one-dimensional superconductors. TheI–V curves take three different types depending on theH regions. One has hysteresis due to phase-slip centers. The others have no hysteresis. The critical current againstH shows hysteresis owing to the surface currents induced byH. The modification of the pair-breaking time was introduced to treat theH dependence of the hysteresis ofI–V curves.     

Dielectric strength of transformer insulation at DC polarityreversal

Among special insulation tests for DC power converter transformers, polarity reversal tests can be substituted by applied AC voltage tests from a stress similarity in oil ducts. In order to investigate equivalent levels of other insulation tests to polarity reversal tests, the dielectric strength of a transformer at polarity reversals was examined by use of a model of typical oil/paper composite insulation. From the comparison of polarity reversal and other insulation tests, it was found that dielectric strength of transformer insulation at polarity reversals is phenomenally similar to that under switching impulse stresses. Equivalent AC test voltage to polarity reversal test was also estimated from the experimental results. The breakdown characteristics of polarity reversal tests showed that partial discharges at polarity reversals impose less harmful stress on insulation barriers than those at usual AC or impulse tests     

A three‐phase voltage‐source PWM inverter system characterized by sinusoidal output voltage with neither common‐mode voltage nor normal‐mode voltage

This paper deals with an inverter system integrating a small‐rated passive EMI filter with a three‐phase voltage‐source PWM inverter. The purpose of the EMI filter is to eliminate both common‐mode and normal‐mode voltages from the output voltage of the inverter. The motivation of this research is based on the well‐known fact that the higher the carrier or switching frequency, the smaller and the more effective the EMI filter. An experimental system consisting of a 5‐kVA inverter, a 3.7‐kW induction motor, and a specially designed passive EMI filter was constructed to verify the viability and effectiveness of the EMI filter. As a result, it is shown experimentally that both three‐phase line‐to‐line and line‐to‐neutral output voltages look purely sinusoidal as if the inverter system were an ideal variable‐voltage, variable‐frequency power supply when viewed from the motor terminals. This results in complete solution of serious issues related to common‐mode and normal‐mode voltages produced by the inverter. © 2003 Wiley Periodicals, Inc. Electr Eng Jpn, 145(4): 88–96, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10206