Microstructural investigation of the breakdown of the protective oxide scale on a 304 steel in the presence of oxygen and water vapour at 600 °C

This article focuses on the detailed microstructural investigation of the oxide scale formed on a 304 steel in the presence of oxygen and water vapour (40%) at 600 °C. The work has been carried out using a combination of microanalytical techniques including FIB, TEM, EDX and electron diffraction. The local breakdown of the initially protective oxide scale and the growth of island/crater oxide morphology are described. Special consideration is given to the influence of the microstructure of the steel and the oxide scale on the breakdown behaviour.     

Effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents

To investigate the effects of multiple weak interactions on the binding of phenolic compounds by polymeric adsorbents, macroporous polystyrene (PS) resin and PS‐based adsorbents with different hydrogen‐bond acceptor atoms (PS CH₂( OCH₂CH₂)_n OCH₃, n = 0, 1, 2, and 3, denoted as PS‐EG₀, PS‐EG₁, PS‐EG₂, and PS‐EG₃) were prepared. The phenol adsorption strength order on these adsorbents was PS/PS‐EG₀ < PS‐EG₁ < PS‐EG₂ < PS‐EG₃, indicating that the adsorption on PS and PS‐EG₀ was driven by hydrophobic and π–π interactions, and the adsorption on PS‐EG₁, PS‐EG₂, and PS‐EG₃ was driven by a hydrogen bond in addition to hydrophobic and π–π interactions. PS‐EG₂ may adsorb a second phenol molecule on each binding site and PS‐EG₃ may adsorb second and third ones. The adsorption strength of resorcinol increased in the order of PS, PS‐EG₁, and PS‐EG₂, indicating that the adsorption was driven by 0, 1, and 2 hydrogen bonds in addition to hydrophobic and π–π interactions. Similarly, the adsorption of phloroglucinol on PS, PS‐EG₁, PS‐EG₂, and PS‐EG₃ was driven by 0, 1, 2, and 3 hydrogen bonds in addition to hydrophobic and π–π interactions because the adsorption strength increased in this order. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4652–4658, 2006     

A Shortcut Method for Estimating the HETP of Structured Packed Distillation Columns at Elevated Pressure

A shortcut model is developed for predicting the HETP of a structured packed distillation column operating at elevated pressure. The proposed model incorporates the geometrical parameters of the packing, physical properties of the vapor and liquid phases, and the hydrodynamics of the two‐phase flow. The proposed model is tested and validated by comparing the predicted results with the present experimental data and some published HETP data. The results show that the proposed model can predict the experimental data with a deviation smaller than 20 %.     

D1100-11型造气鼓风机技术改造

针对国内采用煤制气工艺的部分中氮肥生产厂发生的造气鼓风机出力不足的现象，根据不同的系统工作状况对原风机的叶轮进行重新设计施工，不改变机组其余部分，以起到增压扩容的效果，从而实现增产降耗的目的。     

一种新型背面接触式H~+-ISFET

简要地介绍了氢离子敏场效应晶体管(H~+-ISFET)的基本结构和工作原理,提出了一种新型背面接触式H~+-ISFET。对该结构在版图、工艺设计中的有关问题,进行了探讨。最后指出:它在pH值的测量中有较好的实用价值。     

GZF高压注水井口测试防喷器的研究与应用

针对高压 (2 5MPa以上 )分层注水井进行井下分层流量测试时 ,上顶力大 ,仪器下井困难 ,井口喷漏严重 ,测试工人劳动强度大等问题 ,研制了GZF高压注水测试井口防喷器。这种防喷器采用节流降压原理进行设计 ,主要由自动输送钢丝装置、节流降压密封装置和防喷管总成 3部分组成 ,是一种用于高压注水井下测试和投捞调配的井口辅助工具 ,具有井口防喷和输送钢丝两大功能。现场试验证明 ,该防喷器结构紧凑、安装使用方便、密封可靠 ,使用井口压力可达 35MPa,自动化程度高 ,可保证仪器顺利下井 ,同时还将高空人力手送钢丝改为远距离自动输送 ,操作灵活、简单安全。特别适用于低渗高压分层注水井的井下测试和投捞。     

雨洪资源利用的必要性及其措施探讨

遵循水的规律,坚持防汛抗旱并举,实现防汛工作由单纯的洪水控制向洪水资源化转变和单一农业性抗旱向以保证包括城市供水为重点的全面抗旱转变是新时期治水新思路的重要观点之一.文章在回顾雨洪资源利用发展简史的基础上,就其必要性、可行性和利用方式进行了初步探讨.     

对我厂防治加热管内碳酸钙垢的思索

分析了我厂两碱法原卤净化后,加热管内壁结碳酸钙垢的原因,探讨了我厂采取加盐酸、加阻垢剂、用超声波阻垢器的方法,以及对加热管内碳酸钙垢防治的情况和存在的问题.     

用于平场光谱仪的非球面全息凹面光栅设计

基于全息凹面光栅理论和ZEMAX软件,设计了一种用于平场光谱仪的消象差平场非球面全息凹面光栅。与采用相同口径、相同相对孔径的全息凹球面光栅构成的平场光谱仪比较,在入射狭缝宽度相同的情况下,该光栅所构成的平场光谱仪的分辨率得到明显提高。同时,利用较大相对孔径非球面全息凹面光栅,可使平场光谱仪的结构更紧凑,从而可实现平场光谱仪的小型化。