化学气相沉积铜薄膜研究进展

本文综术了集成电路工艺的Cu布线中Cu薄膜化学气相沉积(CVD)的研究背景,详细介绍了CVD生长Cu金属薄膜的国内外研究进展及CVD对前趋物的要求,并对前趋物的一些物理、化学性质进行了总结,最后,对薄膜沉积的计算机摸拟作了简要介绍。     

环境友好水基润滑添加剂的研究

在脂肪酸分子中引入硼和氮，合成了一种环境友好水基润滑添加剂BNR，并利用红外光谱对其主要官能团进行了表征。通过四球试验机考察了BNR添加剂在水中的抗磨性能与极压性能，用X射线光电子能谱仪对磨痕表面元素进行了分析，探讨了该类添加剂的极压抗磨作用机理。结果表明：硼氮化水基润滑添加剂BNR在水中具有优良的抗磨和减摩性能；其润滑作用机理是由于长链脂肪酸分子的载体作用、硼的缺电子性、氮的高反应活性以及三者的协同作用与摩擦金属表面形成了一层高强度的吸附膜和／或摩擦化学反应膜。     

Preparation and characterization of cuprous iodide nanoparticles

A new technique for the preparation of CuI nanoparticles from CuSO₄ and KI ethanol solutions has been developed. Preparation conditions were optimized through a series of experiments. Under these conditions, the yield of CuI reached 95.39%. The product was characterized and the reaction kinetics was studied. The results show that the product takes a roughly spherical shape with an average particle size of less then 50 nm. The activation energy of the formation of CuI is found to be E _a = 0.58 × 10² kJ/mol, and the preexponential factor in the Arrhenius equation is k ₀ = 7.43 × 10¹⁶ mol/(l s). The text was submitted by the authors in English.     

开流形的曲率与拓扑

应用比较几何的方法研究了完备非紧且具有特定曲率条件的黎曼流形，证明了在一定Pinching条件限制下，流形具有有限拓扑型或者微分同胚于R^n。     

10MW高温气冷实验堆(HTR-10)燃耗测量系统控制方案的改进

基于10MW高温气冷实验堆(HTR-10)的FCA系统及CFC系统的设计原理及运行规程,在不改变FCA系统原有设备部件的前提下,对FCA系统运行逻辑关系进行了优化,改进了原燃耗测量程序,实现了燃耗测量过程的自动运行及测量结果的自动建库.在此基础上,设计了CFC系统与FCA系统PLC的通信协议,实现了燃耗测量流程与控制系统的实时数据通信.上述改进的结果使得燃料装卸流程不再需要另设运行班组,提高了效率,将人为操作的步骤最少化,降低了误操作的可能性.     

含V、N无缝钢管表面外折缺陷产生原因的分析

通过对鞍钢生产的部分批号V、N微合金强化无缝钢管及生产该钢管的原料连铸坯和连轧管坯的表面缺陷进行研究，分析了含V、N钢管表面外折缺陷的成因，提出了改善钢管表面质量的方法。采用改进后工艺生产的无缝管，其表面外折废品量大幅度降低。     

Density Measurement of Liquid Ni-Ta Alloys by a Modified Sessile Drop Method

The density of liquid Ni- Ta alloys was measured by using a modified sessile drop method. It is found that the density of the liquid Ni- Ta alloys decreases with the increasing temperature, but increases with the increase of tantalum concentration in the alloys. The molar volume of liquid Ni- Ta binary alloys increases with the increase of temperature ancl tantalum concentration.     

Ozonation of CI Reactive Black 5 using rotating packed bed and stirred tank reactor

This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry     

Study on Oxygen Isotope Fractionation in RE Oxide Minerals

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新型超微晶软磁合金FePCCuMoSi微观结构缺陷的正电子湮没研究

用正电子湮没方法研究了新型超微晶软磁合金的微观结构缺陷，样品选用的是在不同温度下退火的Ｆｅ８１Ｐ１２Ｃ３Ｃｕ１Ｍｏ０．５Ｓｉ２．５合金，结果表明，合金的微观结构构陷大小，密度随退火温度有规律地变化，这种现象可能与非晶的晶化过程有关。