The Fusion Science Research Plan for the Major U.S. Tokamaks

This is the May 1996 report of a subpanel of the US Department of Energy Fusion Energy Sciences Advisory Committee (FESAC), charged with conducting a review of the progress, priorities and potential near-term contributions of TFTR, DIII-D and Alcator C-MOD (and other facilities as appropriate) as part of the transition to a Fusion Energy Sciences Program and produce an optimum plan for obtaining the most scientific benefit from them.     

Validating the MERIS Terrestrial Chlorophyll Index (MTCI) with ground chlorophyll content data at MERIS spatial resolution

The Medium Resolution Imaging Spectrometer (MERIS) Terrestrial Chlorophyll Index (MTCI), a standard level 2 European Space Agency (ESA) product, provides information on the chlorophyll content of vegetation (amount of chlorophyll per unit area of ground). This is a combination of information on Leaf Area Index (LAI, area of leaves per unit area of ground) and the chlorophyll concentration of those leaves. The MTCI correlates strongly with chlorophyll content when using model, laboratory and field spectrometry data. However, MTCI calculated with MERIS data has only been correlated with surrogate chlorophyll content data. This is because of the logistical difficulties of determining the chlorophyll content of the area covered by a MERIS pixel (9 × 10⁴ m²). This paper reports the first attempt to determine the relationship between MTCI and chlorophyll content using actual MERIS data and actual chlorophyll content data.

During the summer of 2006 LAI and chlorophyll concentration data were collected for eight large (> 25 ha) fields around Dorchester in southern England. The fields contained six crops (beans, linseed, wheat, grass, oats and maize) at different stages of maturity and with different canopy structures, LAIs and chlorophyll concentrations. A stratified sampling method was used in which each field contained sampling units in proportion to the spatial variability of the crop. Within each unit 25 random points were sampled. This approach captured the variability of the field and reduced the potential bias introduced by the planting pattern or later agricultural treatments (e.g. pesticides or herbicides). At each random point LAI was estimated using an LAI-2000 plant canopy analyser and chlorophyll concentration was estimated using a Minolta-SPAD chlorophyll meter. In addition, for each field a calibration set of 30 contiguous SPAD measurements and associated leaf samples were collected.

The relationship between MTCI and chlorophyll content was positive. The coefficient of determination (R²) was 0.62, root mean square error (RMSE) was 244 g per MERIS pixel and accuracy of estimation (in relation to the mean) was 65%. However, one field included a high proportion of seed heads, which artificially increased the measured LAI and thus chlorophyll content. Removal of this field from the dataset resulted in a stronger relationship between MTCI and chlorophyll content with an R² of 0.8, an RMSE of 192 g per MERIS pixel and accuracy of estimation (in relation to the mean) of 71%.     

Use of Polyaminocarboxylic Acids as Hydrophilic Masking Agents for Fission Products in Actinide Partitioning Processes

During the partitioning of trivalent actinides from High Active Raffinate (HAR) solutions, most processes have to cope with an undesirable co-extraction of some of the fission products. Four hydrophilic complexing agents of the group of polyaminocarboxylic acids, namely EDTA, HEDTA, DTPA, and CTDA were tested and compared for their ability to complex fission products in a simulated PUREX raffinate solution, thereby preventing their extraction into an organic solvent. Several solvents, based on TODGA and the DIAMEX reference molecule DMDOHEMA, that are commonly known to show quite high Zr and Pd co-extraction, were studied. Our investigations ultimately resulted in a substitution of oxalic acid and HEDTA by cyclohexanediaminetetraacetic acid (CDTA). A small addition of this hydrophilic complexing agent to the feed decreased the distribution ratios of Zr from 100 to <0.01. The suppression of Pd was also very effective, resulting in >90% of the metal retained in the feed solution. The extraction of trivalent actinides and lanthanides was not negatively affected by the presence of CDTA. Furthermore, experiments with high concentrations of Zr proved the applicability of this new masking agent. The suppression of Zr and Pd extraction was also verified at a high Pu loading which makes CDTA as a masking agent attractive for grouped actinide extraction processes (GANEX) as well as DIAMEX-SANEX type separations.     

Retention of oral microorganisms on cobalt-chromium alloy and dental acrylic resin with different surface finishes

OBJECTIVES: The purposes of this study were to determine the cytocompatibility of four endodontic sealers and gutta-percha using various extracts and to compare the cellular injuries resulting from these materials in permanent 3T3 monolayers and primary human periodontal ligament fibroblasts. STUDY DESIGN: Set specimens from four sealers (AH26, Apexit, Sealapex, N2) as well as gutta-percha were eluted with cell culture medium for 24 hours, 5 days, 5 days, and 24 hours, respectively. Cytotoxic effects due to these extracts were evaluated by determining proliferation of permanent 3T3 cells and primary human periodontal ligament fibroblasts by means of the fluorochrome propidiumiodide. RESULTS: No statistically significant cellular alterations were induced by gutta-percha and Apexit, whereas various extracts of AH26 and Sealapex caused significant moderate or severe growth inhibition. Severe cellular damage was documented for all extracts of N2, which was statistically significantly different from the other materials in both cell lines (p < 0.05). CONCLUSIONS: Our results confirm that various root canal sealers constantly segregate substances after being exposed to an aqueous environment for extended periods, possibly causing moderate or severe cytotoxic reactions and possibly contributing to failure.     

ELASTIC AND VISCOUS PROPERTIES OF SEVERAL POTASH-SILICA GLASSES IN THE ANNEALING RANGE OF TEMPERATURE*

Quantitative data are presented, and conclusions are drawn regarding the molecular nature of elastic and viscous processes in certain silicate glasses.     

Ultraviolet and visible Raman analysis of thin a-C films grown by filtered cathodic arc deposition

Amorphous carbon thin films with a wide range of sp² fraction from 20 to 90% grown by filtered cathodic arc deposition have been examined by ultraviolet (UV) at 325 nm and visible Raman spectroscopy at 457 nm excitation wavelength. The comprehensive study of behaviour of G, D and T band with sp²/sp³ content has been carried out. The upwards shift of the G peak with sp³ content was observed for both excitation wavelengths. It was also found that the I(D)/I(G) ratio decreases with sp³ content for UV and visible excitations, and for high sp³ content I(D)/I(G) tends to zero. The dispersion of the G peak is also investigated in this work as a function of sp² content.     

Multivariate statistical monitoring of the aluminium smelting process

This paper describes the development of a new ‘cascade’ monitoring system for the aluminium smelting process that uses latent variable models. This system is based on the changes of variability patterns within a feeding cycle which are used to provide indications of faults and their possible causes. The system has been tested offline using 31 data sets. The performance of the system to detect an anode effect has been compared with a typical latent variable model that monitors the change of behaviour at every time instant. The results show that the ‘cascade’ monitoring system is able to detect abnormal events. It was possible to relate each event with specific patterns associated with abnormalities thus facilitating later fault diagnosis.