Degradation of NiCr/CuNiMn/NiCr films on alumina substrates

This paper addresses the aging behaviour of NiCr/CuNiMn/NiCr triple layers on Al₂O₃ ceramics at temperatures up to 200°C for film thicknesses d0.5 μm. Investigations of the film structure and the increase of resistance and its temperature coefficient during the annealing process and studies of the dependence of this aging drift on both the film thickness and the storage temperature have been carried out. Furthermore, the film stress and the effect of substrate bending on resistance have been measured. The results can be explained by the irregular film structure (columns and small bridges between them), which causes stress and current concentrations as well as local creeping, cracking and oxidation processes in the micro-bridges. They are compared with such for structurally homogeneous films on silicon wafers.     

Complex frequency technique for linear and second harmonic optical properties of metallic surfaces

We describe a complex frequency technique for evaluating the linear and quadratic dielectric responses of metal surfaces, illustrated by application to the surface of jellium. The electric susceptibilities are shorter-range functions of the spatial coordinates at complex frequency, whereas their general behaviour is complicated, long-range and highly oscillatory at real frequency. As a result the linear and the second harmonic electric charges induced by an optical perturbation are then numerically easier to calculate at complex frequency. As the functions which characterize the optical behaviour of the metal surface are analytic in the upper complex frequency half-plane, the dielectric response at real frequency can be deduced by analytic continuation from the results at complex frequency. We illustrate and discuss this approach, which should be useful for studying more realistic models of a surface in which the crystal potential is included, and where a direct calculation of the dielectric response is difficult to obtain at real frequency.     

Assessment of Capillary Rise from Shallow Groundwater by the Simulation Model SIMWASER Using Either Estimated Pedotransfer Functions or Measured Hydraulic Parameters

The performance of the water balance and crop growth model SIMWASER to estimate the water supply of a lawn by capillary rise from shallow ground water was investigated by using lysimeter measurements with a sandy and a clayey soil. Moreover the robustness of the model was evaluated by running it either with measured hydraulic soil parameters or with estimated pedotransfer functions (PTFs) derived from texture and bulk density. Simulations were performed for the years 1996–1998 with input data from the lysimeter station Berlin-Dahlem (Germany) for lysimeters containing undisturbed sandy or clayey soil monoliths, with groundwater at 135 cm depth. Simulated evapotranspiration and percolation/capillary rise were in good agreement with the measured data for all variants, while simulated soil water storage was acceptable only for the variants using hydraulic soil data based on laboratory measurements or using PTFs derived from known soil class and bulk density. PTFs based on mean total pore volume of the respective soil classes yielded soil water storages which were evidently too high; therefore they should be used with care and must be avoided at all in simulating the soil water balance of arid sites with shallow groundwater.     

Algorithmen zur Pulsweitenmodulation für Wechselrichter mit in Echtzeit berechnetem Pulsmuster

Übersicht Mit Hinblick auf die zunehmend Verbreitung findende Pulsmusterberechnung in Echtzeit werden in dem Aufsatz Gesichtspunkte diskutiert, die sich aus den Eigenschaften des leistungselektronischen Stellgliedes, des Pulswechselrichters, ergeben. Die bei Abtastregelungen für die Dauer einer Abtastperiode konstante Stellgröße muß bei ihm durch Pulsweitenmodulation in ein Pulsmuster mit konstanter Amplitude und Pulsen variabler Breite umgesetzt werden. Durch ein neues Verfahren mit versetzter Abtastung haben dabei Rechentotzeiten bis zur Dauer einer halben Abtastperiode keinen Einfluß mehr auf das Pulsmuster.

---

Algorithms for pulswidth modulation of inverters with online calculated pulse patterns

Contents Online calculation of pulse patterns will be employed more intensively in the future. Aspects concerning the powereleotronic circuit, the pulsewidth-modulated inverter, are to be discussed. The set value being constant for the duration of a sampling interval, has to be converted by a modulation algorithm into a pulse pattern with constant amplitude and pulses of variable width. Calculation dead-times up to half of sampling interval have no influence on the pulse pattern when using a new algorthm with shifted sampling instants.

---

---

Herrn Prof. Dr.-Ing. Klemens Heumann zum 60. Geburtstag gewidmet     

Cure monitoring of thermoset coatings

The combination of favorable features of tensile mode dynamic mechanical analysis and torsional braid analysis leads to a useful method for cure monitoring of thermoset coatings. This sensitive technique allows the observation of cure reactions over a wide time and temperature range, thus including gelation and long-term curing in one measurement. Isothermal baking can be simulated realistically, since evaporation of volatile compounds like solvents or blocking agents is not hindered and the sample film is in direct contact with the heating atmosphere. Examples are given showing the cure behavior of automotive clear coats and electro coats depending on parameters like crosslinker type and catalytic agents.     

Food Process Engineering: The Last 25 Years and Challenges Ahead

In the first part of this contribution, an overview is given of some of the main developments in food process engineering in the last 25 years of the 20th century. This overview is, of course, colored by the personal experience of the authors, but a sincere effort was made to maintain a general perspective. Topics that will be briefly discussed are: progress in understanding how to control food microstructure formation during processing, separation processes, conversion processes and stabilization processes, progress in flavor technology and understanding of flavor retention during processing and release. In the 2nd part, in our view, the most exiting future developments are briefly discussed. The major items here are: processing requirements for functional foods, integrated process design approaches, application of novel‘fields’in food processes,‘precision’processing, supply chain approaches to food manufacturing, and more.     

Internal drift effects on the diffusion of Ag in CdTe

Anomalous diffusion profiles of Ag in single crystalline CdTe were observed using the radiotracer ¹¹¹Ag. The diffusion anneals were performed at 800 K under Cd or Te vapor and in vacuum with low Ag concentrations. The measured Ag profiles directly reflect the distribution of the self-interstitials and vacancies of the Cd sublattice and are the result of chemical self-diffusion which describes the variation of the deviation from stoichiometry of the binary crystal as a function of depth and time. It turned out that the spread of the Ag dopant essentially is determined by the drift of the charged defects within the electric field caused by the distribution of the extrinsic and intrinsic defects.     

Thermal Generation of Residual Stress Fields for Purpose of Distortion Minimization

Thermal treatments of steel components with the goal of hardening often result in distortion by releasing the residual stresses which were brought into the specimen during the preceding processing steps. The goal of the presented work is the minimization of this distortion. By generating definite residual stress fields and investigating the resulting distortion, the distortion mechanism can be observed in detail. A flexible and reproducible way to generate such residual stress fields inside a specimen is by means of local thermal treatment with a laser beam. Computer simulations as well as experiments were carried out using an idealized tooth of a gearwheel (finger sample) as a model system. The deformation of the samples due to the laser heat treatment and the stress fields generated inside the samples were determined with respect to different process parameters.     

Inotropic effects of glyceryl trinitrate and spontaneous NO donors in the dog heart

Facial fractures may portend intracranial and skullbase injury and may lead to rapid compromise of the airway. Primary care physicians may provide emergency care for patients who have sustained facial trauma. After immediate resuscitation and stabilization, management of facial fractures requires knowledge of the anatomy, rapid treatment methods and identification of potential associated injuries for each type of facial fracture. Differentiation between the life-threatening aspects of these injuries and the less urgent, but more apparent, facial injuries will lessen the risk of complications such as bleeding, meningitis and asphyxia. Knowledge of the anatomy of the facial skeleton and of the potential injuries associated with each of the various types of facial fractures will facilitate effective management decisions. Consultation should be sought when functional features are involved or when the injury threatens to produce future cosmetic anomalies.     

Developmental assessment of 5/ 3.1 with separate effect and integral test experiments: model changes and options

A summary of modifications and options introduced in 5/ 3.1 ( 5 3.1) is presented and is shown that the predicting capabilities of the modified version of the code are improved greatly, while the general philosopy we followed in arriving at these modifications is also outlined. These changes which are the same ones we implemented in the past in the version 7j of the code, include two different heat transfer packages (one of them activated during reflooding), modification of the low mass-flux Groeneveld CHF look-up table and of the dispersed flow interfacial area (and shear) as well as of the criterion for transition into and out from this regime, almost complete elimination of the under-relaxation schemes of the interfacial closure coefficients, etc. The modified 5 3.1 code is assessed against a number of separate-effect and integral test experiments and in contrast to the frozen version, is shown to result in physically sound predictions which are much closer to the measurements, while almost all the predicted variables are free of unphysical spurious oscillations. The modifications introduced solve a number of problems associated with the frozen version of the code and result in a version which can be confidently used both for and analyses.