Herstellung einer komplexen Titan‐Knochenschraube aus Metallpulverspritzguss

Complex titanium bone screw fabricated by metal injection moulding M etal I njection M oulding (MIM) is a recently developed powder metal forming technology which is ideally suited to manufacture small geometrically complex parts from alloy powders. This innovative technology was used to fabricate a complex bone screw using metal powder of the biological inert Ti Al6 Nb7 alloy. This article presents the MIM‐technical boundary conditions to produce the screw and results of mechanical and chemical screw tests which qualify this injection moulded part as an advanced implant.     

Bis-(1-chlor-3-phenoxy-prop-2-yl)-sulfane – Nucleophile Substitution und Regiochemie,Diastereomerentrennung und -zuordnung. Synthese diastereomerenreiner Trithiacyclen

Bis-(1-chloro-3-phenoxy-prop-2-yl)-sulfanes – Nucleophilic Displacement and Regiochemistry. Separation and Assignment of Diastereomers. Synthesis of Diastereomerically Pure Trithiacycles The title compounds 1 were substituted by a series of O-, N- and S-nucleophiles (H₂O solvolysis, AgOAc, NaN₃, KSCN, NaSPh, thiourea). A strong tendency to β-elimination of HCl depending on the kind of the attacking nucleophile was found. In most cases no regioisomerization could be detected in the isolated products of the nucleophilic displacement. Best results were obtained with sulfur nucleophiles. The separation of the diastereomeric mixture of the p-kresyl derivative 1b into the individual diastereomers 1bA and 1bB in a preparative scale was achieved. These 3-thia-1,5-dichlorides and several products of substitution could be assigned to the meso- or (±)-form by examination of the stereochemistry and symmetry of the corresponding sulfoxides. The 1,5-dimercapto derivatives 8 are convenient as structural units for the synthesis of diastereomerically pure cis- or trans-disubstituted trithiacycles e.g. 15bA , 15bB . The (±)-form of the 4,6-disubstituted 2,5,8-trithia[9]-(2,6)-pyridinophane 16bA was characterized by X-ray crystal structure determination.     

Heterocyclic syntheses with malonyl chloride. 15. 7-Chloro-3,4-dihydro-4,5-dioxo-3-aryl(or-alkyl)-2-thio-2H,5H-pyrano[3,4-2-e]-1,3-oxazine from aryl or alkyl isothio-cyanates and their degradation with morpholine and ethanol

Substituted aromatic isothiocyanates with malonyl chloride yield 7-chloro-3-substituted-3,4-dihydro-4,5-dioxo-2-thio-2H,5H-pyrano [3,4-e]-1,3-oxazine ( 1 ). Alkyl isothiocyanates with malonyl chloride yield a mixture of 7-chloro-3-alkyl-2-thio pyranooxazine ( 2 ) and the 2-oxo-analogue ( 3 ). The pyrano oxazine 1 react stepwise with morpholine undergoing replacement of the 7-chloro substituent yielding the 7-morpholino analogue ( 4 ), then the pyrone ring was opened producing 5-morpholino carbonyl-4-oxo-3-substituted phenyl-2-thio-1,3-oxazine-6-ylacetomorpholid ( 5 ). Finally the oxazine ring was opened yielding 2-substituted phenyl carbomyl-3-morpholino-N,N-glutaconoyldimorpholine ( 6 ). Ethanol react with compound 1 at any molar ration causing the opening of the pyrone ring and retain the oxazine ring. Mass spectra. ¹H-n.m.r., u.v. and i.r. spectroscopic data provided information about the fine structures of the products.     

Theoretical and numerical investigation of flow stability in porous materials applied as volumetric solar receivers

This article reports results of a theoretical analysis as well as a numerical study investigating the occurrence of flow instabilities in porous materials applied as volumetric solar receivers. After a short introduction into the technology of volumetric solar receivers, which are aimed to supply heat for a steam turbine process to generate electricity, the general requirements of materials applied as solar volumetric receivers are reviewed. Finally, the main methods and results of the two studies are reported. In the theoretical analysis it is shown that heat conductivity as well as permeability properties of the porous materials have significant influence on the probability of the occurrence of flow instabilities. The numerical study has been performed to investigate the occurrence of unstable flow in heated ceramic foam materials. In the simulations a constant heat flow of radiation, that is absorbed in a defined volume, and constant permeability coefficients are assumed. Boundary conditions similar to those of the 10 MW Solucar Solar project have been chosen. In a three dimensional, heterogeneous two phase heat transfer model it was possible to simulate local overheating of the porous structure. The parameters heat conductivity, turbulent permeability coefficient and radial dispersion coefficient have been varied systematically. Consequently, for a heat flux density of 1 MW/m² a parameter chart could be generated, showing the possible occurrence of “unstable” or “stable” thermal and fluid mechanical behaviour. These numerical results are beneficial for the design of optimized materials for volumetric receivers.     

PIXE analysis and fission track dating of obsidian from South American prehispanic cultures (Colombia, Ecuador)

In the present work we have coupled PIXE with fission track dating to characterise obsidian artefacts from about 40 archaeological sites of Colombia and Ecuador. PIXE analysis, carried out with the external beam line of the AGLAE tandem accelerator, yields the content in about 15 elements with Z > 8, whereas fission track dating is applied to ages in excess of about 10 000 years. About 120 artefacts were investigated by PIXE, of which 50 were dated by fission tracks. Ages and compositions were compared to those of obsidians from all known geological sources of the region. We show that this double characterisation allows us to determine the number of obsidian sources exploited in an ancient past and to give some insight into obsidian circulation.     

Finite difference transmission line model for the design of safe multi-section cables in MRI

Magnetic Resonance Materials in Physics, Biology and Medicine - To show the relevance of a simple finite difference transmission line model to help design safe implanted cables in 1.5T MRI’s...