Melt-spun poly(tetrafluoroethylene) fibers

The recent discovery of melt-processable poly(tetrafluoroethylene) (PTFE) allows for common thermoplastic-polymer processing technologies to be applied to this unique polymer, which heretofore was considered to be highly intractable. In this paper, we report simple melt-spinning of monofilaments of a set of melt-processable (modified) PTFE grades with weight-average molar masses (M _w) ranging from 77 to 292 kg/mol. Fibers were spun at 380 °C at draw-down ratios of up to 2,750, yielding filaments of linear densities as low as 0.8 tex, corresponding to a diameter of ∼20 μm. The maximum Young’s modulus and tensile strength of as-spun fibers produced in this study were 91.7 cN/tex (1,972 MPa) and 12.0 cN/tex (258 MPa), respectively, accompanied by a strain to break of 24%.     

Estimation of Bridging Interactions for Natural Cracks from Bending Strength of Coarse-Grained Al2O3

Several ceramic materials show R -curve effects which in the past were investigated mainly with specimens containing artificial macrocracks. This paper describes how the R -curve effects caused by bridging interactions between the crack surfaces will influence the strength of specimens with natural crack populations. Calculations in terms of averaged stress intensity factors were performed to describe the development of surface cracks from the initial size up to the size at failure. As a consequence of bridging interactions, deviations from the expected straight line in the Weibull representation of strength will occur even under the assumption that the initial crack size is Weibull-distributed. A least-squares procedure allows the bridging stresses to be estimated from bending strength measurements.     

TESTING EQUALITY OF VARIANCES FOR PAIRED TIME SERIES

Abstract. We develop a simple test for testing equality of variances for paired stationary Gaussian time series. The test statistic is a modified z statistic. It is based on the periodograms of the two series and consistent estimation of the difference between the two spectral densities. Simulations illustrate the validity of the asymptotic results for finite samples. An application to EEG data is discussed.     

Effects of Geometrical Uncertainties on Electrocardiography

This paper investigates the influence of uncertainties in geometrical coordinates on calculated torso and epicardial potentials. Two types of sources, spherical epicardial and multipolar, are both considered. A concentric sphere model with the epicardial surface represented by a unit sphere and the torso surface represented by a spherical surface of radius 1.4 is utilized. While the representation of biological surfaces with spheres is a highly idealized situation, the dimensions chosen and the approximations utilized are such that the results should be indicative of those using measured biological coordinates.     

Effect of hot-air drying on flavour compounds of bell peppers (Capsicum annuum)

The influence of hot-air drying on the composition of both volatile and non-volatile flavour compounds of different Dutch bell pepper cultivars was investigated. Contents of glucose, fructose, ascorbic, citric, and oxalic acid decreased significantly after drying, while the levels of sucrose, malic, fumaric, and cis-aconitic acid increased. Glucose, fructose and ascorbic acid probably participate in Maillard reactions during heating. Different effects of drying could be distinguished on the composition of volatile compounds. The majority of these compounds evaporated during drying. Some compounds were partly retained in the dried bell peppers, whereas others disappeared completely. Gas chromatography-sniffing port analysis revealed that compounds with mainly “fresh” odour notes like lettuce/grassy/green bell pepper ((Z-2-3-hexenal), fruity/almond ((E)-2-hexenal), fruity (octanal), lettuce/green bell pepper ((Z)-3-hexenol), and grassy/green bell pepper ((Z)-2-hexenal) decreased or disappeared after drying. Another group of compounds increased or were formed during drying, like 4-octen-3-one, (E)-2-heptenal, (E)-2-octenal, (E,Z)- and (E,E)-2,4-heptadienal, decanal, and (E)-2-nonenal; most are known as autoxidation products of unsatu-rated fatty acids. The increased levels of 2-methylpropionic and 2- and 3-methylbutyric acid, 2-metlhylpropanal, and 2- and 3-methylbutanal seemed to be due to Strecker degradation. Gas chromatography-sniffing port analysis showed that the latter three compounds had distinct cacao, sweaty, and spicy odour characteristics.     

Effects of 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) on early life stages of the pike (Esox lucius L.)

Freshly fertilized pike eggs were exposed to 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) at concentrations of 0.1, 1.0 and 10 ppt (ng/liter) for 96 hours. At all concentrations examined egg development was retarded by 23%, and the growth of fry was also significantly retarded for a long period after exposure. A dose-related mortality was observed. Highest mortality rates occurred during resorption of the yolk and reached almost 100 percent at a concentration of 10 ppt. Death was preceded by development of severe generalized edemas.Histopathologically edemas and hemorrhages were observed, together with alterations of bloodvessel walls. In the liver, two stages of pathological changes were distinguished. The first was characterized by a dilation of sinusoids and a slight swelling of hepatocyte nuclei; in the second stage the nuclei were enlarged up to twice the normal diameter. Hepatocytes were degenerated and varied in size and shape and liver architecture was a almost completely lost.