Interfacial electrical properties of diamond-like carbon/gallium arsenide heterostructures

Deposition onto GaAs of dielectric film with good interfacial properties is difficult owing to the high surface state densities at the GaAs surface. Study of diamond-like carbon (DLC)/GaAs heterostructures is worthwhile because of the advantageous properties of insulating DLC film and the low temperatures involved in its preparation. In this paper, we compare the electrical interfacial properties of DLC/GaAs with those of DLC/Si and DLC/Ge structures. The DLC films were prepared by r.f. plasma-assisted chemical vapour deposition using a mixture of propane and n-butane. Capacitance measurements were taken in the frequency range 400 Hz to 1 MHz. The interface trap density distribution N_ss(E) was estimated for the DLC---Si interface using Terman's method. Compared with the DLC---Si and DLC---Ge interfaces, the DLC---GaAs interface shows qualitatively different behaviour. There is an indication that the interfacial layer at the DLC---GaAs interface is more conducting than the DLC film, giving rise to Maxwell-Wagner type relaxation. As a result, the effective permittivity of the DLC film is one order of magnitude higher. The formation of this interfacial layer could be related to pre-etching of the GaAs substrate using argon plasma.     

Performance of Wang–Landau algorithm in lattice model of liquid crystals

We present a study on the performance of the Wang–Landau algorithm in a lattice model of liquid crystals which is a continuous lattice spin model. We propose a novel method of the spin update scheme in a continuous lattice spin model. The proposed scheme reduces the autocorrelation time of the simulation and results in faster convergence.     

Authentication study of volatile flavour compounds composition in Slavonian traditional dry fermented salami “kulen”

Volatiles from famous Slavonian salami “kulen” were isolated by nitrogen purge and steam distillation (NPSD) and analysed, for the first time, by gas chromatography and mass spectrometry (GC and GC–MS). In all, 119 organic compounds were identified that originated from lipid oxidation, amino acid degradation, smoke treatment and added spices with different distribution among NPSD traps. NPSD method enabled comprehensive profiling with almost exclusive distribution of several major compounds in particular trap with little or no interference from abundant lipid constituents in the samples. The major identified flavour important compounds were methylphenols, methoxyphenols, organosulphur compounds (diallyl sulphide, diallyl disulphide, methylallyl disulphide, diallyl trisulphide and methional) and several derivatives of 2-cyclopenten-1-one such as ethyl cyclotene. Non-important flavour constituents such as high-molecular fatty acids, alcohols and aldehydes were also present among abundant compounds. General trends for possible discrimination of “kulen” volatiles profile among other European salami volatiles were noticed (lower amount of terpenes and higher percentages of diallyl sulphide, methoxyphenols, methylphenols and 2-cyclopenten-1-one derivatives).     

Safety assessment and evaluation of probiotic potential of bacteriocinogenic Enterococcus faecium KH 24 strain under in vitro and in vivo conditions

In the present investigation, a previously isolated Enterococcus faecium KH 24 strain was evaluated for the presence of virulence determinants (agg, esp, efaAfm, gelE, cylA, cylB, clyM, cpd, cob, ccf, ace and hyl), sensitivity to various antibiotics and production of biogenic amines. No virulence determinants were detected, except efaAfm. KH 24 was found to be sensitive to most of the tested antibiotics and none of the biogenic amines were produced by it. Moreover, KH 24 showed good in vitro tolerance to biological barriers and furthermore, its survival in gut of mice was also evaluated. Mice group fed with E. faecium KH 24 strain showed better weight gain and nearly 1 log cfu/g decrease in Salmonella enteritidis counts in the intestines as compared to control (p < 0.05). Enhanced growth of lactobacilli (p < 0.05) and decrease in coliform counts (p < 0.05) were also observed in test group. E. faecium KH 24 is, therefore, found to be a safe strain and it may be used as protective culture or as a probiotic in food preparations.     

Impact of Milk Derived β-Casomorphins on Physiological Functions and Trends in Research: A Review

β-Casomorphins are a group of opioid peptides released during gastrointestinal digestion or food processing from the β-casein of milk protein. Consequently, milk can be divided into A1 and A2 “like” groups depending upon the presence or absence of proline or histidine at the 67th position of β-casein. A1 “like” milk is postulated to be a source of BCM-7 as histidine allows the cleavage at this position, while A2 “like” milk has proline that resists the hydrolysis. On one hand, BCM-7 has been implicated as a risk factor for cardiovascular diseases, type I diabetes, and neurological disorders. On the other hand, various physiological effects of these peptides have also been documented, i.e., secretion of mucus, increased activity of superoxide dismutase and catalase, increased levels of prolactin, and analgesic role. In addition, many evidences correlate these peptides with various immunological functions, such as development of innate immunity, lymphocyte proliferation and cellular immunity, role in autoimmune diseases, histamine release, and allergy. In conclusion, the role of β-casomorphins in physiological functions remains controversial and more research with improved diagnostic techniques is needed to unravel the mechanism and study physiological functions of β-casomorphins. Thus, health-related aspects of β-casomorphins (positive, negative, and immunological impacts) have been comprehensively reviewed in this article.     

Effects of kiwifruit and mixed dietary fibre on faecal properties and microbiota in rats: a dose–response analysis

In this study, a rat model was used to explore the interaction of kiwifruit with co‐consumed mixed dietary fibre. Rats were used in three consecutive trials in which faecal properties and composition, and bacterial populations were examined. In trial 1 diets, content of a dietary fibre mixture (DFM; Raftiline–citrus fibre–wheat fibre) was increased from 0% to 20%. In trial 2, dried kiwifruit pulp (KFP) content was increased from 0% to 20%. In trial 3, KFP was increased from 0% to 20% in a diet containing a 20% basal content of the DFM. The KFP caused a small dose‐dependent increase in faecal bulk and water‐holding capacity and had much less effect than the DFM. Faecal bacterial populations examined were stable across all diets and intakes of DFM and KFP. The disappearance of fermentable fibre during hind gut passage was not reduced with increasing KFP. Therefore, kiwifruit may not only have the beneficial effect of extending fermentation distally in the colon through gut activation, but may do so without disrupting the bacterial ecosystem and its functions.