Proline-derived in situ synthesis of nitrogen-doped porous carbon nanosheets with encaged Fe2O3@Fe3C nanoparticles for lithium-ion battery anodes

The homogeneous incorporation of heteroatoms into two-dimensional C nanostructures, which leads to an increased chemical reactivity and electrical conductivity as well as enhanced synergistic catalysis as a conductive matrix to disperse and encapsulate active nanocatalysts, is highly attractive and quite challenging. In this study, by using the natural and cheap hydrotropic amino acid proline—which has remarkably high solubility in water and a desirable N content of ~12.2 wt.%—as a C precursor pyrolyzed in the presence of a cubic KCl template, we developed a facile protocol for the large-scale production of N-doped C nanosheets with a hierarchically porous structure in a homogeneous dispersion. With concomitantly encapsulated and evenly spread Fe₂O₃ nanoparticles surrounded by two protective ultrathin layers of inner Fe₃C and outer onion-like C, the resulting N-doped graphitic C nanosheet hybrids (Fe₂O₃@Fe₃C-NGCNs) exhibited a very high Li-storage capacity and excellent rate capability with a reliable and prolonged cycle life. A reversible capacity as high as 857 mAh•g^–1 at a current density of 100 mA•g^–1 was observed even after 100 cycles. The capacity retention at a current density 10 times higher—1,000 mA•g^–1—reached 680 mAh•g^–1, which is 79% of that at 100 mA•g^–1, indicating that the hybrids are promising as anodes for advanced Li-ion batteries. The results highlight the importance of the heteroatomic dopant modification of the NGCNs host with tailored electronic and crystalline structures for competitive Li-storage features.

     

Surface energy-mediated fibronectin adsorption and osteoblast responses on nanostructured diamond

Nanostructured diamond have potential applications in many biomedical related fields and demonstrated extraordinary capacity to influence cellular responses. Studying the surface property of nanodiamond and its influence to protein adsorption and subsequent cellular responses along with the mechanism behind such capacity becomes more important. Here the role of surface energy associated with nanostructured diamond in modulating fibronectin and osteoblast(OB, bone forming cells) responses was investigated. Nanocrystalline diamond(NCD) and submicron crystalline diamond(SMCD) films with controllable surface energy were prepared by microwave-enhanced plasma chemical vapor deposition(MPCVD) techniques. Fibronectin adsorption on the diamond films with varied surface energy values was measured via the enzyme-linked immunosorbent assay(ELISA) and the relationship between the surface energy and fibronectin adsorption was studied. The result indicated that fibronectin adsorption on nanostructured surfaces was closely related to both surface energy and material microstructures. The spreading and migration of OB aggregates(each containing 30–50 cells) on the NCD with varied surface energy values were also studied. The result indicates a correlation between the cell spreading and migration on nanodiamond and the surface energy of nanostructured surface.     

Container-Based Internet of Vehicles Edge Application Migration Mechanism

Internet of Vehicles (IoV) applications integrating with edge computing will significantly drive the growth of IoV. However, the contradiction between the high-speed mobility of vehicles, the delay sensitivity of corresponding IoV applications and the limited coverage and resource capacity of distributed edge servers will pose challenges to the service continuity and stability of IoV applications. IoV application migration is a promising solution that can be supported by application containerization, a technology forseamless cross-edge-server application migration without user perception. Therefore, this paper proposes the container-based IoV edge application migration mechanism, consisting of three parts. The first is the migration trigger determination algorithm for cross-border migration and service degradation migration, respectively, based on trajectory prediction and traffic awareness to improve the determination accuracy. The second is the migration target decision calculation model for minimizing the average migration time and maximizing the average service time to reduce migration times and improve the stability and adaptability of migration decisions. The third is the migration decision algorithm based on the improved artificial bee colony algorithm to avoid local optimal migration decisions. Simulation results show that the proposed migration mechanism can reduce migration times, reduce average migration time, improve average service time and enhance the stability and adaptability of IoV application services.     

Influence of Matrices on Oxygen Sensing of Three Sensing Films with Chemically Conjugated Platinum Porphyrin Probes and Preliminary Application for Monitoring of Oxygen Consumption of Escherichia coli (E. coli)

Oxygen sensing films were synthesized by a chemical conjugation of functional platinum porphyrin probes in silica gel, polystyrene (PS), and poly(2-hydroxyethyl methacrylate) (PHEMA) matrices. Responses of the sensing films to gaseous oxygen and dissolved oxygen were studied and the influence of the matrices on the sensing behaviors was investigated. Silica gel films had the highest fluorescence intensity ratio from deoxygenated to oxygenated environments and the fastest response time to oxygen. PHEMA films had no response to gaseous oxygen, but had greater sensitivity and a faster response time for dissolved oxygen than those of PS films. The influence of matrices on oxygen response, sensitivity and response time was discussed. The influence is most likely attributed to the oxygen diffusion abilities of the matrices. Since the probes were chemically immobilized in the matrices, no leaching of the probes was observed from the sensing films when applied in aqueous environment. One sensing film made from the PHEMA matrix was used to preliminarily monitor the oxygen consumption of Escherichia coli (E. coli) bacteria. E. coli cell density and antibiotics ampicillin concentration dependent oxygen consumption was observed, indicating the potential application of the oxygen sensing film for biological application.     

2HL055恒流二极管参数测试

2HL055是贵州博越公司生产的恒流二极管,该类器件恒定电流大,极限电压低,可以直接驱动负载,但器件形成实验室成品后,没有进行过参数测试,其基本参数范围不能确定。文章拟通过试验,进一步测试2HL055器件的基本参数,并确定部分参数的测试方法。     

Multi‐Unit Bayesian Auction with Demand or Budget Constraints

We consider the problem of revenue maximization on multi‐unit auctions where items are distinguished by their relative values; any pair of items has the same ratio of values to all buyers. As is common in the study of revenue maximizing problems, we assume that buyers' valuations are drawn from public known distributions and they have additive valuations for multiple items. Our problem is well motivated by sponsored search auctions, which made money for Google and Yahoo! in practice. In this auction, each advertiser bids an amount b_i to compete for ad slots on a web page. The value of each ad slot corresponds to its click‐through‐rate, and each buyer has her own per‐click valuations, which is her private information. Obviously, a strategic bidder may bid an amount that is different with her true valuation to improve her utility. Our goal is to design truthful mechanisms avoiding this misreporting. We develop the optimal (with maximum revenue) truthful auction for a relaxed demand model (where each buyer i wants at most d_i items) and a sharp demand model (where buyer i wants exactly d_i items). We also find an auction that always guarantees at least half of the revenue of the optimal auction when the buyers are budget constrained. Moreover, all of the auctions we design can be computed efficiently, that is, in polynomial time.     

Reversible data hiding in encrypted images based on multi-level encryption and block histogram modification

Multimedia Tools and Applications - In recent years there has been significant interest in reversible data hiding, and also in particular, reversible data hiding in encrypted images (RDH-EI). This...