喷嘴的熔模铸造生产工艺研究

重点介绍了喷嘴的熔模铸造基本工艺过程和主要工艺参数。结果表明,该工艺合理可行,解决了该产品普通铸造中的铸造缺陷问题。不但成功生产出了高质量的产品,提高了产品的合格率,而且还为同类产品的熔模铸造提供了参考。     

PPES/MC尼龙6中相互作用对MC尼龙6的结晶及熔融行为影响

采用原位共混与溶液共沉淀两种不同的方法制得了PPES/MC尼龙6共混物。通过对共混物的DSC非等温结晶与熔融行为表征,推出共混物之间的相互作用。结果表明两种共混物中PPES对MC尼龙6的结晶都起阻碍作用,溶液共混物中熔融峰温(Tm)相对于MC尼龙6变化不大,而其在原位共混物中的影响很大,使得MC尼龙6的熔融峰温(Tm)向高温移动。更值得注意的是,原位共混物中MC尼龙6的结晶与熔融峰温相对于溶液共沉淀样品中偏移纯MC尼龙6的峰温更明显,说明原位共混物中PPES与MC尼龙6之间的相互作用大于溶液共沉淀共混物中的PPES与MC尼龙6的相互作用。在溶液共沉淀中MC尼龙6的结晶和熔融峰温均比在原位共混物中的高。     

A Simple Method to Synthesize Cadmium Hydroxide Nanobelts

Cd(OH)₂ nanobelts have been synthesized in high yield by a convenient polyol method for the first time. XRD, XPS, FESEM, and TEM were used to characterize the product, which revealed that the product consisted of belt-like crystals about 40 nm in thickness and length up to several hundreds of micrometers. Studies found that the viscosity of the solvent has important influence on the morphology of the final products. The optical absorption spectrum indicates that the Cd(OH)₂ nanobelts have a direct band gap of 4.45 eV.     

Multiscale, Multiphysics Numerical Modeling of Fusion Welding with Experimental Characterization and Validation

Various physical interfacial phenomena occur during the process of welding and influence the final properties of welded structures. As the features of such interfaces depend on physics that resolve at different spatial scales, a multiscale and multiphysics numerical modeling approach is necessary. In a collaborative research project Modeling of Interface Evolution in Advanced Welding, a novel strategy of model linking is employed in a multiscale, multiphysics computational framework for fusion welding. We only directly link numerical models that are on neighboring spatial scales instead of trying to link all submodels directly together through all available spatial scales. This strategy ensures that the numerical models assist one another via smooth data transfer, avoiding the huge difficulty raised by forcing models to attempt communication over many spatial scales. Experimental activities contribute to the modeling work by providing valuable input parameters and validation data. Representative examples of the results of modeling, linking and characterization are presented.     

Mg/Zn界面的AF超动力学中的阿累尼乌斯方程及两步法模拟机制(英文)

加速因子(AF)法是解决固体界面原子深层扩散简单且适用的方法。在AF超动力学模拟的框架内,以Mg/Zn界面为例,首先研究原子沿界面z轴方向上的一维扩散系数Dz与温度的关系,进而探讨加速因子A对扩散常数、扩散激活能的影响;然后,在AF法的基础上,通过两步法对Mg/Zn界面的原子扩散及相形成过程进行模拟。结果表明,不同加速因子下的扩散系数Dz均较好地遵循Arrhenius方程;在没有发生相变的情况下,当扩散机制一定时,扩散常数D0的值与A无关;采用AF超动力学模拟时原子的扩散激活能Q*与原激活能Q的关系符合Q*=Q/A。据此,构建了AF超动力学模拟下的一维阿累尼乌斯方程:Dz=D0exp[Q/(ART)]。同时,AF法可以对界面相形成过程及其变化趋势作预测,且只有两步法才能确切得到不同传质阶段的体系平衡结构及平衡能量。     

ZnO溶胶改性的玻璃中空纤维膜制备及其染料分离性能研究

将聚偏氟乙烯和钠硼硅玻璃粉先后加入到N,N-二甲基乙酰胺中形成铸膜液,采用干-湿法纺丝和高温烧结处理得到玻璃中空纤维膜,然后在膜上涂覆ZnO溶胶得到ZnO改性的玻璃中空纤维膜.涂覆ZnO溶胶的膜对碳素、刚果红和亚甲基蓝截留率分别为98.65％、98.08％和55.62％,与基膜相比,ZnO溶胶的涂覆促进了染料的截留.此外还测试了涂覆ZnO溶胶膜的长期稳定性,也表现出了对刚果红染料高效的去除率.     

Ga掺杂对Fe4N材料电磁性能的影响

采用固气反应法合成不同掺Ga量的GaxFe4-xN(0≤x≤0.9)粉体,用10wt%石蜡粘结制备成块体材料,研究了Ga掺杂对Fe4N磁体的晶体结构、饱和磁化强度、矫顽力和复磁导率的影响。结果表明,在完全固溶范围内,Ga掺杂会导致Fe4N晶格常数a增大,随着掺杂量x的增大a线性增大;GaxFe4-xN的饱和磁化强度随着掺Ga量的增大线性降低;适量掺Ga有利于降低Fe4N粉体的矫顽力Hc,当掺杂量x在0.4～-0.6这个范围时,Hc达到最低值10Oe;在10MHz～1GHz频段范围内,微量掺杂在一定程度上能够提高GaxFe4-xN的起始磁导率及虚部最大值,但降低了其截止频率,而当Ga掺杂量较高时Fe4N磁导率会显著降低。     

Mg-6Zn-1Mn镁合金的热压缩变形行为及加工图

采用Gleeble-1500热/力模拟试验机进行压缩试验,研究了Mg-6Zn-1Mn合金在变形温度250～450℃、应变速率0.001～10 s-1范围内的流变应力行为,采用Zener-Hollomon参数法构建合金高温塑性变形的本构关系;并以热压缩试验为基础,建立并初步分析了Mg-6Zn-1Mn合金的DMM加工图。结果表明:Mg-6Zn-1Mn合金在热压缩过程中发生了明显的动态回复与动态再结晶,流变应力随应变速率的增加而增加,随温度的升高而降低;流变应力的预测值与试验值较吻合;建立的加工图表明合金高温变形时存在2个失稳区域,而在温度325～425℃、应变速率0.01～0.365 s-1范围内出现1个非失稳区、功率耗散峰值区,该区域最适合Mg-6Zn-1Mn合金进行热加工。     

Recent Developments in Delivery of MicroRNAs Utilizing Nanosystems for Metabolic Syndrome Therapy

Metabolic syndrome (MetS) is a set of complex, chronic inflammatory conditions that are characterized by central obesity and associated with an increased risk of cardiovascular diseases. In recent years, microRNAs (miRNAs) have become an important type of endocrine factors, which play crucial roles in maintaining energy balance and metabolic homeostasis. However, its unfavorable properties such as easy degradation in blood and off-target effect are still a barrier for clinical application. Nanosystem based delivery possess strong protection, high bioavailability and control release rate, which is beneficial for success of gene therapy. This review first describes the current progress and advances on miRNAs associated with MetS, then provides a summary of the therapeutic potential and targets of miRNAs in metabolic organs. Next, it discusses recent advances in the functionalized development of classic delivery systems (exosomes, liposomes and polymers), including their structures, properties, functions and applications. Furthermore, this work briefly discusses the intelligent strategies used in emerging novel delivery systems (selenium nanoparticles, DNA origami, microneedles and magnetosomes). Finally, challenges and future directions in this field are discussed provide a comprehensive overview of the future development of targeted miRNAs delivery for MetS treatment. With these contributions, it is expected to address and accelerate the development of effective NA delivery systems for the treatment of MetS.