Ionothermal synthesis of a three-dimensional zinc phosphate with DFT topology using unstable deep-eutectic solvent as template-delivery agent

A three-dimensional zinc phosphate compound with DFT topology, designated as ZnPO₄-EU1, has been synthesized by an ionothermal approach from the system HF-ZnO–P₂O₅-choline chloride-imidazolidone. Ethylenediamine, derived from decomposition of the imidazolidone component of the deep-eutectic solvent (DES) itself, is delivered to the synthesis and serves as an appropriate template for ZnPO₄-EU1. Experiments in which the synthesis conditions were varied showed that ZnPO₄-EU1 may be prepared over a wide molar ratio of P/Zn = 0.55–13.0. Powder X-ray diffraction patterns have been obtained at intervals to track the crystallization process of this material. The experimental data show that Zn₃(PO₄)₂ · 4H₂O (a dense phase) was first isolated from the DES after reaction for 1 h. Subsequently, the pure phase of ZnPO₄-EU1 was obtained with increasing crystallization time from 12 h to 72 h. The experimental results show that the nucleation and crystallization take place with relatively low levels of solvent degradation, demonstrating that zinc phosphate with a three-dimensional framework can be synthesized by in situ generation of an appropriate template using an unstable DES at high temperatures (150–200 °C).     

Two-dimensional symmetric multimode interferences in silicon square waveguides

Symmetric interference in two-dimensional multimode silicon waveguides is experimentally investigated. For a 100/spl times/100 /spl mu/m/sup 2/ cross section, 2700-/spl mu/m-long waveguide fabricated on silicon-on-insulator substrate, an 8/spl times/8 matrix of replicated images with high contrast ratio is demonstrated for 1530-1570 nm wavelength range. Symmetric interference results in reduced device length, and the actual device length is consistent with the theoretical expectation. The device also exhibits stable imaging in terms of good loss uniformity, and low wavelength and polarization dependencies among the replicated images.     

基于OpenGL和MFC的石油井管道的绘制

介绍了O penGL的知识和石油井的基本概念,利用O penGL实现石油井管道的绘制,包括石油井数据的变换和管道起始点的跟踪和角度的旋转。纹理光照效果增强图形生动性,交互操作改变图形视角。并且利用DAO数据库和L istv iew控件实现数据保存和修改。该程序能够完成石油井的管道绘制和数据保存。     

关于新农村农民公寓建设的建议——以山东省枣庄市市中区为例

近年来,随着工业化、城镇化步伐不断加快,特别是各类开发区建设的推进,土地被大量占用,部分农民失去了土地,并衍生出"失业、失房"现象,造成新的弱势群体和不稳定因素。如何实现经济发展和     

A 3-D Enlarged Cell Technique (ECT) for the Conformal FDTD Method

In this paper, we present an enlarged cell technique (ECT) to avoid the time step reduction encountered in the conformal finite-difference time-domain (CFDTD) method due to small irregular cells truncated by metallic boundaries. We focus our efforts on the discussion of the accuracy and stability of the ECT and its comparison with other conformal methods, especially the one called the uniformly stable conformal (USC) method. We also provide a simplified ECT, which is much easier to implement. In the ECT, a stability criterion is first constructed to identify instable irregular cells, i.e., those having so small an area to cause instability. Those instable cells are then enlarged into their adjacent cells to obtain a large, stable area. Careful treatment is performed on the communication between the intruding and intruded cells in terms of electromotive force by keeping the total electromotive force conservative. This technique is verified by several 3-D numerical experiments. Results show that the ECT is second-order accurate and numerically stable at the regular Courant time step limit.     

基于XML的基金会现场总线设备描述技术

本文简单介绍了基金会现场总线FF的设备描述和新一代稳定、可靠、通用的网络标记语言XML的特点，提出了一种用XML语言实现设备描述的方法。     

高压水射流射孔井眼应力数值模拟研究

水力射孔技术是一种新型完井方式,利用深穿透水力射孔技术辅助定向压裂,可实现油层改造和油井增产。考虑套管水泥环的影响,采用有限元理论结合ANSYS软件计算了高压水射流水力射孔井眼周围的应力,重点分析了水力射孔参数对井周应力的影响规律,初步研究了直井水力压裂时水力射孔对裂缝起裂的影响。计算结果表明,沿最大水平地应力方向布孔时,孔眼根部的周向拉应力最大,裂缝将会在孔眼根部起裂;选择合理水力射孔参数可有效降低地层破裂压力。研究结果可为高压水射流水力射孔辅助定向压裂提供参数优选的依据。     

住宅设计的误区

文章列举了目前住宅设计中存在的问题,反映了当前设计领域的一些现象,阐述了建筑师应当辨证地看待这一现象,对其有一个正确的认识,担负起历史责任.     

降低紧密纺色织物浆纱断头的几项措施

为了降低紧密纺色织品种的浆纱断头,提高产品质量,分析了该品种在浆纱过程中产生断头的原因,介绍了在操作方面应采取的措施及在工艺方面应注意的问题.通过适当加大干分绞区张力及前浆槽纱线的喂入张力、预烘张力,单独控制前浆槽的浆液粘度,确保回潮率满足工艺要求,有效解决了紧密纺色织品种浆纱断头问题,提高了织轴质量.     

Novel tiO2 nanocatalysts for wastewater purification: tapping energy from the sun.

Water treatment using TiO2 semiconductor as a durable heterogeneous photocatalyst has been the focus of environmentalists in recent years. Currently, we developed an inexpensive and highly efficient approach for synthesizing nitrogen-doped TiO2 with lower band-gap energy that can respond to visible light. Doping on the molecular scale led to an enhanced nitrogen concentration of up to 21.8%. Reflectance measurements showed the synthesized N-doped TiO2 nanoparticles are catalytically active with the absorbance that extends into the visible region up to 600 nm. The water purification potential of this new class of compound was evaluated by studying the photodegradation of Acid Orange 7 (AO7) and E. coli. Experiments were conducted to compare the photocatalytic activities of N-doped TiO2 nanocatalysts and commercially available Degussa P25 power under identical solar light exposure. N-doped TiO2 demonstrated superior photocatalytic activities in both chemical compound degradation and bactericidal reactions. The result of this study shows the potential of applying new generations of catalyst for wastewater purification and disinfection.