石灰石在煤气化过程中的催化和固硫作用

基于CaO在煤气化中的催化和固硫作用,以及石灰石加热分解的性质,石灰石有可能作为煤气化过程中的催化剂和固硫剂。本文根据国内外对石灰石在煤燃烧和煤气化中作用的研究,从石灰石结构、Ca/C,Ca/S,可能的反应机理等几个方面进行了介绍和分析,并指出需进一步研究的内容。     

Correlation of the reactivity,the active surface area and the total surface area of thin films of pyrolytic carbon

Using thin films of pyrolytic carbon the rate of the reaction with oxygen has been measured over the temperature range 625–740°C and at pressures of oxygen from 6–100 torr. The active surface area (ASA) of the films was measured from the total concentration of strongly-bound complexes with oxygen on the surface and the relative total surface area (TSA) was measured by low-temperature adsorption of nitrogen. A maximum in reactivity and in ASA was observed for films of average thickness of about 20 nm with a TSA of about 30 m² g^?1. At the maximum the ASA and TSA were essentially equal. The results are interpreted in terms of the mechanism of formation of pyrolytic carbon in the initial stages.     

纳米SiO2粉体的制备与研究

纳米SiO2粉体的制备是以硅酸钠和盐酸为原料，添加适宜的稳定剂(非离子表面活性剂)和分散剂，在适宜的pH值和温度下，采用化学沉淀法合成。研究表明，要得到性能优良纳米的SiO2粉体，最佳工艺条件为：温度20～40℃，pH=6，反应液质量浓度P1=20g／L，P2=1．20g／L，反应时间15min。结果表明：制备的纳米SiO2粒径30～50nm，比表面积大，分散性好，质量优良，可达到产业化的生产。     

HDPE新牌号树脂的研究

根据扬子石化公司开发HDPE新牌号产品的生产经验,从分子量及分子量分布与树脂性能的关系、密度对HDPE性能的影响、HDPE的共聚改性、HDPE的共混改性、添加剂与HDPE改性等5个方面讨论了HDPE新牌号产品开发的方法。     

火电厂发电机组常见的电气故障与维修研究

发动机组是火电厂各生产环节中重要的组成部分,其运行效率不但决定了生产效率,还关系着各类生产资源应用的有效性,对实现节能降耗具有重要意义,所以,必须加强对其运行稳定性的管理。分析了火电厂发动机组常见电气故障,并提出了相应的解决措施。     

数控系统伺服驱动优化方法

如何提高伺服驱动系统的动态特性和零件加工精度,是维修、调试人员必须掌握的一项工作.机床各轴的驱动、电机的数据,比如速度环、位置环的增益会直接影响轴的动态运行特性.如果这些参数设置不当,就可能出现机床振动、伺服电机啸叫等现象,使加工无法进行,甚至导致丝杆或导轨损坏.目前,数控机床配置的数控系统主要为日本的FANUC和德国的SIEMENS系统.以这2种系统为例,阐述了驱动参数的优化方法及其具有的实际意义.     

基于web的外贸企业资金流管理平台的设计

本文针对外贸型企业对外贸易服务流程中的资金流动和资金流管理中存在的问题,设计了一个基于Web的外贸企业资金流管理平台,实现跨地域、多角色、实时的资金流录入、统计和分析,使企业能够高效准确地管理业务和资金流,能够随时统计资金的流向以及分析盈利情况;着重论述外贸企业资金流管理需求、基于Web的系统框架设计、数据加密存储、加密传输、用户角色及权限控制等。     

The topological basis realization and the corresponding Heisenberg model of spin-1 chain

In this paper, it is shown that the Heisenberg model of spin-1 chain can be constructed from the Birman–Wenzl algebra generator while we have got that the Heisenberg model of spin- $\frac{1}{2}$ chain can be constructed from the Temperley–Lieb algebra generator in our previous work (Sun et al. in EPL 94:50001, 2011). Here, we investigate the topological space, we find that the number of topological basis states raise from the previous two to three, and they are also the three eigenstates of a closed four-qubit Heisenberg model of spin-1 chain. Specifically, all the topological basis states are also the spin single states and one of them is the energy single state of the system. It is worth noting that all conclusions we get in this paper are consistent with our previous work (Sun et al. in EPL 94:50001, 2011). These just indicate that the topological basis states have particular properties in the system.     

Direct equivalence between geometric conditions and algebraic conditions for discrete-time nonlinear observer

Unlike the continuous-time case, algebraic necessary and sufficient conditions for a single output discrete-time system to be state equivalent to a nonlinear observer canonical form have been found and are easier to verify for those who are not accustomed to differential geometry. The geometric conditions look very different from the algebraic conditions. In this paper, we show direct equivalence of the geometric conditions and the algebraic conditions in order to enhance the understanding of the geometric conditions.     

A model-based fault diagnosis scheme for wheeled mobile robots

In this paper, a fault diagnosis scheme for wheeled mobile robots is presented. In the fault detection module, a nonlinear observer is designed based on the mobile robot dynamic model. A fault is detected when at least one of the residuals exceeds its corresponding threshold. After the fault is detected, the fault isolation module is activated to isolate three types of fault: right wheel fault, left wheel fault, and other changing dynamic parameter faults. Three simulation examples are performed to show the effect of each fault to the tracking performance of mobile robot in a real situation. The simulation results demonstrate the effectiveness of our proposed approach for fault detection and isolation in wheeled mobile robots.