应用Casimir力实现真空"零点能"的利用研究

阐述了产生零点能及Casimir力的理论依据，对真空中的两平行平面等结构内的零点能及Casimir力进行了分析，并对一些影响因素进行了讨论，最后对应用Casimir力实现零点能利用的可行性进行了分析。     

Diamino telechelic polybutadienes for solventless styrene-butadiene-styrene (SBS) triblock copolymer formation

High molecular weight, high functionality diamino telechelic polybutadienes (TPBs) were synthesized by ring-opening metathesis polymerization (ROMP) of 1,5-cyclooctadiene (COD) in the presence of a chain transfer agent, 1,8-dicyano-4-octene, followed by lithium aluminum hydride reduction. Melt coupling of diamino TPB with anhydride-terminated polystyrene (PS-anh) resulted in the formation of styrene-butadiene-styrene (SBS) triblock copolymers; ca. 80% maximum conversion of PS-anh was achieved within 30 s. The results from SAXS, TEM, and rheological measurements of the coupling products confirmed the formation of SBS triblock copolymers having lamellar morphology. A fluorescent-labeled PS-anh was used to study the coupling kinetics by diluting the reactants by the addition of non-functional PS.     

Effects of tube rupture modeling and the parameters on the analysis of multiple steam generator tube rupture event progression in APR1400

A multiple steam generator tube rupture (MSGTR) event in APR1400 has been investigated using the best estimate thermal hydraulic system code, MARS1.4. The effects of the parameters such as the number of ruptured tubes, rupture location, affected steam generator on the analysis of the MSGTR event in APR1400 are examined. In particular, tube rupture modeling methods, single tube modeling (STM) and double tube modeling (DTM), are compared. The APR1400 is found to have the capability of allowing more than 30 min to operators for the MSGTR event of five tubes. The effects of rupture location on the MSSV lift time is not significant in the case of STM, but the MSSV lift time for tube-top rupture is found to be 25.3% larger than that for rupture at the hot-leg side tube sheet in the case of DTM. The MSSV lift time for the cases that both steam generators are affected (4C5x, 4C23x) are found to be larger than that of the single steam generator cases (4A5x, 4B5x) due to a bifurcation of the primary leak flow. The discharge coefficient of Cd is found to affect the MSSV lift time only for a smaller value of 0.5. It is found that the most dominant parameter governing the MSSV lift time is the leak flow rate. Whether any modeling method is used, it gives the similar MSSV lift time if the leak flow rate is close, except in the case where both steam generators are affected. Therefore, the system performance and the MSSV lift time of the APR1400 are strongly dependent on the break flow model used in the best estimate system code.     

DJG-1阳离子絮凝剂合成的影响因素

DJG-1阳离子絮凝剂的合成步骤为：玉米淀粉与丙烯酰胺在硝酸铈铵引发下接枝，得A；A与醇在酸催化下发生酯化反应得B；甲醛与二甲胺反应得N-羟甲基胺（C）；在C中加入酸使pH值为4左右。得酸性范围内的N-羟甲基胺（C′）。B与C′发生曼尼希反应得D（叔胺盐）；D发生烷基化反应E（季铵盐）；E与四苯硼钠反应生成白色沉淀。室内试验分析了DJG-1阳离子絮凝剂合成的影响因素。评价了DJG-1的水处理效果并与硫酸铝进行了对比。实验结果表明，DJG-1阳离子絮凝剂合成的影响因素包括引发剂的选用，活化时间，投料比，反应时间与温度及溶液pH值等。用DJG-1絮凝剂混凝处理钻井废水时，絮凝沉淀的速度比用硫酸铝处理时大得多，废水处理效率高，但DJG-1絮凝剂与硫酸铝复合使用经济效益更好，且硫酸铝用量为300mg/L时，DJG-1的最佳用量为3-4mg/L。     

Formation and surface modification of self-assembled films with acrylated hyperbranched poly(ester-amine) as the outmost layer

An acrylated hyperbranched poly(ester-amine) (HPEA) synthesized from piperazine and trimethylolpropanetriacrylate at a molar ratio of 1:1.42 was used as the polycation to form self-assembled films by layer-by-layer dipping with poly(sodium-p-styrenesulfonate) as the polyanion. The surface morphology and hydrophilicity of the films with HPEA as the outmost layer were controlled by adjusting the solution pH of HPEA. Due to the existence of many acrylate groups, the films with HPEA as the outmost layer were further reacted with a series of reagents, including piperazine, piperidine, laurylamine and p-phenylenediamine. The surface reactions of the films depended on both the nature of the reagents and the morphology of the initial surface. In the presence of the strong basic amines, piperazine and piperidine, the films dissolved extensively into the solution. In the case of laurylamine, a modified film with an opaque appearance was obtained due to the crystallization of long alkyl chains. With the weak basic amine p-phenylenediamine as the reactant, the film was effectively modified without any change in the surface morphology.     

High affinity hormone binding to the extracellular N-terminal exodomain of the follicle-stimulating hormone receptor is critically modulated by exoloop 3

The human follicle-stimulating hormone receptor (FSH-R) consists of two distinct domains of >330 amino acids, the N-terminal extracellular exodomain and membrane-associated endodomain. The exodomain alone binds hormone with high affinity, whereas the endodomain is the site of receptor activation. Coordination of these two domains is essential for successful hormone action but little is known about their functional and structural relationship. In this communication, we report that exoloop 3 of FSH-R constrains follicle-stimulating hormone binding to the exodomain. When the FSH-R exodomain was prepared by truncating its endodomain, the hormone binding affinity of the exodomain was slightly improved, compared with the wild type receptor. The binding affinity was further improved by >3-fold when the exodomain was attached to the membrane-associated domain of CD8. These results suggest that the FSH-R endodomain attenuates hormone binding at the exodomain. As a first step to test this hypothesis, the 11 amino acids except Ala589 of exoloop 3 were individually substituted with Ala. Ala substitution for Leu583 or Ile584 improved the hormone binding affinity by 4-6-fold while totally abolishing cAMP induction, indicating an inverse relationship. The Ala substitution for Lys580 or Pro582 had a similar trend but to a lesser extent. This significant improvement in the binding affinity suggests that the four residues at the N-terminal region of exoloop 3 interact with the exodomain and constrain the hormone binding in the wild type receptor. This effect is specific since substitutions for other than the 4 residues did not improve the hormone binding affinity. Computer modeling shows that the 4 residues can be positioned on one side of exoloop 3. This result and the apparent inverse relationship of hormone binding and cAMP induction suggest that these two essential functions may work against each other. Therefore, hormone binding might be compromised to preserve cAMP inducibility while maintaining a reasonably high, but below maximum, binding affinity.     

Java语言及其虚拟机技术探讨

随着Internet的迅猛发展，Internet编程语言Java愈来愈成为计算机行业的焦点。本文在简述了Java的主要特点后，重点对Java最关键的技术──虚拟机进行了深入的探讨。     

Mapping field density distribution in radiators by microwave noise

In his earlier paper on Active Microwave Radiometry, the author indicated that microwave noise can be used to map field density distribution inside radiators and in antenna systems, without the need for anechoic chambers. The presented paper gives details and results of such experiment. The method is described, details of equipment are given and results are presented with a concluding commentary.     

CH_4、CO_2与O_2制合成气的研究 Ⅱ工艺条件的影响

在固定床反应器中考察了１２％Ｎｉ－５％ＲＥ－２％Ｃｕ－２％Ｌｉ／Ａｌ２Ｏ３（ｍａｓｓ）催化剂在ＣＨ４、ＣＯ２与Ｏ２催化氧化重整制合成气反应中催化剂粒径、工艺操作条件（空速与温度）及原料气配比对反应的影响，确定了较佳的操作条件：催化剂粒径２０～４０目，反应最佳温度为８００℃，ＳＶ＝４×１０４ｍｌ／（ｇ·ｈ）。同时看到在不同的原料气配比的条件下该催化剂的活性亦很稳定，不仅达到了反应平衡，且产物Ｖ（ＣＯ）／Ｖ（Ｈ２）比有很强的调变性。     

对聚合物驱单井效果评价的几点认识

通过对喇嘛甸油田聚合物驱单井效果分析，给出了采油井阶段效果评价方法，即单井见效时间和含水回升时间早晚的确定方法，单井见效时间取决于油层条件，注聚前含油饱和度及累计采出地下体积倍数，单井含水回升时间主要取决于聚驱阶段剩余储量采出程度，根据单井阶段评价结果，对试验区进行跟踪调整，在单井阶段效果评价的基础上，对单井最终效果采用吨聚增油量和聚驱阶段剩余储量采收率来进行客观，有效的评价，对聚驱产量预测具有一定指导意义。