Adsorption of antifouling booster biocides on metal oxide nanoparticles: Effect of different metal oxides and solvents

Controlling the release rate of biocides (antifouling agents) from a paint coating is a key issue for the development of multi-season antifouling marine coatings. One promising approach is the use of nanoparticles onto which biocides are adsorbed to prevent premature depletion of the biocide. Adsorption of one novel (Medetomidine) and six commercially available and widely used antifouling biocides (Chlorothalonile, Dichlofluanid, Diuron, Irgarol, Seanine, Tolylfluanid) onto oxide nanoparticles (Al₂O₃, CuO, MgO, SiO₂, TiO₂, ZnO) was investigated by HPLC and NMR in different organic solvents. Large differences in adsorption strength depending on the type of nanoparticle and solvent employed were observed. It was shown that nanoparticles coordinate preferentially with the imidazole moiety of Medetomidine. Independent of the type of particle this interaction was considerably stronger in comparison to the other biocides. However, the interaction strength was strongly dependant on the type of solvent, where the largest strongest interaction was achieved in o-xylene. In addition field tests were performed where a considerable decrease in release rate was displayed from coatings containing Medetomidine adsorbed to nanoparticles compared to coatings containing Medetomidine as single additive.     

Film-forming capability in rough surface EHL investigated using contact resistance

Highly loaded machine elements such as gears and cams have a non-smooth surface topography that is created during manufacturing. It is well known that the film-building properties of such surfaces may be different from those that are perfectly smooth. The capability to form a separating film may also be altered in time due to run-in phenomena. In this study, a smooth steel ball was loaded against rough steel discs and run under pure rolling as well as sliding conditions. Several different steel surfaces were tested under nominal EHL conditions, where the contact was monitored by means of its electrical resistance and capacitance. Each surface was first run in for 15 min, followed by a sweep-in speed determining the lift-off curve. Electrical contact measurements were continuously conducted during run in as well as lift-off. Fully formulated gear oil and its base fluid were used as test lubricants. Results show that run in of a surface seems to be a competition between conformation of surface topography and tribofilm formation. At the tested conditions, the formation of a tribofilm is dependent on the initial surface topography and is created rapidly causing less metal–metal contact. This film also seems to effectively prohibit changes in surface topography causing less structural run in than expected.     

Location and co-location in retail: a probabilistic approach using geo-coded data for metropolitan retail markets

In this paper, we employ geo-coded data at a fine spatial resolution for Sweden’s metropolitan areas to assess retail co-location. Retail clusters and their place in urban space are assessed from several angles. The probability of a specific type of retail unit to be established in a 250 by 250 m square is modelled as a function of (i) the presence of other similar retail establishments, (ii) the presence of stores that belong to other retail sectors and (iii) other characteristics of the square area, and its access to demand in the pertinent urban landscape. The analysis clarifies which types of retail clusters one can expect to find in a metropolitan region, as well as their relationship to the urban landscape. We analyse three distinct types of stores: clothing, household appliances, and specialized stores. Stores with high intensities of interaction are co-located, and predominantly located close to the urban cores, consistent with predictions from bid rent theory and central place theory. We further document negative location tendencies between shops that sell frequently purchased products and shops that sell durables. Moreover, our results highlight the importance of demand in the close surroundings, which is particularly strong for small-scale establishments.     

Microstructural characterization and in vitro bioactivity of porous glass-ceramic scaffolds for bone regeneration by synchrotron radiation X-ray microtomography

One of the key purposes of bone tissue engineering is the development of new biomaterials that can stimulate the body's own regenerative mechanism for patient's anatomical and functional recovery. Bioactive glasses, due to their versatile properties, are excellent candidates to fabricate porous 3-D architectures for bone replacement. In this work, morphological and structural investigations are carried out on Bioglass^®- and CEL2-derived scaffolds produced by sponge replication (CEL2 is an experimental glass developed at Politecnico di Torino). Synchrotron radiation X-ray microtomography is used to study the samples 3-D architecture, pores size, shape, distribution and interconnectivity, as well as the growth kinetics on scaffolds struts of a newly formed apatitic phase during in vitro treatment in simulated body fluid, in order to describe from a quantitative viewpoint the bioactive potential of the analyzed biomaterials. An accurate comparison between architectural features and bioactive behaviour of Bioglass^®- and CEL2-derived scaffolds is presented and discussed.     

On the stability of delamination growth at scratching of thin film structures

Scratching of thin film/substrate structures is studied theoretically and numerically. The results are discussed in connection to delamination initiation and in particular subsequent growth at scratching. The material behavior of the film is described by classical elastoplasticity accounting for large deformations. The deformation of the substrate is neglected indicating that the results are pertinent to soft thin films. The numerical investigation is performed using the finite element method (FEM) and the numerical strategy is discussed in some detail. The results from this study show that delamination growth at thin film scratching is a stable feature with crack arrest occurring at a decreasing load.     

Bartlett Corrections for Unit Root Test Statistics

Bartlett corrections of the log likelihood ratio test for a unit root in an AR(1) process, as well as for some asymptotically equivalent tests, are studied. The corrections are obtained by an analytical method. The numerical performance of the results is checked in a simulation study.     

Pheromones and Other Semiochemicals for Monitoring Rare and Endangered Species

As global biodiversity declines, biodiversity and conservation have become ever more important research topics. Research in chemical ecology for conservation purposes has not adapted to address this need. During the last 10–15 years, only a few insect pheromones have been developed for biodiversity and conservation studies, including the identification and application of pheromones specifically for population monitoring. These investigations, supplemented with our knowledge from decades of studying pest insects, demonstrate that monitoring with pheromones and other semiochemicals can be applied widely for conservation of rare and threatened insects. Here, I summarize ongoing conservation research, and outline potential applications of chemical ecology and pheromone-based monitoring to studies of insect biodiversity and conservation research. Such applications include monitoring of insect population dynamics and distribution changes, including delineation of current ranges, the tracking of range expansions and contractions, and determination of their underlying causes. Sensitive and selective monitoring systems can further elucidate the importance of insect dispersal and landscape movements for conservation. Pheromone-based monitoring of indicator species will also be useful in identifying biodiversity hotspots, and in characterizing general changes in biodiversity in response to landscape, climatic, or other environmental changes.     

Islet amyloid polypeptide in patients with pancreatic cancer and diabetes

Population-based psychiatric admission rates vary across geographic areas, but reasons for this variation are unknown. Insofar as Community Mental Health Centers (CMHCs) provide outpatient services that may deter the need for hospitalization, the presence and structural characteristics of CMHCs may have an impact on a population's psychiatric admission rates. This study uses small area analysis to examine how general hospital psychiatric admission rates are associated with CMHC characteristics. Based on a survey of all CMHCs in Iowa and corresponding small area variation data, it was found that population admission rates were higher in areas closer to the CMHC and lower in outlying catchment areas, adjusting for age, sex, and urban/rural differences in populations. There was little evidence that differences in staffing and service variables influenced admission rates, although greater CMHC staff coverage by social workers and psychiatric residents was associated with lower admission rates. The results suggest that CMHCs do not lower an area's hospitalization rate, and in fact, the presence of CMHCs may promote a "supplier-induced demand" phenomenon of higher admissions.     

On computational homogenization of microscale crack propagation

The effective response of microstructures undergoing crack propagation is studied by homogenizing the response of statistical volume elements (SVEs). Because conventional boundary conditions (Dirichlet, Neumann and strong periodic) all are inaccurate when cracks intersect the SVE boundary, we herein use first order homogenization to compare the performance of these boundary conditions during the initial stage of crack propagation in the microstructure, prior to macroscopic localization. Using weakly periodic boundary conditions that lead to a mixed formulation with displacements and boundary tractions as unknowns, we can adapt the traction approximation to the problem at hand to obtain better convergence with increasing SVE size. In particular, we show that a piecewise constant traction approximation, which has previously been shown to be efficient for stationary cracks, is more efficient than the conventional boundary conditions in terms of convergence also when crack propagation occurs on the microscale. The performance of the method is demonstrated by examples involving grain boundary crack propagation modelled by conventional cohesive interface elements as well as crack propagation modelled by means of the extended finite element method in combination with the concept of material forces. © 2016 The Authors. International Journal for Numerical Methods in Engineering Published by John Wiley & Sons Ltd.     

On the influence of surface roughness on real area of contact in normal,dry, friction free,rough contact by using a neural network

A model previously developed at LTU was used in order to perform numerical simulations of normal, dry, friction free, linear elastic contact of rough surfaces. A variational approach was followed and the FFT-technique was used to speed up the numerical solution process. Five different steel surfaces were measured using a Wyko optical profilometer and several 2D profiles were taken. The real area of contact and the pressure distribution over the contact length were calculated for all the 2D profiles. A new slope parameter was defined. An artificial neural network was applied to determine the relationship between the roughness parameters and the real area of contact. The trained model was able to capture the dependence of the real area of contact on the roughness parameters. The ability of the neural network to generalize on unseen data was tested. The neural network was able to prove the correlation between the roughness parameters and the real area of contact.