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21.
Tribological Characteristics of SiC Ceramics in High-Temperature and High-Pressure Water 总被引:2,自引:0,他引:2
Satoshi Kitaoka Toshihide Tsuji Toshio Katoh Yoshimi Yamaguchi† Kazumi Kashiwagi 《Journal of the American Ceramic Society》1994,77(7):1851-1856
The effects of temperature and sliding speed on the tribological behavior of a SiC ceramic by sliding on the same material in deoxygenated water were investigated from room temperature to 300°C under the corresponding saturated vapor pressures. The friction coefficient and specific wear rates of both plates and disks increased at elevated temperatures at all sliding speeds, but decreased with increasing sliding speed at 120° and 300°C. Fine mirrorlike worn surfaces were observed without wear debris under all sliding conditions. The wear mechanism appears to consist of hydrothermal oxidation of SiC and dissolution of reaction products such as silica. 相似文献
22.
Hakoshima Toshio; Tanaka Masahiro; Itoh Takeshi; Tomita Ken-khi; Amisaki Takashi; Nishikawa Satoshi; Morioka Hiroshi; Uesugi Sei-ichi; Ohtsuka Eiko; Ikehara Morio 《Protein engineering, design & selection : PEDS》1991,4(7):793-799
Hydrophobic effects on binding of ribonuclease Tl to guaninebases of several ribonucleotides have been proved by mutatinga hydrophobic residue at the recognition site and by measuringthe effect on binding. Mutation of a hydrophobic surface residueto a more hydrophobic residue (Tyr45 Trp) enhances thebinding to ribonucleotides, including mononucleotide inhibitorand product, and a synthetic substrate-analog trinudeotide aswell as the binding to dinucleotide substrates and RNA. Enhancementson binding to non-substrate ribonucleotides by the mutationhave been observed with free energy changes ranging from 2.2 to 3 .9 kJ/mol. These changes are in good agreementwith that of substrate binding, 2.3 kJ/mol, which iscalculated from Michaelis constants obtained from kinetic studies.It is shown, by comparing the observed and calculated changesin binding free energy with differences in the observed transferfree energy changes of the amino acid side chains from organicsolvents to water, that the enhancement observed on guaninebinding comes from the difference in the hydrophobic effectsof the side chains of tyrosine and tryptophan. Furthermore,a linear relationship between nucleolytic activities and hydrophobicityof the residues (Ala, Phe, Tyr, Trp) at position 45 is observed.The mutation could not change substantially the base specificityof RNase Tl, which exhibits a prime requirement for guaninebases of substrates. 相似文献
23.
Pervaporation membranes for the ethanol–water mixture were prepared by plasma polymerization of tetrafluoroethylene, perfluoropropane, and perfluoropropylene onto porous substrates. The influence of the monomers on the elemental ratio (F/C) of the polymer depositions by X-ray photoelectron spectroscopy was rather small compared with that of the W/FM parameter (W = wattage for plasma excitation, FM = mass flow rate of a monomer). The optical emission spectroscopy indicated the similarity of gaseous species formed in the plasmas. The membranes were found ethanol-permselective, showing separation coefficients (αEtOH) around 4–7 and a wide range of permeation rates (J), 10–10?2 kg/m2 h, for the 4.8 wt % ethanol solution at 40°C. The αEtOH of the membranes with thicker depositions could be correlated to the F/C ratios as a measure of membrane hydrophobicity. It was thought that, by making a plot αEtOH against J values for the perfluorocarbon membranes, they could be classified into three groups on thickness of deposition. The ethanol-separation mechanisms for each group, which may contain four kinds of mass transfer schemes, i.e., distillation through larger pores, flow of sorption layer at the liquid–membrane interface, and diffusions through deposition or substrate, were also discussed. 相似文献
24.
Toshio Ogasawara Takashi Ishikawa Takashi Matsuzaki 《Journal of the American Ceramic Society》2003,86(5):830-837
The thermal response and oxidation of Tyranno™ Lox-M fiber-reinforced Si-Ti-C-O matrix composites in high-enthalpy dissociated air was investigated in an arc jet facility (an arc wind tunnel). The maximum surface temperature reached 1310–1670°C. Catalytic recombination of oxygen and nitrogen on the composite surface under dissociated air was not significant. Surface recession was insignificant below 1600°C surface temperatures and above 5 kPa of oxygen partial pressure at the stagnation point. Passive-to-active oxidation transition of the composite agreed with Balat's theory for monolithic silicon carbide. A glass sealant prevented active oxidation of the composite for short-time exposures. 相似文献
25.
Shigeji Taniguchi Toshio Shibata Naoyuki Asanuma Hanyi Lou Fuhui Wang Weitao Wu 《Oxidation of Metals》1993,39(5-6):457-473
The oxidation behavior of TiAl coupons coated with a fine-grain Co-30Cr-4Al (mass %) film of about 30-m thickness has been studied at 1100–1400 K in a flow of purified oxygen at atmospheric pressure for up to 500 ks. Three oxidation stages were recognized: initial transient, parabolic, and accelerated stages. However, at 1100 K a parabolic stage continues for more than 800 ks. The activation energy for parabolic oxidation agrees with reported values for the oxidation of alumina-former alloys, although the mass gains during the parabolic stages are relatively small at 1200 and 1300 K. Micropores developed mainly at the scale/coating and coating/substrate interfaces as oxidation proceeded. This is attributable to recrystallization of the coating during oxidation and a Kirkendall effect due to preferential diffusion of Co into the substrate. The accelerated oxidation can be explained in terms of the formation of rutile mounds on the scale. 相似文献
26.
The oxidation behavior of Ni and Ni-3, 6, and 10Al alloys at 800°C in an N2–O2 gas mixture was investigated. The mass gain of each alloy depended on both the oxidation periods and Al content. NiO scale was formed on all alloy substrates accompanied by internal oxides of Al2O3. Many cavities were formed at the NiO/substrate interface at shorter oxidation times, and these cavities were found to be filled by metallic Ni(Al) from the matrix in the internal-oxidation zone by the development of internal oxides. The filling of cavities by Ni(Al) was more significant on higher Al alloys, which had a higher density of internal Al2O3. Once metallic Ni(Al) formed along the entire NiO/substrate interface, the oxidation kinetics became the same as pure Ni. It was concluded that pure Ni filling the cavities at the interface provided a diffusion path of Ni from the substrate to the NiO scale, and that controlled the oxidation kinetics. 相似文献
27.
Gallium activity in the B2 phase regions of both binary Co–Ga and ternary Co–Ga–Sb systems was measured by EMF method with stabilized zirconia solid electrolyte The temperature range was 1073–1273 K and Sb concentrations were 1, 2 and 3 mol fractions. Ga activity at 1173 and 1273 K increases sharply in Ga rich region and the addition of Sb to the CoGa phase increases Ga activity. Activity change corresponds to the lattice parameter change with Sb addition to the CoGa phase. 相似文献
28.
Kenichi Yokoyama Toshio Ogawa Kenzo Asaoka Junichi Sakai 《Journal of Alloys and Compounds》2005,400(1-2):227-233
The hydrogen absorption properties of Ti–0.2 mass% Pd (Ti–0.2Pd) alloy in 2.0% and 0.2% acidulated phosphate fluoride (APF) and neutral 2.0% NaF solutions (25 °C) has been evaluated by hydrogen thermal desorption analysis. During the early stage of immersion (120 h) in the 2.0% APF solution, the amount of absorbed hydrogen was lower than 500 mass ppm. A thermal desorption of hydrogen primary appearing with a peak at 500–600 °C and a broad desorption ranging from 100 to 400 °C were observed. In the 0.2% APF solution, the amount of absorbed hydrogen saturated at 100–200 mass ppm; the thermal desorption of hydrogen appeared with a single peak at 550 °C. In the 2.0% NaF solution, hydrogen absorption was negligible even after 1000 h of immersion, although corrosion pits were observed. The results of the present study suggest that the hydrogen absorption of Ti–0.2Pd alloy, as compared with commercial pure titanium, is suppressed in fluoride solutions. 相似文献
29.
This study developed a coupled land-atmosphere satellite data assimilation system as a new physical downscaling approach, by coupling a mesoscale atmospheric model with a land data assimilation system (LDAS). The LDAS consists of a land surface scheme as the model operator, a radiative transfer model as the observation operator, and the simulated annealing method for minimizing the difference between the observed and simulated microwave brightness temperature. The atmospheric model produces forcing data for the LDAS, and the LDAS produces better initial surface conditions for the modelling system. This coupled system can take into account land surface heterogeneities through assimilating satellite data for a better precipitation prediction. To assess the effectiveness of the new system, 3-dimensional numerical experiments were carried out in a mesoscale area of the Tibetan Plateau during the wet monsoon season. The results show significant improvement compared with a no assimilation regional atmospheric model simply nested from the global model. The surface soil moisture content and its distribution from the assimilation system were more consistent to in situ observations. These better surface conditions affect the land-atmosphere interactions through convection systems and lead to better atmospheric predictability as confirmed by satellite-based cloud observations and in situ sounding observations. Through the use of satellite brightness temperature, the developed coupled land-atmosphere assimilation system has shown potential ability to provide better initial surface conditions and its inputs to the atmosphere and to improve physical downscaling through regional models. 相似文献
30.
A manufacturing XML schema definition and its application to a data management system on the shop floor 总被引:1,自引:0,他引:1
Digitization for sharing knowledge on the shop floor in the machinery industry has been given much attention recently. To help engineers use digitization practically and efficiently, this paper proposes a method based on manufacturing case data that has a direct relation to manufacturing operations. The data are represented in XML schema, as it can be easily applied to Web-based systems on the shop floor. The definitions were made for eight manufacturing methods including machining and welding. The derived definitions consist of four divisions of metadata, work-piece, process and evaluation. Three divisions except for the “process” division are common to the manufacturing methods. The average number of elements for a manufacturing method is about 200. The represented schema is also used to convey knowledge such as operation standards and manufacturing troubleshooting on the shop floor. Using the definitions, a data management system is developed. It is a Web-based Q&A system, in which the engineers specify the manufacturing case data mainly by selecting from the candidates. Then, the system fills in the blank portions and/or shows messages to help complete the case data. The proposed method is evaluated through practical scenarios of arc welding and machining. 相似文献