Use of recycled copper slag for blended cements

Copper slag is a by‐product generated during smelting to extract copper metal from the ore. The copper slag obtained may exhibit pozzolanic activity and may therefore be used in the manufacture of addition‐containing cements. In this paper the effect of the incorporation of the copper slag in cement is measured. Blends of copper slag with Portland cement generally possess properties equivalent to Portland cement containing fly ash, but very different to the silica fume incorporation. Copper slag and fly ash reduce the heat of hydration more effectively than silica fume in mortars. The replacement of 30% cement by copper slag reduces the flexural and compressive strength in a similar way to fly ash; however, after 28 days, the reduction is less than the percentage of substitution. Hydrated calcium aluminate phases were analysed using scanning electron microscopy (SEM) and X‐ray diffraction (XRD) techniques. The pozzolanic activity of copper slag is similar to that of fly ash and higher than silica fume. In the presence of low water/cement ratios, certain pozzolanic materials produce a very compact cement paste that limits the space available for hydration products, a determining factor in the formation of hydrated calcium aluminates. SEM was found to be a useful analytical technique when aluminates are formed and can be clearly detected by XRD. Copyright © 2008 Society of Chemical Industry     

Time Decay of the Activity of the Reduction Reaction of NO by CO on a Pd/Al2O3 Catalyst

An experimental study is made of the time decay of activity of the CO–NO reaction on a Pd/Al₂O₃ looking at the effect on reaction order and apparent activation energy. The optimum kinetics parameters fitting the steady state data at moderate pressures are determined. The time decay curves are analyzed through various catalyst deactivation models.     

Xylene Isomerization in a ZSM-5/SS Membrane Reactor

A membrane reactor containing different types of ZSM-5/porous SS membranes was used to perform the xylene isomerization reaction. The parent Na-ZSM-5 layer was synthesized by secondary growth on top of porous stainless steel tubes. The xylene isomerization reaction was carried out at different temperatures in the membrane reactor and in a fixed-bed reactor of identical geometry for comparison. Two different kinds of membranes were prepared by ion exchange: a Pt/H-ZSM-5 catalytic membrane and two Ba-ZSM-5 composites with different Ba²⁺ concentration. The p-xylene production using 100% exchanged Ba-membrane was about 28% higher than the fixed-bed reactor at 370 °C, when m-xylene was fed.     

Ultrasonic treatment restores the photoelectric parameters of silicon solar cells degraded under the action of <Superscript>60</Superscript>Co gamma radiation

The photoelectric parameters of silicon solar cells degraded under the action of ⁶⁰Co gamma-radiation can be partly restored using an ultrasonic treatment (UST). The growth of the maximum output power of solar cells after the UST is related to a redistribution of the radiation defects and an increase in the homogeneity of a semiconductor crystal structure.     

Integrating trust into the CyberCraft Initiative via the Trust Vectors model [Application Notes]

This research supports the hypothesis that the Trust Vector model can be modified to fit the CyberCraft Initiative, and that there are limits to the utility of historical data. This research proposed some modifications and expansions to the Trust Model Vector, and identified areas for future research.     

Translating a typical business process modelling language to a web services ontology through lightweight mapping

Bridging the gap between enterprise modelling methods and Semantic Web services is an important yet challenging task. For organisations with business goals, the automation of business processes as Web services is increasingly important, especially with many business transactions taking place within the Web today. Taking one approach to address this problem, a lightweight mapping between Fundamental Business Process Modelling Language (FBPML) and the Web Services Ontology (OWL-S) is outlined. The framework entails a data model translation and a process model translation via the use of ontologies and mapping principles. Several working examples of the process model translations are presented together with the implementation of an automated translator. FBPML constructs and process models that could not be translated to OWL-S equivalents highlight the differences between the languages of the two domains. It also implies that evolving Semantic Web technologies, in particular OWL-S, are not adequate for all service modelling needs and could thus benefit from the more traditional and mature BPM methods. On a more interesting note, this is effectively the first step towards enabling a semantic-based business workflow system     

QoS assessment of 3G video-phone calls by tracing watermarking exploiting the new colour space `YST?

Tracing watermarking has been recently proposed as a technique to provide a blind measure of the quality of service of the communication link, focusing on multimedia communication scenarios. 3G communication scenarios, where each customer transmits both voice and MPEG-4 video sequences in real time, have been considered. Typical video-phone call consists of close shots of speakers, framing their face in the foreground. For such particular application, a novel colour space (YST) is adopted to minimise the perceptual distortions on face coding introduced by watermarking. In the YST space, the luminance component (Y) is the same as in conventional YUV space, whereas the vectors S and T lie within the chrominance (UV) plane. The S (skin) component is a linear combination of U and V obtained as the 'average' chrominance estimated from an assorted set human faces to achieve a reasonable generalisation. The third component, T, is defined as orthogonal to the YS plane. The results show the benefits obtained in digital watermarking by the new representation against the conventional approach. In fact, the sensitivity of the YST representation outperforms the conventional one in terms of objective (mean square error, peak signal-to-noise ratio) and subjective (video-quality metrics) indicators.     

Shooter localization in urban terrain

Detecting and accurately locating snipers has been an elusive goal of the armed forces and law enforcement agencies for a long time. Most successful sniper-detecting systems are based on acoustic measurements. We develop an acoustic system that works well even in complex urban environments. Funded through the Network Embedded Systems Technology program of the US Defense Advanced Research Projects Agency's Information Exploitation Office, the PinPtr system uses a wireless network of many low-cost sensors to determine both a shooter's location and the bullet's trajectory by measuring both the muzzle blast and the shock wave. The PinPtr sensor-fusion algorithm, which runs on a base station, performs a search on a hyper-surface defined by a consistency function. This function provides the number of sensor measurements that are consistent with hypothetical shooter positions and shot times. The algorithm automatically classifies measurements and eliminates those that result from multipath effects or are otherwise erroneous. A fast search algorithm finds the global maximum of the surface, which corresponds to the shooter position.     

A moving horizon approach to Networked Control system design

This paper presents a control system design strategy for multivariable plants where the controller, sensors and actuators are connected via a digital, data-rate limited, communications channel. In order to minimize bandwidth utilization, a communication constraint is imposed which restricts all transmitted data to belong to a finite set and only permits one plant to be addressed at a time. We emphasize implementation issues and employ moving horizon techniques to deal with both control and measurement quantization issues. We illustrate the methodology by simulations and a laboratory-based pilot-scale study.