Physico-mechanical,rheological and gas barrier properties of organoclay and inorganic phyllosilicate reinforced thermoplastic films

Insertion of 2:1 organo-modified phyllosilicate tactoids into rheologically tough thermoplastics has extraordinary potential candidate in oxygen permeability and microstructural toughening. Herein, two commercially abundant clays have been taken for improvement of the thermoplastic's gas barrier property in reasonably low loading. The cause of low loading has been accounted to the usage of maleated polyethylene (MA-g-PE) during the melt mixing tenure. The optimized nanocomposite compression molded film has been tested against uniaxial stretching, which showed a negligible change in the residual permanent set with sacrificing the elongation at break feature. Moreover, nanoindentation was also performed to get the hardness of the sample surface. The flow behavior of the nanocomposites showed thixotropic likely with increasing the frequency. Oxygen transmission rate (OTR) has significantly decreased for tallow amine-modified nanoclay system (cloisite 15A) in comparison to cloisite Na⁺ providing 'tortoise path' formation inside the matrix. Thus, hitherto, the work could demonstrate and provide the information of comparative studies between organo-clay and simple phyllosilicates, which could be remediation of the loopholes in mechanical toughening and gas barrier lineaments.     

A Library of Thiazolidin-4-one Derivatives as Protein Tyrosine Phosphatase 1B (PTP1B) Inhibitors: An Attempt To Discover Novel Antidiabetic Agents

Protein tyrosine phosphatase 1B (PTP1B) is an important target for the treatment of diabetes. A series of thiazolidin-4-one derivatives 8 – 22 was designed, synthesized and investigated as PTP1B inhibitors. The new molecules inhibited PTP1B with IC₅₀ values in the micromolar range. 5-(Furan-2-ylmethylene)-2-(4-nitrophenylimino)thiazolidin-4-one ( 17 ) exhibited potency with a competitive type of enzyme inhibition. structure–activity relationship studies revealed various structural facets important for the potency of these analogues. The findings revealed a requirement for a nitro group-including hydrophobic heteroaryl ring for PTP1B inhibition. Molecular docking studies afforded good correlation with experimental results. H-bonding and π–π interactions were responsible for optimal binding and effective stabilization of virtual protein-ligand complexes. Furthermore, in-silico pharmacokinetic properties of test compounds predicted their drug-like characteristics for potential oral use as antidiabetic agents.Additionally, a binding site model demonstrating crucial pharmacophoric characteristics influencing potency and binding affinity of inhibitors has been proposed, which can be employed in the design of future potential PTP1B inhibitors.     

Bioinspired Electrically Activated Soft Bistable Actuators

Movement and morphing in biological systems provide insights into the materials and mechanisms that may enable the development of advanced engineering structures. The nastic motion of plants in response to environmental stimuli, e.g., the rapid closure of the Venus flytrap's leaves, utilizes snap‐through instabilities originating from anisotropic deformation of plant tissues. In contrast, ballistic tongue projection of chameleon is attributed to direct mechanical energy transformation by stretching elastic tissues in advance of rapid projection to achieve higher speed and power output. Here, a bioinspired trilayered bistable all‐polymer laminate containing dielectric elastomers (DEs) is reported, which double as both structural and active materials. It is demonstrated that the prestress and laminating strategy induces tunable bistability, while the electromechanical response of the DE film enables reversible shape transition and morphing. Electrical actuation of bistable structures obviates the need for continuous application of electric field to sustain their transformed state. The experimental results are qualitatively consistent with our theoretical analyses of prestrain‐dependent shape and bistability.     

A Chicken Tissue Phantom for Studying an Electrical Impedance Tomography (EIT) System Suitable for Clinical Imaging

The study of practical phantoms is essential for assessing the reconstruction algorithms and instrumentation used in Electrical Impedance Tomography (EIT). Responses of saline phantoms with insulator inhomogeneities differ from the real tissue phantoms in several aspects. Also, it is difficult to reconstruct the actual resistivity of the insulator inhomogeneity in a saline background because of their large resistivity difference. A practical biological phantom consisting of two different materials with low resistivity difference is more suitable for impedance imaging studies. In order to demonstrate this, a chicken tissue phantom was developed to study the resistivity imaging in EIT. A 16-electrode array was placed inside the phantom tank filled with chicken muscle tissue paste and chicken tissue. A 1 mA, 50 kHz sinusoidal current was injected at the phantom boundary and the boundary potentials are measured using opposite current injection protocol. Resistivity images were reconstructed from the boundary data using Electrical Impedance and Diffuse Optical Reconstruction Software (EIDORS) and the reconstruction was evaluated by calculating the contrast parameters of the images. Results show that the resistivity of the chicken fat is successfully reconstructed with a proper background resistivity. Impedance spectroscopic studies show that the chicken tissue phantom can be suitably used to evaluate a multifrequency EIT system.     

Development and Integration of a Data Acquisition System for SST-1 Phase-1 Plasma Diagnostics

Long pulse(of the order of 1000 s or more) SST-1 tokamak experiments demand a data acquisition system that is capable of acquiring data from various diagnostics channels without losing useful data(and hence physics information) while avoiding unnecessary generation of a large volume data.SST-1 Phase-1 tokamak operation has been envisaged with data acquisition of several essential diagnostics channels.These channels demand data acquisition at a sampling rate ranging from 1 kilo samples per second(KSPS) to 1 mega samples per second(MSPS).Considering the technical characteristics and requirements of the diagnostics,a data acquisition system based on PXI and CAMAC has been developed for SST-1 plasma diagnostics.Both these data acquisition systems are scalable.Present data acquisition needs involving slow plasma diagnostics are catered by the PXI based data acquisition system.On the other hand,CAMAC data acquisition hardware meets all requirements of the SST-1 Phase-1 fast plasma diagnostics channels.A graphical user interface for both data acquisition systems(PXI and CAMAC) has been developed using LabVIEW application development software.The collected data on the local hard disk are directly streaming to the central server through a dedicated network for post-shot data analysis.This paper describes the development and integration of the data acquisition system for SST-1 Phase-1 plasma diagnostics.The integrated testing of the developed data acquisition system has been performed using SST-1 central control and diagnostics signal conditioning units.In the absence of plasma shots,the integrated testing of the data acquisition system for the initial diagnostics of SST-1 Phase-1 operation has been performed with simulated physical signals.The primary engineering objective of this integrated testing is to validate the performance of the developed data acquisition system under simulated conditions close to that of actual tokamak operation.The data acquisition is synchronized with a clock and trigger provided by the central timing system.     

How the monomer concentration of polymerization influences various properties of polybenzimidazole: A case study with poly(4,4′‐diphenylether‐5,5′‐bibenzimidazole)

In this work, a series of poly(4,4′‐diphenylether‐5,5′‐bibenzimidazole)s (OPBIs) were synthesized from 4,4′‐oxybis(benzoic acid) and 3,3′,4,4′‐tetraaminobiphenyl through the variation of the initial monomer concentration with a solution polycondensation technique in a poly(phosphoric acid) medium. The resulting polymers were characterized by various techniques such as infrared (IR), nuclear magnetic resonance, dynamic mechanical analysis (DMA), and thermogravimetric analysis. The initial monomer concentration in the polymerization mixture played an important role in controlling the molecular weight of the resulting polymers. A temperature‐dependent IR study showed that the free movement of the ? NH group of the imidazole ring was blocked by the absorbed moisture. The DMA study showed that the glass‐transition temperature (T_g) varied with the molecular weight, and the presence of the ether linkage in the OPBI polymer backbone had a significant influence on T_g. A high‐molecular‐weight OPBI polymer tended to form a supramolecular organization, which influenced the thermal characteristic of the polymer. Photophysical studies demonstrated the fluorescent characteristics of the OPBI polymers in both solid and solution states. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2009     

Unraveling heavy oil desulfurization chemistry: targeting clean fuels

The sulfur removal chemistry of heavy oils has been unraveled by systematically investigating several heavy oils with an extremely wide range of properties. The heavy oil feed and product properties have been characterized by advanced analytical methods, and these properties have been related to the sulfur conversion data observed in pilot hydrotreating units. These studies coupled with kinetic treatment of the data have revealed that the desulfurization chemistry of heavy oils is essentially controlled by the strongly inhibiting three and larger ring aromatic hydrocarbon content and surprisingly not by the content of the "hard-to-remove" sulfur compounds. Such enhanced understanding of the heavy oil sulfur removal is expected to open new avenues for catalyst/process optimization for heavy oil desulfurization and thereby assist the efficent production of clean transporation fuels.     

Nonlinear Decentralized Feedback Linearizing Controller Design for Islanded DC Microgrids

This paper aims to design decentralized controllers for different components in islanded DC microgrids. The major components in the DC microgrid as considered in this paper include a fuel cell, solar photovoltaic (PV) unit, and battery energy storage system (BESS) along with critical and non-critical loads. The main control objective is to maintain the power balance within the DC microgrid through the regulation of the common DC-bus voltage. The controllers are designed based on the dynamical models of the fuel cell, solar PV unit, and BESS. The feedback linearization technique is employed to obtain the control laws, which simplifies the original dynamical models and decouples different components in the form of several subsystems. In this way, the feedback linearization technique allows different components in DC microgrids to achieve the desired control objectives by using only the local information (i.e., in a decentralized manner). The performance of the proposed decentralized controllers for different components is evaluated on a test DC microgrid under different operating conditions. Simulation results demonstrate that the proposed control scheme performs in a much better way as compared to an existing proportional integral controller.