City energy management through underground storage

This paper traces the historical development of the energy infrastructure of cities. As a result of 150 years of this infrastructure mainly comprises electricity, gas, and, sometimes, district heating. This paper describes basic characteristics of underground storage systems applicable within city limits: gas storage, compressed air energy storage, and thermal storage. Finally, the paper describes a central storage facility for all energy forms that has the potential to provide much of the flexibility required for optimal city energy management.     

Effects of perimortem stress on farmed Atlantic cod product quality: a baseline study

The potential effects of handling stress on the product quality of farmed Atlantic cod were studied in a controlled experiment (fish anesthetized with metomidate or isoeugenol, or subjected to stress by chasing for 30 min). For comparison, stress and fillet quality was also studied for commercially slaughtered farmed cod (fish sampled from waiting cage, after pumping and stunning with carbon dioxide, and after bleeding and chilling). Baseline values for stress-related parameters (blood chemistry, muscle high-energy phosphates and inosine monophospate, initial pH, muscle twitches, and rigor mortis) of rested Atlantic cod have been established. Since our stress bout showed that this species was not easily excitable, we were less convinced that we actually did study the other extreme, namely, exhausted fish. Nevertheless, the present data from the commercial slaughter of cod suggested that our stress bout was of adequate magnitude to represent potential poor handling routines. Our results consistently showed largely no differences between treatments, and that perimortem handling stress did not cause inferior flesh quality. This suggested that farmed cod can be processed with little risk of reducing product quality (quality index, fillet water content, water-holding capacity, ultimate pH, adenosine triphosphate-related degradation products and K-value, skin and fillet color, water and salt-soluble proteins, hardness, and gaping). For better maintenance of skin appearance after storage, the importance of storing the gutted cod on the belly, avoiding direct contact between skin and crushed ice, is demonstrated.     

Synthesis of active carbon-based catalysts by chemical vapor infiltration for nitrogen oxide conversion

Direct reduction of nitrogen oxides is still a challenge. Strong efforts have been made in developing noble and transition metal catalysts on microporous support materials such as active carbons or zeolites. However, the required activation energy and low conversion rates still limit its breakthrough. Furthermore, infiltration of such microporous matrix materials is commonly performed by wet chemistry routes. Deep infiltration and homogeneous precursor distribution are often challenging due to precursor viscosity or electrostatic shielding and may be inhibited by pore clogging. Gas phase infiltration, as an alternative, can resolve viscosity issues and may contribute to homogeneous infiltration of precursors. In the present work new catalysts based on active carbon substrates were synthesized via chemical vapor infiltration. Iron oxide nano clusters were deposited in the microporous matrix material. Detailed investigation of produced catalysts included nitrogen oxide adsorption, X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray spectroscopy. Catalytic activity was studied in a recycle flow reactor by time-resolved mass spectrometry at a temperature of 423 K. The infiltrated active carbons showed very homogeneous deposition of iron oxide nano clusters in the range of below 12 to 19 nm, depending on the amount of infiltrated precursor. The specific surface area was not excessively reduced, nor was the pore size distribution changed compared to the original substrate. Catalytic nitrogen oxides conversion was detected at temperatures as low as 423 K.     

Broadband Omnidirectional Diversion of Light in Hybrid Plasmonic‐Photonic Heterocrystals

Broadband, omnidirectional, and polarization‐independent diversion has been achieved of more than 90% of the light flow intensity off its incidence direction using hybrid metal–dielectric plasmonic‐photonic heterocrystals. These architectures were prepared by depositing metal film on the interface between two photonic crystals of different parameters. The magnitude of light losses was extracted from angle‐resolved measurements of transmission and reflectance spectra. Comparing these data for different stages of constructing the complex architecture, the diffraction in colloidal crystals, the excitation and radiative decay of short‐living surface plasmon polaritons in a corrugated metal film and the eigenmode mismatch at the interface between two different photonic crystals were identified as corroborating physical mechanisms behind the light diversion.     

40 Jahre industrielles Magnetron‐Sputtern in Europa

40 Years of Industrial Magnetron Sputtering In October 1974, the first magnetron discharge assisted by a ring gap magnet was carried out successfully at the former Manfred von Ardenne Research Institute (IvA). Similar developments were made in several countries in Europe and the US at that time. Inspired by the 40th anniversary, this article provides a brief survey of the history of magnetron sputtering and the driving factors behind the development of the sputtering technique into a reliable industrial process. Even if this development was also influenced by a major success in the US, the author focuses chiefly on developments in Europe. It also illustrates the progress of magnetron sputtering technology from small circular sputtering sources to industrially proven tools for large‐area coating solutions.     

Die Modellierung von Stofftransportprozessen in Mehrphasenströmungen – am Beispiel des Strahlzonen‐Schlaufenreaktors

The efficiency and selectivity of chemical reactions are influenced by the mixing characteristics of the reactor. Existing models often assume homogeneous mixing on micro scale to calculate the reaction yield. However, neglecting the local hydrodynamic phenomena causes a discrepancy between model calculation and experimental data especially considering mass transfer limited reactions. In two‐phase flows different mass transfer phenomena have to be considered: the diffusion in the gas‐liquid boundary layer and diffusion in the Batchelor layer. The aim of the paper is to describe the mass transfer affecting mechanisms in multi‐phase flows and to discuss the first results of the investigation of local mass transfer phenomena in a two phase flow driven jet‐zone loop reactor.     

Variationally-based theories for buckling of partial composite beam-columns including shear and axial effects

This paper is focused on elastic stability problems of partial composite columns: the conditions for the axial load not to introduce any pre-bending effects in composite columns; the equivalence, similarities and differences between different sandwich and partial composite beam theories with and without the effect of shear, with and without the effect of axial extensibility, and also the effect of eccentric axial load application. The basic modelling of the composite beam-column uses the Euler-Bernoulli beam theory and a linear constitutive law for the slip. In the analysis of this reference model, a variational formulation is used in order to derive relevant boundary conditions. The specific loading associated with no pre-bending effects before buckling is geometrically characterized, leading to analytical buckling loads of the partial composite column. The equivalence between the Hoff theory for sandwich beam-columns, the composite action theory for beam-columns with interlayer slip and the corresponding Bickford-Reddy theory, is shown from the stability point of view. Special loading configurations including eccentric axial load applications and axial loading only on one of the sub-elements of the composite beam-column are investigated and the similarity of the behaviour to that of imperfect ordinary beam-columns is demonstrated. The effect of axial extensibility on kinematical relationships (according to the Reissner theory), is analytically quantified and compared to the classical solution of the problem. Finally, the effect of incorporating shear in the analysis of composite members using the Timoshenko theory is evaluated. By using a variational formulation, the buckling behaviour of partial composite columns is analysed with respect to both the Engesser and the Haringx theory. A simplified uniform shear theory (assuming equal shear deformations in each sub-element) for the partial composite beam-column is first presented, and then a refined differential shear theory (assuming individual shear deformations in each sub-element) is evaluated. The paper concludes with a discussion on this shear effect, the differences between the shear theories presented and when the shear effect can be neglected.