Municipal solid waste conversion to energy

In recent years it has been recognised by an increasing number of nations that there is considerable energy potential within MSW. As a result many countries have established R,D& D programmes to examine methods of exploiting this potential. The IEA's MSW Conversion Activity was set up in 1986 to provide an infrastructure for sharing information and co-ordinating work in this area internationally. This Activity was extended in 1989 and currently a total of 9 nations participate in it.

To cope with the wide scope of the area (encompassing both biological and thermal processing of MSW) the Activity was divided into three subgroups or Expert Working Groups (EWGs). Each of these dealt with a distinct area of expertise:

1. •Downstream effects of source separation and screening of MSW

2. •Sampling and analytical protocols

3. •Landfill gas

In addition to these groups a central secretariat based at Harwell (UK) has provided guidance, established and administered databases of contacts and produced a series of national reports.

This paper describes the achievements of the Activity and discusses work proposed for the future.     

DETERMINATION of the MIXING INDEX of PADDY GRAINS UNDER VIBRATING CONDITIONS

Mixing of ingredients is an important operation in processing of food for obtaining the better quality product. A laboratory set‐up capable of modulating both frequency and amplitude of vibration of the grain bed was used to determine the mixing indices of paddy grains under varied experimental conditions. the mixing indices of three different types of paddy grain for three different grain bed depths were determined. the parameters varied were the vibration amplitude, frequency and the mixing time, respectively from 2 to 10 mm, 10 to 50 Hz and 5 to 120 s. Three varieties of paddy (short bold, medium slender and long slender) were used in the experiments with different length‐breadth ratio (slenderness ratio, μ, of 5.77, 4.48 and 2.70). Response surface methodology was adopted to optimize the amplitude and frequency of vibration of the mixing device. the results revealed that, the optimum frequency and amplitude of vibration for the medium slender (μ= 4.48) variety of paddy were 20–22 Hz and 8–9 mm, respectively for all the three grain bed depths of 25, 12 and 6 mm. Irrespective of grain bed depth, all the three different types of paddy showed maximum mixing indices value after 1 min of mixing. Extending the mixing time did not have any effect on mixing indices. the effect of bed depth was found to be insignificant for short bold variety of paddy.     

Effect of precyclic loading on stress-corrosion-cracking initiation in an X-65 pipeline steel exposed to near-neutral pH soil environment

A study was carried out to understand the effect of precyclic loading on stress-corrosion-crack initiation in an X-65 pipeline steel exposed to a near-neutral-pH soil environment. The test specimens were precyclically loaded before corrosion exposure to represent a service history of up to about 20 years, depending on the severity of pressure fluctuation. Microcracks had initiated on the polished surface of the X-65 pipeline steel after long-time exposure at open-circuit potential (OCP) in a near-neutral-pH synthetic soil solution. These microcracks were mostly initiated from pits at metallurgical discontinuities such as grain boundaries, pearlitic colonies, and banded phases in the steel. Strong preferential dissolution was observed along planes of the banded structures in the steel. The selective corrosion attack at these metallurgical discontinuities is attributed to the galvanic nature of those areas to their neighbors. Cyclic loading prior to corrosion exposure had significant effects on microcrack initiation and propagation during subsequent corrosion exposure. Cyclic loading prior to corrosion exposure either reduced or increased the probability of crack initiation and the rate of crack propagation, depending upon the magnitude of the stress cycles. The largest reduction was seen at a peak cyclic stress of about 0.8 of the yield strength. This cyclic-loading-dependent cracking behavior might be related to the alteration of the substructures and the residual stress in the steel as a result of precyclic loading.     

Theoretical investigation of penetration characteristics in gas metal-arc welding using finite element method

In the modeling of the gas metal-arc (GMA) welding process, heat inputs to the workpiece by the arc and the metal transfers have been considered separately. The heat energy delivered due to the metal transfer has been approximated in the form of a cylindrical volumetric heat source, whose dimensions of the radius and the height are dependent on the molten metal droplet characteristics. The pinch instability theory (PIT) and the static force balance theory (SFBT) of drop detachment have independently been used to obtain the expressions for various characteristics of the drop,i.e., the drop radius, the drop velocity, and the drop frequency at various welding parameters. The occurrence or the nonoccurrence of finger penetration, routinely found in the GMA welding at high welding currents, has been satisfactorily explained by the cylindrical heat source model. The effect of various welding parameters,e.g., the welding current, the wire radiusetc., on the weld bead penetration characteristics has been investigated. In this modeling effort, the heat conduction equation has been solved in three dimensions.     

Chelated alkoxyalumoxanes and a silica-free binder based on them

Chelated alkoxyalumoxane oligomers have been synthesized through consecutive hydrolysis and alcoholysis of organoaluminum compounds stabilized by compounds capable of keto-enol tautomerism. The chelated alkoxyalumoxanes were used to prepare a silica-free binder for the fabrication of heat-resistant (up to 2050°C), chemically inert corundum ceramic composites. The likely structures of the synthesized preceramic alumoxane oligomers were inferred from physicochemical characterization results (¹H, ¹³C, and ²⁷Al NMR, IR spectroscopy, mass spectrometry, gel-permeation chromatography, thermal analysis, and elemental analysis).     

Powder Deposition in Three Parallel-Oriented Dies of Different Shapes

Uniformity of bulk density distribution during the die filling process is required to minimize quality problems, such as distortion and cracking, for powder compacts. Understanding the die filling process is necessary in ensuring a uniform powder deposition. The second-generation pressure deposition tester (PDT-II) was used to investigate the deposition process and final pressure distribution of powder filling in toroidal, cylindrical, and E-shaped dies. All tests were conducted using a spray-dried free-flowing granular powder. The results indicated that for toroidal dies: (1) the area around 0° orientation (the leeward end) had the highest pressure values (1186.7 to 2498.0 Pa), with the average pressure values of the remaining area 353.7-648.0 Pa; (2) the pressure distribution was symmetrical about the centerline parallel to the feed shoe movement direction; (3) the highest feed shoe speed (500 mm/s) led to the most nonuniform pressure distribution among the three speeds; (4) higher feed shoe speed did not always result in higher final pressure values; and (5) the right die tended to have higher final pressure values (215.0 to 2498.0 Pa) than the center die (95.4 to 2052.5 Pa). For E-shaped dies: (1) the final pressure values of the middle leg (308.9 to 760.7 Pa) were higher than those of the left and the right legs (148.9 to 530.3 Pa); (2) the area along the backside had the highest final pressure value (1054.6 to 1303.8 Pa); (3) the pressure distribution was symmetrical about the centerline parallel to the feed shoe movement direction; and (4) neither the center die nor the right die always had higher pressure values than the other one at all locations. Comparison between cylindrical and toroidal dies indicated that: (1) neither of the two die shapes (cylinder and toroid) led to consistently higher or lower final pressure values at all locations and (2) for all three feed shoe speeds, the toroidal die had higher average final pressure values in the 0° orientation.     

Electrophysical Characteristics of a Posistor Block

The influence of the parameters of posistor elements and the conditions of their heat exchange on the electrical and dynamic characteristics of a posistor block have been investigated. Good agreement between calculation results and experimental data has been established.