Photodecomposition du bioxyde de chlore et des ions chlorite par irradiation u.v. en milieu aqueux-partie II. Etude cinetique

The decomposition of ClO₂ and ClO₂⁻ by u.v. radiation leads to the production of chlorate, chloride and oxygen as end-products via complex reactions which are initiated by the products generated by the primary reactions of photolysis (Buxton and Subhani, 1972a; Mialocq et al., 1973; Karpel Vel Leitner et al., 1992). As far as the rate of decomposition is concerned, Bowen and Cheung (1932) and Zika et al. (1985) have shown that the quantum yield of photodecomposition of chlorine dioxide (overall reaction) increases when the wavelength decreases [Zika et al. (1985): φ = 0.46 at 366 nm and 1.4 at 296.7 nm]. However, the values of the quantum yield of photodecomposition of ClO₂ and ClO₂⁻ at 253.7 nm as well as the quantum yields for the primary reactions of photolysis of ClO₂ and ClO₂⁻ at different wavelengths are not given in the literature.The aim of this work was to study the kinetics of photodecomposition of chlorine dioxide and of chlorite by u.v. irradiation.     

Radon concentration in houses over a closed Hungarian uranium mine

High radon concentration (average 410 kBq m-3) has been measured in a tunnel of a uranium mine, located 15-55 m below the village of Kovágószolos, Hungary. The mine was closed in 1997; the artificial ventilation of the tunnel was then terminated and recultivation works begun. In this paper, a study has been made as to whether the tunnel has an influence on the radon concentration of surface dwellings over the mining tunnel. At different distances from the surface projection of the mining tunnel, radon concentration, the gamma dose, radon exhalation and radon concentration of soil gas were measured. The average radon concentration in the dwellings was 483 Bq m-3. Significantly higher radon concentrations (average 667 Bq m-3) were measured in houses within +/-150 m from the surface projection of the mining tunnel +50 m, compared with the houses further than the 300-m belt (average 291 Bq m-3). The average radon concentration of the soil gas was 88.8 kBq m-3, the average radon exhalation was 71.4 Bq m-2 s-1 and higher values were measured over the passage as well. Frequent fissures crossing the passage and running up to the surface and the high radon concentration generated in the passage (average 410 kBq m-3) may influence the radon concentration of the houses over the mining tunnel.     

Analysis and jointing of polygonal road slabs

Conclusions 1. For anlaysis of circular (polygona) slabs which can be included in the category of absolutely rigid slabs, a practical approximate method of analysis has been developed and experimentally verified which permits determining the bending moments under centrally and eccentrically applied loads acting over a small circular area, as well as at any other points in the slab beyond the limits of the loaded area.2. Monolithic bonding of hexagonal road slabs up to 3–4 m² in area designed for the N-30 load results in increased design bending moments and, consequently, in thicker pavements. For these slabs it is expedient to use nonrigid joints, which do not transmit bending or torsional moments; however, these slabs must be placed on stabilized beds and their joints must be filled with waterproofing mastic.Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 5, pp. 19–22, September–October, 1974.     

The relative influence of wind,sunlight and temperature on user comfort in urban outdoor spaces

This paper presents the development of a comfort index that measures adaptivity in outdoor spaces. Over a 9-month period 649 people were surveyed in three locations, in temperatures between 10 and 28 °C. An exploratory factor analysis develops a 15-item scale of comfort that includes measures of adaptivity: clothing, exposure time and seating location. The scale is regressed on physical measures: average instantaneous wind speed; maximum wind speed; mean-exposed radiant temperature; mean-shaded radiant temperature and ambient temperature. The results model the relative contributions of the microclimatic factors for the comfort in the outdoor space. Analyses suggest gustiness and wind speed are most important in determining user satisfaction. There is strong support for the theory that people actively adapt to microclimatic conditions.     

Features of disinfection kinetics of water containing <Emphasis Type="Italic">Escherichia Coli</Emphasis> in conditions of hydrodynamic cavitation

The paper has investigated the disinfecting effect of hydrodynamic cavitation on the microorganisms of E. coli in water. It has been found that disinfection kinetics depend on the intensity of the hydrodynamic cavitation field, the microbial load, and gas content. We have studied structure and morphology variation of the E. coli bacteria. It has been demonstrated that the antimicrobial effect is achieved owing to the physicochemical effects of the cavitation field, under whose influence there occurs mechanical destruction of cells and chemical disinfection by the radicals of hydroxyl and hydrogen peroxide.     

Experience with the preconstruction of thawing of soils in the foundation bed of the main building of the Neryungrinsk state area power plant

Conclusions 1. The scheme that we developed is efficient and ensures thawing over a period of 40–45 days. 2. To accelerate thawing by 8–10 days when using two electric heaters in each hole, it is necessary to raise the heaters by 3–4 m after 25 days and continue thawing. 3. An 8–10-day reduction in the thaw time is also possible by using three 1.25-kW electric heaters in each hole in place of two heaters of the same capacity, installing them at depths of 20, 14, and 8 m from the surface. Taking the results of the experimental work account, the State Institute for Special Design developed a plan for the production preconstruction thawing of soils over a area of 12,380 m². The volume of soil thawed was 324,400 m³. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 3, pp. 7–8. May–June, 1982.     

Probabilistic calculation for the bed under an individual foundation in accordance with the second group of limiting states

Conclusions 1. The method proposed for the probabilistic design of beds makes it possible to obtain a well-founded design solution corresponding to a given reliability level, which, in many cases, is more economic than the solution recommended in the Construction Rules and Regulations. 2. The design solution adopted as a result of the calculation set forth in the Construction Rules and Regulations possesses a reliability level, which, for some unknown reason, is on the high side. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 2, pp. 18–20, March–April 1991.     

Elastoplastic finite-element analysis of the bearing capacity of beds of reconstructed entities

A method is presented for determination of the coefficients that take into account the increase in angle of internal friction and specific cohesion of silty-clayey soils in predicting variation in the bearing capacity of beds after the long-term effect of the consolidating service-induced loads. __________ Translated From Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 2, Pp. 18–21, March–April, 2007.