The effect of the new traffic law on drinking and driving in São Paulo,Brazil

Objective

To present data on drinking and driving in the city of São Paulo, Brazil, and the effects of the new traffic law (Law 11,705) introduced in 2008.

Methods

A cross-sectional study was performed using a questionnaire and passive breath test data to study the prevalence of drinking and driving and the association of drinking and driving with background characteristics and drinking patterns on two separate occasions. The data were gathered from 2007 to 2009 through roadside surveys conducted on busy public roads. Four thousand two-hundred thirty-four (4234) drivers were approached, before and after prohibition, from the south, north, east, and west regions of the city of São Paulo, located in southeastern Brazil, including cars, motorcycles, and utility vehicles. A total of 3854 (91%) consented to participate in the survey and answered the questionnaire. Out of this group, 3229 (84%) agreed to take the passive breathalyzer test.

Results

Logistic regression analyses controlling for gender and age was used to predict a positive breath test (above 0.2 g/l) and the impact of the new law. These analyses indicated that, after the passage of the new traffic law, there was a 45% decrease in driver behavior with positive breathalyzer results. Having a pattern of alcohol consumption of at least once a week and the habit of drinking and driving are risks for a positive breathalyzer.

Conclusions

Despite the decline in the frequency of motorists driving under the influence of alcohol, traffic-related injuries and deaths, after the new law, other measures for a public policy related to alcohol should be considered based on scientific evidence, consistency of action, clear goals, community support, and greater reliability in the laws.     

The Male-produced Sex Pheromone of the True Bug, Phthia picta, is an Unusual Hydrocarbon

Phthia picta is part of a complex of true bugs (Heteroptera) in Brazil that attack tomatoes, being particularly damaging because nymphs and adults feed on both leaves and fruit. Gas chromatography (GC) of aeration extracts of adult males vs. females revealed the presence of a male-specific compound. GC-electroantennographic detector experiments indicated that the antennae of females are highly sensitive to this male-specific compound. GC-mass spectrometry and GC-FTIR analyses suggested a methyl branched hydrocarbon structure for this compound. After synthesis of three different proposed structures, the natural product was indentified as 5,9,17-trimethylhenicosane, which was strongly attractive to females in Y-tube olfactometer bioassays. Analysis of dissected body parts of adults revealed that the pheromone is produced in the lateral accessory glands of the metathoracic scent gland of males only.     

Synthesis and characterization of semi‐interpenetrating networks based on poly(dimethylsiloxane) and poly(vinyl alcohol)

Semi‐interpenetrating networks (Semi‐IPNs) with different compositions were prepared from poly(dimethylsiloxane) (PDMS), tetraethylorthosilicate (TEOS), and poly(vinyl alcohol) (PVA) by the sol‐gel process in this study. The characterization of the PDMS/PVA semi‐IPN was carried out using Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), scanning electron microscopy (SEM), and swelling measurements. The presence of PVA domains dispersed in the PDMS network disrupted the network and allowed PDMS to crystallize, as observed by the crystallization and melting peaks in the DSC analyses. Because of the presence of hydrophilic (? OH) and hydrophobic (Si? (CH₃)₂) domains, there was an appropriate hydrophylic/hydrophobic balance in the semi‐IPNs prepared, which led to a maximum equilibrium water content of ～ 14 wt % without a loss in the ability to swell less polar solvents. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010     

Elastomeric composites based on ethylene–propylene–diene monomer rubber and conducting polymer-modified carbon black

Thermally stable elastomeric composites based on ethylene–propylene–diene monomer (EPDM) and conducting polymer-modified carbon black (CPMCB) additives were produced by casting and crosslinked by compression molding. CPMCB represent a novel thermally stable conductive compound made via “in situ” deposition of intrinsically conducting polymers (ICP) such as polyaniline or polypyrrole on carbon black particles. Thermogravimetric analysis showed that the composites are thermally stable with no appreciable degradation at ca. 300°C. Incorporating CPMCB has been found to be advantageous to the processing of composites, as the presence of ICP lead to a better distribution of the filler within the rubber matrix, as confirmed by morphological analysis. These materials have a percolation threshold range of 5–10 phr depending on the formulation and electrical dc conductivity values in the range of 1 × 10⁻³ to 1 × 10⁻² S cm⁻¹ above the percolation threshold. A less pronounced reinforcing effect was observed in composites produced with ICP-modified additives in relation to those produced only with carbon black. The results obtained in this study show the feasibility of this method for producing stable, electrically conducting composites with elastomeric characteristics. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers     

Overview of anaerobic corrosion of carbon steel radioactive waste packages in alkaline media in support of the Belgian supercontainer concept

The so-called supercontainer concept is currently being considered as the reference design for the final disposal of vitrified high-level radioactive waste and spent fuel in Belgium. It comprises a prefabricated Portland cement-based buffer that completely surrounds a carbon steel overpack. In this highly alkaline environment (pH ~13.6), and under normal conditions (i.e., without the ingress of aggressive species), the carbon steel overpack will be protected by a passive oxide film, which is expected to result in very low uniform corrosion rates. Considering the long timescales applicable to waste disposal, determining accurate and reliable estimates of the uniform corrosion rate under anoxic conditions forms a very important part of the safety and feasibility strategy. It is also crucial to demonstrate that no other form of corrosion apart from uniform corrosion takes place. This paper presents the progress of the research that has been made since the LTC2016 Workshop (Toronto, Canada) on uniform corrosion, pitting corrosion and stress corrosion cracking behaviour of P355 QL2 grade carbon steel exposed to an artificial concrete pore water solution.     

β-Conglycinin (7S) and glycinin (11S) exert a hypocholesterolemic effect comparable to that of fenofibrate in rats fed a high-cholesterol diet

The hypocholesterolemic effect of isolated soybean proteins and fenofibrate in rats was compared. Forty-five rats were divided into five groups: standard (STD; casein), high cholesterol (HC; STD plus 1% cholesterol/0.5% cholic acid), HC + β-conglycinin, HC + glycinin and HC + fenofibrate. The proteins and the drug were administered by gavage for 28 days. The proteins decreased total cholesterol (TC) and triacylglycerol (TG) in the plasma of the rats fed HC diet, to values very close to those fed on fenofibrate. High density lipoprotein cholesterol (HDL-C) levels in the plasma were increased by the β-conglycinin, glycinin and fenofibrate groups. The largest TC reduction in the liver was observed in the fenofibrate group; in contrast, the β-conglycinin and glycinin groups exhibited reduced the levels of hepatic TG and TC. Based on these data, it could be suggested that the oral daily administration of isolated soybean proteins, in the range of 2.75% of the protein ingested daily, can promote a reduction in TC and TG in the plasma of rats fed hypercholesterolemic diets.     

Expansion Properties of Sour Cassava Starch (Polvilho Azedo): Variables Related to its Practical Application in Bakery

Sour cassava starch (polvilho azedo) is a chemically and enzymatically modified starch with the specific property of expansion in bakery products without the use of any chemical or biological leavening agents. In this work, the cumulative knowledge about sour cassava starch is presented in relation to its physicochemical characteristics, with the purpose of establishing a relation between the application properties and some structural and chemical characteristics in order to design a model of the modified structure of starch and the most important technical variables. Such approach will help to provide some quality standards for future adequate valorization of sour cassava starch, especially with respect to potential use in gluten‐free products. This work showed that a good sour cassava starch is significantly different from low expansion cassava starches with respect to pH, acid factor, swelling power, specific volume, and polymerization degree (intrinsic viscosity). These variables could be related to the maximization of sour cassava starch expansion for a future predictive decision analysis about a high quality sour cassava starch to the baking use.     

Heat inactivation and kinetics of polyphenoloxidase from palmito (Euterpe edulis)

Polyphenoloxidase (PPO, EC 1.14.18.1)was extracted from palmito (Euterpe edulis Mart) using 0.1 M phosphate buffer, pH 7.5. Partial purification of the enzyme was achieved by a combination of (NH₄)₂SO₄precipitation (35–90% saturation) and Sephadex G-25 and DEAE-cellulose chromatography. The purified preparation gave five protein bands on polyacrylamide gel electrophoresis, three of them with PPO activity. The K_mvalues for chlorogenic acid, caffeic acid, catechol, 4-methylcatechol and catechin were 0.57, 0.59, 1.1, 2.0 and 6.25 mM , respectively. PPO has a molecular weight of 51 000 Da, maximum activity at pH 5.6 with chlorogenic acid as substrate, and was stable between pH 5.0 and 8.0. The enzyme was heat stable at 50–60°C and inactivated at 75°C. The heat stability of palmito PPO was found to be pH dependent; at 50°C and pH 4.0 the enzyme was fully inactivated after 30 min. The pH/activity studies showed two groups with pK values c 4.6 and 6.7 involved in PPO catalysis.     

Development of dental resinous systems composed of bisphenol a ethoxylated dimethacrylate and three novel methacrylate monomers: Synthesis and characterization

Three novel monomers with a methacrylate unit, different chain lengths, and functional groups were synthesized and proposed as possible diluent monomers in dental resinous systems containing bisphenol A ethoxylated dimethacrylate (BisEMA) aiming at their use in dental resin mixtures. The monomers were mixed with BisEMA and photopolymerized in the presence of a photoinitiator system. The unfilled formulations were evaluated regarding their degree of conversion, thermal properties, Vickers microhardness, water sorption, water solubility, and surface morphology. The monomers presented a high conversion degree compared to control groups and have affected the glass transition temperature of the samples. Their hardness values were similar to or higher than the value found for the control group. The specimens evaluated presented a homogeneous matrix and stability throughout the water sorption and solubility tests. Considering their simplicity and effective application in synthesis, as well as the results obtained for the polymerized formulation groups, the new monomers presented here represent promising photocurable dental monomers. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013