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961.
The Fe-U system is one of the binaries of the U-Fe-Zr-O quaternary system that is important for a safe nuclear program. A
new thermodynamic assessment of Fe-U is presented, taking into account some recent thermodynamic measurements: enthalpy of
formation and of melting as well as heat capacities for both intermetallic compounds Fe2U and FeU6. The calculated phase diagram and thermodynamic data generally agree very well with the experimental values. The calculated
temperature of the peritectic transformation [FeU6 ↔ liquid + bcc-U] is equal to 1104 K, which is higher than in the previous assessments, but in agreement with Labroche’s
value. However, the experimental melting enthalpy of FeU6 is not reproduced by the present set of thermodynamic parameters. 相似文献
962.
Gnevko A. I. Kazakov N. A. Sultanovskii V. I. Zubov O. E. 《Metal Science and Heat Treatment》2002,44(1-2):94-94
Metal Science and Heat Treatment - 相似文献
963.
O.E.E.K. Omar T. El-Wardany E. Ng M.A. Elbestawi 《International Journal of Machine Tools and Manufacture》2007,47(7-8):1263-1275
During the milling operation, the cutting forces will induce vibration on the cutting tool, the workpiece, and the fixtures, which will affect the surface integrity of the final part and consequently the product's quality. In this paper, a generic and improved model is introduced to simultaneously predict the conventional cutting forces along with 3D surface topography during side milling operation. The model incorporates the effects of tool runout, tool deflection, system dynamics, flank face wear, and the tool tilting on the surface roughness. An improved technique to calculate the instantaneous chip thickness is also presented. The model predictions on cutting forces and surface roughness and topography agreed well with experimental results. 相似文献
964.
965.
Phaseformation processes are considered at the level of a mesocell of a mixture with the use of the state diagram for a binary system. Consecutive schemes of metallochemical reactions of formation and decomposition of intermetallide compounds in a mixture of nickel and aluminum powders are suggested. The problem of diffusion annealing of this mixture is numerically solved for two different conditions: at a constant temperature and at a temperature slowly increasing by a linear law. 相似文献
966.
Symmetrical and non-symmetrical triacylglycerols (TAG) containing oleic (O; 9c-18:1) and elaidic (E; 9t-18:1) acids were required
as part of a study relating the physical characteristics and functionality of trans-containing TAG with the mouth feel, taste characteristics and related characteristics desired by consumers in frying oils
and pastries. To replace the trans isomers in frying oils—a significant part of frying oils prepared by partial hydrogenation of vegetable oils—without loss
of the sensory properties desired by consumers, required the initiation of a study relating the structure of trans-containing TAG with such characteristics as melting range, drop points, and other crystalline properties. Elaidic acid was
esterified to trielaidin (EEE), and the EEE partially converted (glycerol/p-toluenesulfonic acid) to a mixture containing ca. 40% DAG (the 1,3- and 1,2-isomers). The DAG fraction was separated by silica
gel chromatography, the 1,3-dielaidylglycerol (1,3EE-DAG) isomer isolated (structural purity >99%) by crystallization from
acetone and esterified with oleic acid (O) to yield EOE. The 1(3)O-MAG was purchased commercially and esterified with E acid
to prepare OEE. Both syntheses yielded multi-gram quantities of EOE and EEO, in 80–85% yields, and with structural purities
>99%. Thus, by careful selection of the thermodynamically more-stable MAG or DAG precursors, the symmetrical EOE and non-symmetrical
EEO isomers could be readily synthesized, and their drop point and melting point values determined.
The 1- and 3- positions on the glycerol backbone of the MAG, DAG and TAG molecules are assumed to be equivalent. 相似文献
967.
The water vapor (WVP) and oxygen (O2P) permeabilities of beeswax (BW), candelilla wax (CnW), carnauba wax (CrW) and microcrystalline wax (MW), formed as freestanding
films, were determined. CnW and CrW both had small values for O2P (0.29 and 0.26 g·m−1·sec−1·Pa−1 × 10−14, respectively), which are less than half the value for high-density polyethylene and about a decade greater than the value
for polyethylene terephthalate. O2P values for BW and MW were about 6−9× greater than those of CnW and CrW. WVP of CnW was 0.18 g·m−1·sec−1·Pa−1 × 10−12, which is about one-half the value for CrW and MW and about one-third the value for BW. The WVP of CnW was somewhat less
than that of polypropylene and somewhat greater than that of high-density polyethylene. Differences in permeabilities among
the wax films are attributed mainly to differences in chemical composition and crystal type as determined by X-ray diffraction. 相似文献
968.
Oliver Warschkow Lj. Miljacic D. E. Ellis G. B. González T. O. Mason 《Journal of the American Ceramic Society》2006,89(2):616-619
We report first-principles density functional theory calculations of interstitial oxygen in tin-doped indium oxide (ITO), a transparent conducting oxide. Interstitial oxygen plays a critical role in the defect of ITO because it is by removal of interstitial oxygen that n -type charge carriers are produced. The Frank and Köstlin defect model successfully rationalizes the observed conductivity, Sn-doping, and oxygen partial pressure dependencies of ITO by postulating that tin atoms, which substitute for indium, are clustered with interstitial oxygen. Structural evidence for such a clustering, however, remains ambiguous. Recently published Rietveld refinement results of X-ray and neutron diffraction data found interstitial oxygen to be significantly displaced (0.4 Å) from the ideal fourfold position. Our calculations show that the experimental position is plausible only if interstitial oxygen is clustered with SnIn defects at any of the three d -type cation sites nearest to the interstitial, thereby providing direct structural confirmation of the Frank and Köstlin defect model. 相似文献
969.
David O. Cooney 《Chemical Engineering Communications》1990,91(1):1-9
A simple method is presented for determining fluid-phase and solid-phase solute concentration profiles, and solute breakthrough curves, for fixed bed adsorbers when both the fluid-phase and solid-phase mass transfer resistances are important. The method applies to any nonlinear isotherm of the “favorable” type. Freundlich and Langmuir isotherms are used as specific examples in the present paper. Constant-pattern behavior and linear-driving-force rate laws are assumed. 相似文献
970.
In the previous paper, we reported the stand growth of slash pine (Pinus elliottii) during the first 11.5 years of plantation in response to (1) initial fertilization at plantation establishment with P rates of 11, 22, 45 and 90 kg P ha–1 which were either banded or broadcast in the presence or absence of basal fertilizers containing 50 kg N ha–1, 50 kg K ha–1 and 5 kg Cu ha–1 and (2) application of additional 40 kg P ha–1 at age 10 years. Here we present the responses in foliar nutrient concentrations of slash pine in the first 11.5 years to the initial fertilization and the additional P applied at age 10 years.Foliar N and K concentrations in the first 9.6 years of plantation decreased with the initial P rate. Application of the basal fertilizers improved foliar Cu concentration. Foliar Ca and Mg concentrations increased linearly with the initial P rate. The initial fertilization did not affect foliar Mn concentration in the first 9.6 years. Foliar P concentration increased quadratically with the initial P rate, which accounted for 77–86% of the variation in foliar P concentration. Most of the explained variation in foliar nutrient concentrations was attributable to the plantation age except for foliar P concentration. In the case of foliar P concentration, 53% was explained by the initial P rate, 31% by the plantation age and 2% by the positive interaction between the initial P rate and the plantation age. Foliar P concentration of slash pine at age 11.5 years increased quadratically with the initial P rate and linearly with the additional 40 kg P ha–1 applied at age 10 years, accounting for 81% of the variation in the foliar P concentration. Foliar nutrient analysis indicated that P was the major limiting nutrient affecting the stand growth of slash pine in the first 11.5 years. 相似文献