Admiral John A. B. Dahlgren (1809–1870): His life, times and technical work in U.S. naval ordnance

John Dahlgren served in the U.S. Navy for nearly 35 years, sometimes in a sea-keeping capacity but mostly developing large naval artillery. To-day, his name, when recognised by students of naval ordnance, is associated with teh Dahlgren or ‘soda bottle shaped’ gun of 9 to 11 inch calibre. He designed, developed and lived to see his guns installed aboard warships and used to considerable effect, especially in the American Civil War. However, a nearly indistinguishable external design of gun was developed for the Army by T. J. Rodman, an officer now even less known than Dahlgren and whose researches and contributions are virtually forgotten. This paper and that in Ref. [1] attempt to appreciate (along with other technical questions of the period) the different ways pursued by these men towards the final development of the ‘soda bottle shaped’ gun, though it is a matter still not entirely understood.

Both names are totally omitted from several ‘classic’ books on artillery and this is a grave misfortune. Besides trying to throw factual light on the Dahlgren-Rodman controversy and the priority issue (though not one pursued with acrimony by the men themselves at the time), the paper describes Admiral Dahlgren's general career, the books he wrote, the technical problems he attacked and the problematic ordnance discussions of his day, to which he gave his life.

The work of Dahlgren and Rodman, in particular, saw the elevation of American gun design from the level of mere copying (of early Columbiads in the first decades of the century) to that which compelled attention from, and study by, the super-powers of the day, Great Britain, France and Russia.     

Toughening of Dental Porcelain by Tetragonal ZrO2 Additions

The effect on mechanical behavior of ZrO₂ additions to a dental porcelain was investigated. The ZrO₂ was introduced into the glassy matrix phase of the porcelain by refritting the all-glass porcelain constituent. X-ray diffraction indicated that a sizeable fraction of the ZrO₂ was retained in the tetragonal form after the porcelain was fired. Zirconia additions to the porcelain produced substantial improvements in fracture toughness, strength, and thermal shock resistance.     

Dynamic control of the permanent magnet-assisted reluctance synchronous machine

A digital signal processor-based control system for the permanent magnet-assisted reluctance synchronous machine, with the emphasis on dynamic performance, is proposed. A classical design approach is used to design the current and speed controllers for the machine. The stator current of the machine is controlled in such a way that the current angle in the dq synchronous reference frame is constant. The load-torque is estimated using a state space observer and compensation current based on the estimated load is used to improve the dynamic performance of the drive. The control system design is machine specific as it relies on data from finite-element analysis. Simulated and measured results on a 110-kW power level show that the resulting control system is stable and robust with good dynamic performance     

Pesticide monitoring programme of the Ministry of Health of Brazil

The structure of the recently introduced Brazilian government programme for monitoring pesticide residues in six major agricultural products is described. Residues found from the analysis of samples of tomatoes and strawberries are discussed in detail. The much greater frequency of detection of pesticide residues, many of which are not approved for use in Brazil, in produce being sold on the domestic market, as opposed to that produced for export, is of major concern. It is perceived that this new monitoring programme will become permanent and be used to underpin enforcement actions that will need to be taken to reduce the numbers of incidents of illegal residues occurring, particularly in fresh fruits and vegetables.     

The hydration of slag,part 1: reaction models for alkali-activated slag

Reaction models are proposed to quantify the hydration products and to determine the composition of C–S–H from alkali-activated slags (AAS). Products of the slag hydration are first summarized from observations in literature. The main hydration products include C–S–H, hydrotalcite, hydrogarnet, AFm phases (C₄AH₁₃ and C₂ASH₈) and ettringite. Then, three stoichiometric reaction models are established correlating the mineral composition of slag (the glass part) with the hydration products. Using the proposed models, quantities of hydration products and composition of C–S–H are determined. The models are validated with a number of experimental investigations reported in literature, yielding good agreement, i.e., these models can successfully predict the hydration reaction of AAS. The models are furthermore applied to calculate the retained water in the hydration products of AAS in different hydration states and a general hydration equation of AAS is derived. As an illustration to one of the model applications, chemical shrinkage of the AAS cement paste in different hydration states are predicted. The chemical shrinkage of AAS is shown to be remarkably higher than OPC. Furthermore, phase distribution in the hardened AAS paste and the porosity are calculated.     

The wear behaviour of oxide ceramics-A Review

The paper reviews the wear behaviour of oxide ceramics. Wear maps are considered and consequently mild and severe wear are defined. Since the use of ceramics in engineering applications require operation in the mild wear regime, the paper concentrates on mild wear mechanisms, but also considers factors which control the transition to severe wear. Within the mild wear regime, the formation of tribofilms are discussed and the manner in which dislocation activity leads to the wear transition is considered. The wear of so-called ceramic nanocomposites, for which no time dependent wear transition has yet been observed, is considered and the reasons for enhanced performance discussed. The role of transformation toughening in zirconia ceramics is considered in detail, and reasons for the generally poor wear response of these materials defined.     

Production of maraging steel grades and the influence of specified and nonspecified elements for special applications

The material properties of maraging steels are greatly affected by the alloy and inclusion content and hence by the production route. This paper describes various past and current production routes at Böhler Edelstahl GmbH and the effect of these routes on the specified element (alloy) and non-specified element (inclusion) contents. Non-metallic inclusions were investigated by EDX analysis. The effects of various alloying and tramp elements on the material properties are presented as a statistical evaluation of previous melts. Nitrogen solubility was calculated with Thermo–Calc for maraging steel Mat.-No. 1.6354 and the precipitation of nitrides is discussed. A proposal is made for the production of melts with improved properties.