Trimetallic NiFeCr-LDH/MoS2composites as novel electrocatalyst for OER

The development of efficient and stable oxygen evolution reaction (OER) catalysts is an ongoing challenge. In order to solve the problem of low oxygen evolution efficiency of the current OER catalysts, a novel material was synthesized by the incorporation of NiFeCr-LDH and MoS₂, and its structural and electrochemical properties were also investigated. The introduction of MoS₂ improves the electrochemical performance of NiFeCr-LDH. The polarization curve shows that the potential of composite material is only 1.50 V at a current density of 10 mA cm^?2, which is far superior to commercial precious metal catalysts. In addition, the stability experiment shows that the composite material has excellent stability, and the current density has little change after 500 cycles. Furthermore, we found that some metal ions, such as Ni, Cr and Mo, exist in the form of high valence on the surface of NiFeCr-LDH@MoS₂, which is also conducive to the occurrence of oxygen evolution reaction.     

Carbon corrosion mechanism on nitrogen-doped carbon support — A density functional theory study

In this work, density functional theory (DFT) calculations were used to investigate the mechanism of carbon corrosion on nitrogen-doped carbon support. Free energy diagrams were generated based on three proposed reaction pathways to evaluate corrosion mechanisms. The most energetically preferred mechanism on nitrogen-doped carbon was determined. The results show that the step of water dissociation to form ^#OH was the rate-determining step for gra-G-1N (graphene doped with graphitic N) and pyrr-G-1N (graphene doped with pyrrolic N). As for graphene doped with pyridinic N, the step of C^#OC^#O formation was critical. It was found that the control of nitrogen concentration was necessary for precisely designing optimized carbon materials. Abundance of nitrogen moieties aggravated the carbon corrosion. When the high potential was applied, specific types of graphitic N and pyridinic N were found to be favorable carbon modifications to improve carbon corrosion resistance. Moreover, the solvent effect was also investigated. The results provide theoretical insights and design guidelines to improve corrosion resistance in carbon support through material modification by inhibiting the adsorption of surface oxides (OH, O, and OOH).     

生态封场技术在非正规垃圾堆放场治理中的应用

本文通过对各项治理技术比选,提出了生态封场技术在非正规垃圾堆放场治理中的应用,并结合实际案例给出了详细治理方案.     

锁紧机构防脱落保持架设计与分析

针对锁紧机构保持架在恶略环境下,反复振动过程中保持架上钢球脱落问题,提出了一种新型防脱落保持架设计方案,重点介绍了锁紧机构中保持架的工作形式,通过ANSYS进行有限元仿真分析,得出新型保持架结构满足刚强度要求以及热变形要求,且在随机振动6.06 g条件位移小,能有效免锁紧机构直线运动时钢球从外部脱落的可能,提高了锁紧机构工作过程中的可靠性与安全性.     

建筑工业化发展的多群体演化博弈与仿真研究

新型建筑工业化具有高质量、低消耗、可循环发展等特征，其推广已上升到国家战略层面。利用演化博弈方法，建立“政府-开发商-银行” 的三方动态演化博弈模型，进行各博弈主体策略的演化稳定性分析，并针对初始状态、奖惩力度、借贷风险和开发成本等对演化结果的影响进行动态仿真。在此基础上， 考虑开发商群体的网络拓扑特征对演化真实性的影响，引入复杂网络理论， 以无标度网络为载体描述开发商个体的连接偏好和决策机制，构建政府监管下的建筑工业化扩散模型，并通过仿真深入研究相关因素对扩散深度的影响作用，最后结合仿真结果给出相应对策建议。     

石粉和脱硫石膏混合装置的设计与应用

利用双轴搅拌机的工作原理设计的石粉和脱硫石膏混合装置，将石粉和脱硫石膏混合成干湿均匀料加入水泥磨，既利用了石粉、节约了石子，又解决了水泥生产过程中脱硫石膏水分大、不便输送和难稳定入磨的问题，效果显著。     

基于示范城市创建的食品安全治理体系研究

食品安全示范城市创建是食品安全治理体系的重要载体。本文系统性回顾食品安全治理体系相关研究,从“党政同责”、政府监管、市场主体、社会共治等四个治理主体,构建生产规范、产业转型升级等27个评价指标的治理标准,利用层次分析法实证分析了浙江省食品安全示范城市创建情况。结果表明:采用暗查暗访、现场检查、体系评估、示范引领答辩等形式,按照一定的评价流程、评价标准的食品安全示范城市创建,是实现食品安全现代化目标的重要载体。食品安全治理体系包括“治理载体—治理主体—治理标准—治理目标”。食品安全治理成效与跟踪评价、群众满意度以及体系评估高度关联。     

Statistical Piezotronic Effect in Nanocrystal Bulk by Anisotropic Geometry Control

Utilizing inner-crystal piezoelectric polarization charges to control carrier transport across a metal-semiconductor or semiconductor–semiconductor interface, piezotronic effect has great potential applications in smart micro/nano-electromechanical system (MEMS/NEMS), human-machine interfacing, and nanorobotics. However, current research on piezotronics has mainly focused on systems with only one or rather limited interfaces. Here, the statistical piezotronic effect is reported in ZnO bulk composited of nanoplatelets, of which the strain/stress-induced piezo-potential at the crystals’ interfaces can effectively gate the electrical transport of ZnO bulk. It is a statistical phenomenon of piezotronic modification of large numbers of interfaces, and the crystal orientation of inner ZnO nanoplatelets strongly influence the transport property of ZnO bulk. With optimum preferred orientation of ZnO nanoplatelets, the bulk exhibits an increased conductivity with decreasing stress at a high pressure range of 200–400 MPa, which has not been observed previously in bulk. A maximum sensitivity of 1.149 µS m⁻¹ MPa⁻¹ and a corresponding gauge factor of 467–589 have been achieved. As a statistical phenomenon of many piezotronic interfaces modulation, the proposed statistical piezotronic effect extends the connotation of piezotronics and promotes its practical applications in intelligent sensing.     

TRIZ理论在解决回转式空气预热器低温腐蚀以及堵灰问题中的应用

回转式空气预热器冷端传热元件的低温腐蚀、堵灰现象在国内外非常普遍,且受到众多电厂的关注,该问题会严重影响到锅炉的安全运行,导致诸如排烟温度增高、热风温度降低、阻力增大、漏风率上升等问题。根里奇·阿奇舒勒创立的TRIZ理论是一种综合的创新方法,可促进发明创造并得到优异的创新产品,它能够帮助我们系统地分析问题,发现问题的本质以及矛盾,从而得到问题实质解。本文针对回转式空气预热器低温腐蚀以及堵灰问题,采用TRIZ理论进行了深入分析。