Isosteric heat of sorption of CO2 in poly(ethylene terephthalate)

Sorption isotherms for carbon dioxide in poly(ethylene terephthalate) have been measured at 35–55°C. The isotherms were measured gravimetrically on a Mettler Thermoanalyzer-1 from vacuum to 1 atmosphere. The sorption data were used to generate sorption isotherms from which the isosteric heat of sorption of CO₂ in PET was determined. At 45°C the isosteric heat of sorption increases from −10 kcal/mole at a concentration of 0.5 cm³ (STP)/cm³ (polymer) to −8 kcal mole⁻¹ at a concentration of 1.5 cm³ (STP)/cm³ (polymer). It has been reported in the literature that the isosteric heat of sorption for this system decreased through a minimum before increasing with increasing concentration. Our measurement of the low-pressure sorption isotherms shows that this is not the case.     

Synthesis of copoly(ethylene terephthalate /imide)s and crystallization kinetics

Copoly(ehtylene terephthalate/imide)s (PETI) were prepared by melt polycodensation of bis(2-hydroxyethyl)terephthalate (BHET) and imide containing comonomer, 4,4′-bis[(4-carbo-2-hydroxyethoxy)phthalimido]diphenylmethane (BHEI) with Sb₂O₃ as catalyst at 280°C under vacuum (～ 1 mm Hg). The change of T_m with an increase of the BHEI repeat unit in the PETI copolymer was analyzed by the Flory equation. On isothermal crystallization, a longer induction time and a lower activation energy than for the PET homopolymer were observed with an increasing amount of BHEI repeat unit. The Avrami exponent, n, increased from 1.5 to 2.3 as the content of BHEI or crystallization temperature was increased. The Avrami rate constant K decreased with the increase of the BHEL unit. On nonisothermal crystallization, the Ozawa equation and Lawton plot were used to investigate the effect of BHEI units on the crystallization kinetics of PETI copolymers. From the change of the cooling crystallization function and the result of the Lawton plot, it was found that the BHEI unit effectively decreases the rate of crystallization.     

面向新一代智能电表的微电流指纹自动配对技术

针对智能电表与表后断路器大多依赖人工掌机扫码进行配对,配对过程过度依赖人工,成本高,且容易发生误配对串户等问题,提出了面向新一代智能电表的微电流指纹自动配对技术。该技术通过在蓝牙断路器内置开关电容模块和编码电路,将配对特征码信息调制成无功电流信号,利用电力线传输至智能电表,并与蓝牙断路器广播发送的配对特征码信息进行比对,从而实现智能电表与表后断路器的自动配对。该配对过程无需依赖人工,极大地降低了人工成本,提高了配对的准确性。最后,实验验证了所提的微电流指纹自动配对技术的正确性和有效性。     

生物慢滤系统对再生水中氮磷降解的试验研究

利用生物慢滤系统中菌-藻共生的特点,对用于景观补水的再生水中氮磷进行有效的去除,可有效预防由于再生水中氮磷营养盐浓度较高而引发的景观水体富营养化问题。通过生物慢滤系统净化再生水的试验研究表明,生物慢滤系统在保持上覆水深为80cm、滤层厚度为80cm、滤速为0.1m/h的条件下,对水体中总氮、氨氮、硝酸盐氮、总磷和高锰酸盐指数平均去除率分别为57.55%、50.16%、46.37%、66.32%和47.04%,叶绿素a的去除率可达95.75%;经生物慢滤系统处理后的再生水在景观储存过程中藻类的生长缓慢,叶绿素a含量始终维持在较低水平,氮磷含量较低且趋于稳定。经生物慢滤池处理的再生水用于景观水体的补充水源,可减少富营养化的发生频率。     

镁合金废料的回收

在镁合金零部件生产过程中，特别是在压力铸造生产中，产生出来的废料以及使用后报废的镁合金零件逐渐增多。出于成本和环境因素的考虑，必须对这与日俱增的镁合金废料进行有效回收。本文以生产占90％的镁合金零部件压力铸造为主线，介绍镁合金废料回收的经济分析，镁合金废料的来源和分类、现行回收技术的现状及发展趋势。并介绍香港生产力促进局和重庆硕龙科技公司最近研究开发的一种新型镁合金废料现场精炼回收系统。     

Toward a classification of discourse patterns in asynchronous online discussions

The goal of this study was to develop a classification for a range of discourse patterns that occur in text-based asynchronous discussion forums, and that can aid in the distinction of three modes of discourse: knowledge sharing, knowledge construction, and knowledge building. The dataset was taken from Knowledge Forum® databases in the Knowledge Building Teacher Network in Hong Kong, and included three discussion views created for different classes: Grade 5 Science, Grade 10 Visual Arts, and Grade 10 Liberal Studies. We used a combination of qualitative coding and narrative analysis as well as teachers’ understanding of online discourse to analyze student discussions. Nine discourse patterns were identified. These patterns revealed a variety of ways in which students go about their collaborative interactions online and demonstrated how and why students succeed or fail in sustaining collaborative interactions. This study extended the three modes of online discourse and developed different discourse patterns, which are efforts to provide instructional guidance. The implications of supporting productive discourse and the enactment of CSCL innovations in classrooms are discussed.     

Robust H∞ Tracking Control of Uncertain Robotic Systems with Periodic Disturbances

This paper addresses the problem of designing robust tracking control for a large class of uncertain robotic systems. A more general model of the external disturbance is employed in the sense that the external disturbance can be expressed as the sum of a modeled disturbance and an unmodeled disturbance, for example, any periodic disturbance can be expressed in this general form. An adaptive neural network system is constructed to approximate the behavior of unknown robot dynamics. An adaptive control algorithm is designed to estimate the behavior of the modeled disturbance, and in turn the robust H_∞ control algorithm is required to attenuate the effects of the unmodeled disturbance only. Consequently, an intelligent adaptive/robust tracking control scheme is constructed such that an H_∞ tracking control is achieved in the sense that all the states and signals of the closed‐loop system are bounded and the effect due to the unmodeled disturbance on the tracking error can be attenuated to any preassigned level. Finally, simulations are provided to demonstrate the effectiveness and performance of the proposed control algorithm.     

Ketamine effects on the urogenital system--changes in the urinary bladder and sperm motility

Different doses of ketamine (10 mg/kg, 20 mg/kg, 30 mg/kg, 40 mg/kg, 50 mg/kg, and 60 mg/kg) were injected i.p. (I.P.), respectively, to male ICR mice to determine the optimal dosage for chronic administration. At and above 40 mg/kg I.P. injection, mice had almost no hindlimb movement during swimming test. Subsequently, 30 mg/kg was used as the dose for the study in the toxicity of long-term ketamine administration on urinary bladder and sperm motility. The treatment group were subdivided into two (n = 10 each group); one received daily ketamine treatment i.p. for 3 months and another group for 6 months. Corresponding number of mice in control groups (n = 5 each group) received saline injection instead of ketamine. Terminal dUTP nick and labeling (TUNEL) study and Sirius red staining were carried out on the sectioned slides of the urinary bladders to study the degree of apoptosis in both epithelium and muscular layers of the urinary bladder and the relative thickness of the muscular layers in this organ was also computed. Apoptosis in the bladder epithelium was observed initially in the 3-month ketamine treated mice and the number of apoptotic cells was significantly different (P < 0.05) between the 3-month and 6-month ketamine treated mice and the control. The relative thickness of muscular layers in the bladder wall also decreased significantly (P < 0.05) when the 6-month treated mice and the control were compared. Sirius red staining revealed increase of collagen in the urinary bladder of the treated mice, most evidently 6 months after ketamine treatment. In addition, the sperm motility was studied and there was a statistically significant difference between the control and ketamine treated groups in the percentages of sperms which were motile (P < 0.05). This suggested that the chronic administration of ketamine affected the genital system as well.