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A specially designed electro-cross-flow nanofiltration (NF) membrane system was used for this investigation. To enhance the rejection of arsenic ionic species like H2AsO4−, a NF membrane having a negative surface charge was fabricated via the interfacial polymerization process. The membrane was characterized by SEM, AFM, surface charge density, molecular weight cut-off (MWCO), total and skin thickness and pure water flux. The parameters that affected the rejections of As(III) and As(V) were studied; they included the initial arsenic concentration, the applied potential, pH of the feed, the cross-flow filtration pressure and the presence of different salts in the feed. Among those parameters, the pH of the feed greatly affected As(V) rejection; As(V) ([As(V)]o = 1000 ppb) rejection was increased from 72.3 to 98.5% when pH of the feed was changed from 3.0 to 10.0. This might be due to the fact that higher pH enhanced the formation of negative divalent anion like HAsO42− which should be rejected more effectively by the negative surface charge of the NF membrane. Beside the effect of the negative surface charge of the membrane, applied potential increased the As(V) rejection by 48.2% when the applied potential was increased from 0 to 2.0 V for a feed containing 1000 ppb initially. For the same change of applied potential rejection of As(III) was increased from 52.3 to 70.4%; this might be the result of the formation of anionic species like H2AsO3− from the neutral molecule of H3AsO3 by the applied potential. 相似文献
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Microstructure and multifunctional properties of liquid + polymer bicomponent structural electrolytes: Epoxy gels and porous monoliths
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Edwin B. Gienger Phuong‐Anh T. Nguyen Wai Chin Kristopher D. Behler James F. Snyder Eric D. Wetzel 《应用聚合物科学杂志》2015,132(42)
Multifunctional structural batteries and supercapacitors have the potential to improve performance and efficiency in advanced lightweight systems. A critical requirement is a structural electrolyte with superior multifunctional performance. We present here structural electrolytes prepared by the integration of liquid electrolytes with structural epoxy networks. Two distinct approaches were investigated: direct blending of an epoxy resin with a poly(ethylene‐glycol) (PEG)‐ or propylene carbonate (PC)‐based liquid electrolyte followed by in‐situ cure of the resin; and formation of a porous neat epoxy sample followed by backfill with a PC‐based electrolyte. The results show that in situ cure of the electrolytes within the epoxy network does not lead to good multifunctional performance due to a combination of plasticization of the structural network and limited percolation of the liquid network. In contrast, addition of a liquid electrolyte to a porous monolith results in both good stiffness and high ionic conductivity that approach multifunctional goals. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42681. 相似文献
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An Amphiphilic BODIPY‐Porphyrin Conjugate: Intense Two‐Photon Absorption and Rapid Cellular Uptake for Two‐Photon‐Induced Imaging and Photodynamic Therapy
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Dr. Tao Zhang Dr. Rongfeng Lan Longlong Gong Dr. Baoyan Wu Yuzhi Wang Dr. Daniel W. J. Kwong Prof. Wai‐Kwok Wong Dr. Ka‐Leung Wong Prof. Da Xing 《Chembiochem : a European journal of chemical biology》2015,16(16):2357-2364
The new amphiphilic BODPY‐porphyrin conjugate BZnPP and its precursor BZnPH were synthesised, and their linear and two‐photon photophysical properties, together with their cellular uptake and photo‐cytotoxicity, were studied. This amphiphilic conjugate consists of a hydrophobic BODIPY moiety and a hydrophilic tetra(ethylene glycol) chain bridging a cationic triphenylphosphonium group to an amphiphilic porphyrin ZnP through acetylide linkers at its meso positions. A large two‐photon absorption cross‐section (σ=1725 GM) and a high singlet oxygen quantum yield (0.52) were recorded. Intense linear‐ and two‐photon‐induced red emissions were also observed for both BZnPP and BZnPH. Further in vitro studies showed that BZnPP exhibited very efficient cellular uptake and strong photocytotoxic but weak dark cytotoxic properties towards human breast carcinoma MCF‐7 cells. In summary, the two‐photon‐induced emission and the potent photo‐cytotoxicity of BZnPP make it an efficacious dual‐purpose tumour‐imaging and photodynamic therapeutic agent in the tissue‐transparent spectral windows. 相似文献
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均一粒径液滴喷雾干燥塔(MDSD)在生产均匀尺寸颗粒产品中发挥着较大优势,进一步优化其干燥过程操作尤为重要。集成离散相(DPM)和反应工程法(REA)干燥方法,通过耦合分散室和主干燥室模型,本研究开发了完整的MDSD三维计算流体力学模型。并系统探究了在干燥过程中分散气旋流、热空气旋流以及二者共同旋流对颗粒运动和最终干燥效果的影响。模拟结果表明,在30°入射角下加入旋流效果最优。同时引入分散室和干燥室旋流后发现,同向旋流比反向旋流带来的干燥效果提升2%,更比无旋流操作下的干燥效果提升30%。欲达到同样的干燥效果,引入同向旋流,塔身可缩短近12%。 相似文献