把中国建设成世界有色金属制造业基地的对策研究

本文首先介绍了我国有色金属工业的现状以及当前世界有色金属工业发展的新格局,并分析了中国成为世界有色金属制造业基地的支撑条件,最后提出了关于建设具有特色的中国有色金属制造业基地的几点看法。     

One‐step production of 2,3‐butanediol from starch by secretory over‐expression of amylase in Klebsiella pneumoniae

BACKGROUND: 2,3‐Butanediol (2,3‐BD) is a valuable chemical that can be biosynthesized from many kinds of substrates. For commercial biological production of 2,3‐BD, it is desirable to use cheap substrate without pretreatment, such as starch. However, there have been few reports on the production of 2,3‐BD directly from starch. RESULTS: In this work, gene malS coding for α‐amylase (EC 3.2.1.1) precursor was inserted into plasmid pUC18K, and secretory over‐expression of α‐amylase was achieved by engineered Klebsiella pneumoniae. The extracellular recombinant amylase accelerated the hydrolyzation of starch, and one‐step production of 2,3‐BD from starch was carried out by engineered K. pneumoniae. A 2,3‐BD concentration of 3.8 g L^?1 and yield of 0.19 g 2,3‐BD g^?1 starch were obtained after 24 h fermentation. CONCLUSION: The one‐step production of 2,3‐BD from starch was achieved by secretory over‐expression of amylase in K. pneumoniae. This would simplify the process and reduce the production cost considerably by enabling use of starch with minimal pretreatment. Copyright © 2008 Society of Chemical Industry     

Synthesis of p‐aminophenol from the hydrogenation of nitrobenzene over metal–solid acid bifunctional catalyst

BACKGROUND: A single‐step conversion of nitrobenzene (NB) to p‐aminophenol (PAP) through catalytic hydrogenation is a widely used synthesis route for PAP. The main shortcoming of this route is the use of sulfuric acid for rearrangement of the phenylhydroxylamine (PHA) intermediate. In this paper, S₂O₈^2?/ZrO₂ (PSZ) solid acid and Pt‐S₂O₈^2?/ZrO₂ (Pt‐PSZ) bifunctional catalysts were prepared for the synthesis of PAP in non‐acid medium. RESULTS: Calcination temperature has a substantial effect on the acidity, structure and activity for PHA rearrangement of PSZ. The highest PAP yield was 33.8% over PSZ calcined at 823 K when the reaction was carried out in water at 423 K. A high PAP yield of 23.9% was achieved by a single‐step reaction of nitrobenzene over Pt‐PSZ bifunctional catalysts. CONCLUSION: PSZ solid acid exhibits high activity for PHA rearrangement. Perfect tetragonal ZrO₂ and much stronger acid sites play important roles in catalytic activity. Inhibiting the hydrogenation activity by reducing the amount of Pt loading on Pt‐PSZ can improve the competition of PHA rearrangement on acid sites with hydrogenation of PHA on metal active sites, resulting in better selectivity to PAP. Copyright © 2008 Society of Chemical Industry     

准噶尔盆地吉木萨尔凹陷东斜坡油源及成藏分析

油气源对比结果表明，准噶尔盆地吉木萨尔凹陷东斜坡原油分为两类，第Ⅰ类原油为低成熟一成熟油，来源于吉木萨尔凹陷二叠系平地泉组烃源岩；第Ⅱ类原油为高成熟油，来源于该区二叠系石炭系烃源岩。来自吉木萨尔凹陷二叠系平地泉组烃源岩的梧桐沟组的第Ⅰ类原油，根据生物降解程度可分为，未遭受生物降解的原油，遭受轻微生物降解的原油和遭受中等生物降解的原油。吉木萨尔凹陷东斜坡梧桐沟组原油至少存在两期油气成藏。     

龙滩电站大法坪料场爆破施工技术研究

结合龙滩水电站大法坪料场爆破的技术难点,针对不同的岩石和要求,通过对采场的爆破分区,应用车制乳化炸药使料场开挖爆破施工取得成功,爆破料级配良好,满足了供料强度要求。     

提高高炉煤比的措施与效果

分析了影响高炉煤比提高的主要因素，提出了提高高炉煤比的改进措施，通过技术攻关，高炉煤比在无富氧条件下达到了100kg／t以上，降本增效效果明显。     

沁水煤田瓦斯含量与地质因素的关系

为确实做好瓦斯的洲报工作，研究了沁水煤田地质因素与瓦斯含量的关系，辩证地分析了瓦斯的赋存规律。     

埕岛油田东部斜坡带东下段沉积特征及油藏类型研究

埕岛油田东部斜坡带下第三系油藏以三角洲、浊积扇砂体隐蔽油气藏为主，储层埋藏深、厚度变化大，油气成藏复杂。通过对该带的沉积特征、沉积体系和沉积物源的研究，指出其东下段砂体的分布主要受物源和沉积相带两方面控制，砂体只有在有效圈闭情况下才能成藏，并且从构造上总结了三种油藏类型。最后指出该带下一步勘探重点是沿主物源方向展布的、成藏条件良好的各种砂体。     

水上地震折射互换法误差分析

在理论上，用源检互换的方法进行折射地震勘探是没有误差的，在某些特殊条件下无法铺设检波器而又必须进行折射地震勘探时它也是唯一的选择，然而，在实际工作中，由于各种因素的影响，其误差是不可忽略的。为此，本文从地震折射运动学的角度对水上地震折射互换法因过河钢丝绳的重量、水的流速和流向、炮点深度等客观因素造成的解释误差进行了分析，揭示了水上地震折射互换法应注意的问题。这对水上地震折射互换法的资料解释进行误差校正提供了理论基础。     

Evaporation induced self-assembly of zeolite A micropatterns due to the stick-slip dynamics of contact line

In this study, a new surfactant-solvent system was described for the preparation of periodic stripe patterns of zeolite A on solid substrates. The evaporation induced self-assembly of zeolite A particles was due to the stick-slip dynamics of the three-phase contact line of the colloid solutions in acetone containing 10% (v/v) poly(dimethylsiloxane) (PDMS) fluid (2 cst.). In order to investigate the possible effects of particle size and the particle concentration on the stick-slip dynamics, three types of zeolite A samples with different particle sizes (zeolite A-I: 250-500 nm, zeolite A-II: 100-250 nm and zeolite A-III: 0-100 nm) were utilized to prepare 0.007-0.06% (w/v) colloidal dispersions. Zeolite A micropatterns were self-assembled on the surface of glass, high density polyethylene (HDPE) and poly(tetrafluoroethylene) (PTFE) substrates, which were placed vertically inside the colloid solutions and held against the wall of the cylindrical vial during the evaporation of acetone. The stripe patterns of zeolite A particles were analyzed with field emission scanning electron microscope (FE-SEM) and optical microscope. The widths of microstripes and the distance between the stripes were found as 2-20 μm and 40-60 μm respectively depending on the particle concentration. By using the stick-slip dynamics of colloids, the linear micropatterns of zeolite A nanocrystals were prepared with low cost and low energy.