A silica sol-gel design strategy for nanostructured metallic materials

Batteries, fuel cells and solar cells, among many other high-current-density devices, could benefit from the precise meso- to macroscopic structure control afforded by the silica sol-gel process. The porous materials made by silica sol-gel chemistry are typically insulators, however, which has restricted their application. Here we present a simple, yet highly versatile silica sol-gel process built around a multifunctional sol-gel precursor that is derived from the following: amino acids, hydroxy acids or peptides; a silicon alkoxide; and a metal acetate. This approach allows a wide range of biological functionalities and metals--including noble metals--to be combined into a library of sol-gel materials with a high degree of control over composition and structure. We demonstrate that the sol-gel process based on these precursors is compatible with block-copolymer self-assembly, colloidal crystal templating and the St?ber process. As a result of the exceptionally high metal content, these materials can be thermally processed to make porous nanocomposites with metallic percolation networks that have an electrical conductivity of over 1,000 S cm(-1). This improves the electrical conductivity of porous silica sol-gel nanocomposites by three orders of magnitude over existing approaches, opening applications to high-current-density devices.     

Nanotoxicology. No signs of illness

Quantum dots that contain cadmium, selenium and zinc are not toxic to monkeys for periods of up to 90 days, but longer-term studies are needed to determine the ultimate fate of the heavy metals that accumulate in the organs.     

Preparation of diamond like carbon thin films above room temperature and their properties

Diamond like carbon (DLC) thin films were deposited on p-type silicon (p-Si), quartz and ITO substrates by microwave (MW) surface-wave plasma (SWP) chemical vapor deposition (CVD) at different substrate temperatures (RT ∼ 300 °C). Argon (Ar: 200 sccm) was used as carrier gas while acetylene (C₂H₂: 20 sccm) and nitrogen (N: 5 sccm) were used as plasma source. Analytical methods such as X-ray photoelectron spectroscopy (XPS), FT-IR and UV–visible spectroscopy were employed to investigate the structural and optical properties of the DLC thin films respectively. FT-IR spectra show the structural modification of the DLC thin films with substrate temperatures showing the distinct peak around 3350 cm^− 1 wave number; which may corresponds to the sp² C–H bond. Tauc optical gap and film thickness both decreased with increasing substrate temperature. The peaks of XPS core level C 1 s spectra of the DLC thin films shifted towards lower binding energy with substrate temperature. We also got the small photoconductivity action of the film deposited at 300 °C on ITO substrate.     

The mental representation of music notation: Notational audiation.

This study investigated the mental representation of music notation. Notational audiation is the ability to internally "hear" the music one is reading before physically hearing it performed on an instrument. In earlier studies, the authors claimed that this process engages music imagery contingent on subvocal silent singing. This study refines the previously developed embedded melody task and further explores the phonatory nature of notational audiation with throat-audio and larynx-electromyography measurement. Experiment 1 corroborates previous findings and confirms that notational audiation is a process engaging kinesthetic-like covert excitation of the vocal folds linked to phonatory resources. Experiment 2 explores whether covert rehearsal with the mind's voice also involves actual motor processing systems and suggests that the mental representation of music notation cues manual motor imagery. Experiment 3 verifies findings of both Experiments 1 and 2 with a sample of professional drummers. The study points to the profound reliance on phonatory and manual motor processing--a dual-route stratagem--used during music reading. Further implications concern the integration of auditory and motor imagery in the brain and cross-modal encoding of a unisensory input. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

VME培育结构化技术的未来

各娄新型嵌入式结构在高性能应用中相互竞争，值得敬重的VMEbus供应商则用结构化策略描绘着保持生存和未来发展的蓝图。     

AC and DC electromigration failure of aluminum contact junctions

Current flow across a typical aluminum contact interface occurs only where metallic junctions form at cracks in the insulating aluminum oxide. When the total metallic conducting area is small, current density may be high enough to initiate electromigration failure. These experiments use a solid aluminum specimen having a constricted current path, representing a single metallic contact junction. Specimens are tested with alternating or direct current flow at current density up to 10/sup 6/ A/cm/sup 2/. Electromigration failure, observed as a relatively abrupt increase of resistance, occurs in both ac and dc specimens. Electron microscope examination indicates that the deterioration is due to electromigration. Conditions under which electromigration deterioration may occur in practical aluminum power connections are discussed. A method is provided for estimating the minimum possible current density in aluminum connections. The implications for the theory of aluminum contact behavior and the practical considerations of effective life testing are discussed.     

Heroin addicts have higher discount rates for delayed rewards than non-drug-using controls.

Fifty-six heroin addicts and 60 age-matched controls were offered choices between monetary rewards ($11–$80) available immediately and larger rewards ($25–$85) available after delays ranging from 1 week to 6 months. Participants had a 1-in-6 chance of winning a reward that they chose on one randomly selected trial. Delay-discounting rates were estimated from the pattern of participants' choices. The discounting model of impulsiveness (G. Ainslie, 1975) implies that delay-discounting rates are positively correlated with impulsiveness. On average, heroin addicts' discount rates were twice those of controls (p?=?.004), and discount rates were positively correlated with impulsivity as measured by self-report questionnaires (p?     

Characterization of Surface-Breaking Cracks Using One Tangential Component of Magnetic Leakage Field Measurements

We propose a procedure for full characterization of rectangular surface-breaking cracks based on measurements of only one tangential component of the magnetic field with the magnetic flux leakage (MFL) technique. The parameters of interest include orientation, length, and depth of the cracks. We assume that the length and the depth of the investigated cracks are much larger than the crack width, so that the variation of the MFL response with respect to the width is negligible. Our procedure employs fast direct methods that provide reliable estimation of the crack parameters in three separate consecutive steps. We propose denoising and correction techniques as well. We confirmed the accuracy of the methods by simulations based on the finite-element method (FEM) as well as by experimental MFL observations. A procedure is proposed for full characterization of rectangular surface breaking cracks based on measurements of only one tangential component of the magnetic field with the magnetic flux leakage (MFL) technique. The parameters of interest include orientation, length and depth of the cracks. We assume that the length and the depth of the investigated cracks are much larger than the crack width such that the variation of the MFL response with respect to the width is negligible. The proposed procedure employs fast direct methods which provide reliable estimation of the crack parameters in three separate consecutive steps. De-noising and correction techniques are proposed as well. The accuracy of the proposed estimation methods is examined via simulations based on the finite element method (FEM) as well as experimental MFL data.