Investigation of Scale Formation in Heat Exchangers of Phosphoric Acid Evaporator Plants

The primary problem in concentrating phosphoric acid is due to fouling on the tube‐side of the heat exchangers of the evaporator units. Scaling on the heat transfer surfaces occurs because of high supersaturation of phosphoric acid liquor with respect to calcium sulphate. A review of the existing literature reveals that no information is available on heat transfer and on crystallization fouling of industrial phosphoric acid solutions. In this investigation, the solubility of different calcium sulphate types in phosphoric acid solution was studied and its dependency on acid concentration and temperature was investigated. A large number of fouling experiments were carried out in a side‐stream of a phosphoric acid plant at different flow velocities, surface temperatures and concentrations to determine the mechanisms, which control the deposition process. After identifying the effects of operational parameters on the deposition process, a model was developed for prediction of fouling resistances. The reaction of calcium sulphate crystallization followed a second order rate with respect to the supersaturation. The activation energy evaluated for the surface reaction of the deposit formation was found to be 57 kJ/mol. The predicted fouling resistances were compared with the experimental data. Quantitative and qualitative agreement between measured and predicted fouling rates is good.     

工程施工合同履行中的索赔

本文着重介绍工程施工合同履行中索赔的预防，通过签订合同开始到施工过程结束全过程的控制。从施工企业的角度出发寻求索赔机会。     

Adhesive Contact of a Membrane with a Hemispherical Indenter: Theoretical Analysis and Model Liquid System

The axisymmetric Laplace equation is solved numerically to extract contact-angle data for a flat liquid/vapor interface contacting a submerged hemispherical solid. The liquid/vapor interface is treated as a membrane, with a membrane tension equal to the surface energy of the liquid. By measuring the vertical displacement of the membrane and the projected contact area the membrane makes with the hemisphere, the contact angle and correspondingly the driving force for motion of the contact line can be measured. We show that characteristic receding and advancing contact angles can be obtained by measuring the contact radii formed upon initial contact between the interface and hemisphere and final contact just prior to detachment of the interface, respectively. Use of the technique is illustrated with a model experiment involving the contact of an air/water interface with a poly(methyl methacrylate) surface.     

浅谈建筑施工企业的预算与工程成本核算

从建筑施工企业的基础管理、科学分类、严格考核几个关键环节，论述了建设项目专业管理，在保证安全、质量、工期的前提下，以最低的消耗取得最佳的经济效益。     

风险评估在加氢装置的应用

广州石化加氢（二）B装置采用基于风险的检测（RBI）技术，对装置的静设备与管道使用RBI软件RB—eye进行定量、定性分析以及失效概率、失效后果的评价，评估了装置的风险情况，制定了装景基于风险分析的检验策略。     

两种自主开发的图形外延SiGe工艺

使用清华大学微电子学研究所研发的UHV/CVD系统深入研究了图形外延SiGe工艺,分别选用单一的SiO2介质层和SiO2/P0ly-Si复合介质层,作为图形外延SiGe单晶材料的窗口屏蔽介质,开发出了不同的实用化图形外延SiGe工艺.     

四川盆地中部上三叠统香溪群岩性油气藏圈闭类型及其特征

四川盆地川中地区构造平缓,大型断裂欠发育,已发现的油气藏与背斜关系并不十分密切。研究认为,川中地区香溪群主要发育岩性圈闭,根据圈闭形成主控因素,结合香溪群沉积前的古地貌特征和裂缝发育特点,将川中香溪群岩性圈闭划分为4种类型:①与地层尖灭相关的地层—岩性圈闭;②与沉积—成岩相变密切相关的成岩—岩性圈闭;③与古地貌有关的差异压实作用形成的岩性圈闭;④与断层转化调节相关的裂缝—岩性复合圈闭。其中成岩—岩性圈闭和地层—岩性圈闭,是川中香溪群最重要的、分布最广泛的圈闭类型。     

Application of asymptotic waveform evaluation to eigenmode expansion method for analysis of simultaneous switching noise in printed circuit boards (PCBs)

In this paper, the asymptotic waveform evaluation (AWE) technique is first applied to the conventional eigenmode expansion method for characterizing a power/ground (P/G) plane pair and analyzing the simultaneous switching noise on such plane pairs for printed circuit boards or multichip modules. The application of AWE avoids a large number of iterations in computing the impedance frequency response of a P/G plane pair structure and greatly reduces the computation time. Meanwhile, to obtain an accurate solution in an entire frequency range, we employ the complex frequency hopping technique which can help select multiple expansion points. In addition, the proposed approach can also be used to characterize the P/G plane pair structures with irregular shapes. Three examples demonstrate its high efficiency and good accuracy.     

Preparation and characterization of polyurethane microcapsules containing n‐octadecane with styrene‐maleic anhydride as a surfactant by interfacial polycondensation

A series of polyurethane microcapsules containing a phase change material (PCM) of n‐octadecane was successfully synthesized by an interfacial polymerization in aqueous styrene‐maleic anhydride (SMA) dispersion with diethylene triamine (DETA) as a chain extender reacting with toluene‐2,4‐diisocyanate (TDI). The average diameter of microPCMs is in the range of 5–10 μm under the stirring speed of 3000–4000 rpm. Optical and SEM morphologies of microPCMs had ensured that the shell was regularly fabricated with the influence of SMA. FTIR results confirmed that the shell material was polyurethane and the SMA chains associated on core material reacted with TDI forming a part of shell material. The shell thickness was decreasing in the range of 0.31–0.55 μm with the molar ratio of DETA/TDI from 0.84 to 1.35 and the weight of core material increasing from 40 to 80% (wt %). By controlling the weight ratio of PCM as 40, 50, 60, 70, and 80% in microPCMs, it was found using DSC that the T_m and T_c of microPCMs were in the range of 29.8–31.0^oC and 21.1–22.0°C and an obvious phase change had been achieved nearly the same temperature range of that of PCM. The results from release curves of microPCM samples prepared by 1.4, 1.7, and 2.0 g of SMA indicated the release properties were affected by the amount of the dispersant, which attributed to the emulsion effect and shell polymerization structure. The above results suggest that the shell structure of microPCMs can be controlled and the properties of microPCMs determined by shell will perform proper practical usage. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 4996–5006, 2006