Modulation on the electrical and optical properties of Na and Rh co-doped Ruddlesden-Popper layered Ca3Ti2O7

Layered perovskite Ca_2.91Na_0.09Ti_2-xRh_xO₇ (x?=?0.00, 0.02, 0.04, 0.06) were synthesized by a conventional solid-state reaction. Room temperature ferroelectricity has been confirmed. The remanent polarization increases with an increase of Rh content, which is due to a larger oxygen octahedral distortion by Rh doping. The coercive field increases with Rh doping as the pinning effect of oxygen vacancies reduce the mobility of domain wall. Remanent polarization and coercive field are caused by different mechanisms, so it is possible to modulate them independently to meet the requirement of application in ferroelectric field. The concentration of oxygen vacancy increased with Rh doping, leading to the significant increase of leakage current density. The bandgap of samples doped with Rh drastically decrease and the visible light response of the sample was improved by Rh doping due to the formation of impurity energy levels within the band gap.

     

天然橡胶/顺丁橡胶共混物疲劳历程的研究

采用扫描电子显微镜、电性能测定和热重法等分析手段，研究了炭黑补强的天然橡胶／顺丁橡胶共混硫化胶的疲劳历程，探索了其内在的疲劳损伤机理。     

热压烧结Ti3AlC2材料的制备、结构与性能研究

采用热压工艺研究了不同工艺制度和原料中不同的Si含量对Ti3AlC2合成的影响.研究表明在1 300℃～1 500℃,30MPa压力和Ar气氛中热压摩尔比为n(TiC)n(Ti)n(Al)n(Si)=2110.2的混合粉末,可以得到纯度达98%(质量分数)以上的致密块体Ti3AlC2材料;添加的Si均匀分布在基体中,形成固溶体,当添加Si的摩尔比为0.2时,固溶体的化学式为Ti2 76Al0 78Si0.22C2.烧结试样的晶体为层片状结构,1 300℃和1 400℃时,烧结试样的晶粒尺寸分别为10μm～15μm和20μm～30μm.材料的维氏硬度为3.3 GPa～5.0 GPa,弹性模量为289 GPa,抗压强度为785 MPa,抗弯强度为375 MPa,断裂韧性为7.0 MPa·m1/2;25℃时,电导率为3.1×106 S·m-1,热容为125.4 J/mol·K,热导率为27.5 W/m·K;热膨胀系数为8.8×10-6 K-1.     

Zr－1Nb合金吸氢性能研究

研究了１３种不同加工热处理制度的Ｚｒ－１Ｎｂ合金在堆外高压釜内３６０℃、１９ＭＰａ水中的吸氢性能，对其影响因素和吸氢机理进行了分析，并讨论了吸氢动力学，建立了吸氢动力学方程，计算了吸氢动力学参数。     

Electrochemical Study on Formation of Dy-Ni Alloy in Molten Chlorides

ＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＳｔｕｄｙｏｎＦｏｒｍａｔｉｏｎｏｆＤｙ－ＮｉＡｌｌｏｙｉｎＭｏｌｔｅｎＣｈｌｏｒｉｄｅｓＴｏｎｇＹｅｘｉａｎｇ；ＬｉｕＧｕａｎｋｕｎ；ＹａｎｇＱｉｑｉｎ；ＨｏｎｇＨｕｉｃｈａｎ，（童叶翔）（刘冠昆）（杨绮琴）（洪惠婵）...     

我国火电锅炉和电站用钢管的现状与发展

介绍了我国火电锅炉和电站用钢管的现状，以及国内外发展趋势。     

LX—2型变频式喂线设备的研制及应用

根据炼钢生产的实际需要,分析了喂线技术的工艺要求,介绍了所研制的LX－2型变频式喂线机的结构特点,指出了影响喂线机使用效果的因素,并提出了若干措施。     

AN EXPERIMENTAL-NUMERICAL METHOD FOR MEASURING CRACK PROPAGATING VELOCITIES UNDER STRESS WAVE LOADING

An experimental-numerical method for measuring dynamic crack propagating velocities under stress wave loading is established in this paper. The experiments of the three-point bend specimen are done on the improved Hopkinson bar. Deflection of loading point, dynamic load and instantaneous crack length are measured, then crack propagating velocities are calculated. Experiments on 40Cr steel show that the results given by this method have a good agreement with that obtained by the resistance fracture gage method. Therefore this method is feasible for measuring crack propagating velocities under high loading rate and will have wide application.     

基于Rough集的磨削参数决策系统

本文介绍了5层模糊神经网络的优缺点，提出了基于Rough集构造模糊神经网络的方法，并应用于多传感器的磨削参数决策系统，达到控制磨削加工质量的目的。     

冶金工业的发展及其对冶金轧辊的需求

从冶金工业的发展现状可知高质量的轧辊仍是一个很大的市场。高速钢轧辊具有很强的竞争力。离心铸造法生产高速钢轧辊是主要的工艺方法。