全文获取类型
收费全文 | 76141篇 |
免费 | 16215篇 |
国内免费 | 2164篇 |
专业分类
电工技术 | 3142篇 |
技术理论 | 3篇 |
综合类 | 3178篇 |
化学工业 | 22468篇 |
金属工艺 | 2479篇 |
机械仪表 | 3141篇 |
建筑科学 | 4467篇 |
矿业工程 | 1340篇 |
能源动力 | 2002篇 |
轻工业 | 9750篇 |
水利工程 | 1029篇 |
石油天然气 | 1649篇 |
武器工业 | 296篇 |
无线电 | 11176篇 |
一般工业技术 | 15628篇 |
冶金工业 | 2583篇 |
原子能技术 | 484篇 |
自动化技术 | 9705篇 |
出版年
2024年 | 163篇 |
2023年 | 609篇 |
2022年 | 1089篇 |
2021年 | 1725篇 |
2020年 | 2502篇 |
2019年 | 4042篇 |
2018年 | 4063篇 |
2017年 | 4502篇 |
2016年 | 4872篇 |
2015年 | 5321篇 |
2014年 | 5659篇 |
2013年 | 7158篇 |
2012年 | 5107篇 |
2011年 | 4777篇 |
2010年 | 4934篇 |
2009年 | 4637篇 |
2008年 | 4150篇 |
2007年 | 3867篇 |
2006年 | 3569篇 |
2005年 | 3041篇 |
2004年 | 2621篇 |
2003年 | 2824篇 |
2002年 | 3260篇 |
2001年 | 2824篇 |
2000年 | 2150篇 |
1999年 | 1326篇 |
1998年 | 693篇 |
1997年 | 574篇 |
1996年 | 439篇 |
1995年 | 395篇 |
1994年 | 324篇 |
1993年 | 225篇 |
1992年 | 203篇 |
1991年 | 183篇 |
1990年 | 138篇 |
1989年 | 103篇 |
1988年 | 97篇 |
1987年 | 62篇 |
1986年 | 51篇 |
1985年 | 45篇 |
1984年 | 23篇 |
1983年 | 20篇 |
1982年 | 20篇 |
1981年 | 21篇 |
1980年 | 27篇 |
1979年 | 15篇 |
1978年 | 7篇 |
1977年 | 12篇 |
1976年 | 10篇 |
1975年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
11.
N. Jongen M. Donnet P. Bowen J. Lemaître H. Hofmann R. Schenk C. Hofmann M. Aoun‐Habbache S. Guillemet‐Fritsch J. Sarrias A. Rousset M. Viviani M.T. Buscaglia V. Buscaglia P. Nanni A. Testino J.R. Herguijuela 《化学工程与技术》2003,26(3):303-305
The synthesis of powders with controlled shape and narrow particle size distributions is still a major challenge for many industries. A continuous Segmented Flow Tubular Reactor (SFTR) has been developed to overcome homogeneity and scale‐up problems encountered when using batch reactors. Supersaturation is created by mixing the co‐reactants in a micromixer inducing precipitation; the suspension is then segmented into identical micro‐volumes by a non‐miscible fluid and sent through a tube. These micro‐volumes are more homogeneous when compared to large batch reactors leading to narrower size distributions, better particle morphology, polymorph selectivity and stoichiometry. All these features have been demonstrated on single tube SFTR for different chemical systems. To increase productivity for commercial application the SFTR is being “scaled‐out” by multiplying the number of tubes running in parallel instead of scaling‐up by increasing their size. The versatility of the multi‐tube unit will allow changes in type of precipitate with a minimum of new investment as new chemistry can be researched, developed and optimised in a single tube SFTR and then transferred to the multi‐tube unit for powder production. 相似文献
12.
13.
14.
The objectives of this study were to evaluate the possible mechanisms involved in prolongation of bleeding time in pre-eclamptic patients receiving a magnesium sulfate infusion to prevent convulsions. Eighteen pre-eclamptic patients near term or at term (4 cases 33 to 35 weeks; the remainder > 36 weeks) were studied. Fifteen of them received magnesium sulfate infusion; 3 did not and served as controls. Bleeding time (modified Ivy method with Surgicutt), platelet count, platelet aggregation pattern, as well as serum arachidonic acid metabolites [thromboxane B2 (TxB2) and 6-Keto-prostaglandin F1 alpha (6-Keto-PGF1 alpha)] werde done on admission to the labor floor (before magnesium infusion) and repeated at discontinuation of the infusion, 12-24 hours postpartum; the controls received the second test 24 hours postpartum. Thirteen of 15 patients receiving magnesium sulfate had an increase in bleeding time from an average of 6 minutes 31 seconds to 11 minutes 56 seconds, an 82% rise (p < 0.004). In 2 there was a decrease. Among the 3 controls the averages were 6 minutes 38 seconds and 6 minutes 3 seconds. The total magnesium given ranged from 52.5 to 145 grams. Platelet counts averaged 251,000/mm3 (range 145,000-519,000). Platelet aggregation pattern done in 11 patients and was normal and unchanged after magnesium in 10 of the patients with increased bleeding time and one control. TxB2 and 6-Keto-PGF1 alpha levels did not change significantly either after magnesium administration (688 and 135 pgm/ml, to 654 and 117) or in controls (695 and 230 pgm/ml, to 445 and 225). Likewise, the ratio of these 2 substances did not change in either group (6.3 to 6.6, and 4.2 to 2.2). There was no correlation between duration of infusion or total magnesium given and directions of small changes observed. This study confirms a prior preliminary observation that magnesium sulfate infusion, as currently used to prevent eclamptic convulsions, induces a significant prolongation of bleeding time. This effect is mediated neither by changes in platelets count or aggregation pattern, nor by changing the level or ratios of serum arachidonic acid metabolites (TxB2 and 6-Keto-PGF1 alpha). Further studies are needed to clarify the mechanism of this clinically important observation of increased bleeding following magnesium sulfate infusion. 相似文献
15.
Flame structure and NO emission characteristics in counterflow diffusion flame of blended fuel of H2/CO2/Ar have been numerically simulated with detailed chemistry. The combination of H2, CO2 and Ar as fuel is selected to clearly display the contribution of hydrocarbon products to flame structure and NO emission characteristics due to the breakdown of CO2. A radiative heat loss term is involved to correctly describe the flame dynamics especially at low strain rates. The detailed chemistry adopts the reaction mechanism of GRI 2.11, which consists of 49 species and 279 elementary reactions. All mechanisms including thermal, NO2, N2O and Fenimore are taken into account to separately evaluate the effects of CO2 addition on NO emission characteristics. The increase of added CO2 quantity causes flame temperature to fall since at high strain rates a diluent effect is prevailing and at low strain rates the breakdown of CO2 produces relatively populous hydrocarbon products and thus the existence of hydrocarbon products inhibits chain branching. It is also found that the contribution of NO production by N2O and NO2 mechanisms are negligible and that thermal mechanism is concentrated on only the reaction zone. As strain rate and CO2 quantity increase, NO production is remarkably augmented. Copyright © 2002 John Wiley & Sons, Ltd. 相似文献
16.
Brian M. Louie Thomas Franaszek Tina Pho Wen Yen Chiu David S. Soong 《应用聚合物科学杂志》1985,30(9):3841-3856
Oxygen injection has been proposed and experimentally demonstrated as an effective control measure for limiting the rate of heat release and altering the rate of polymerization in emulsion processes. A detailed mathematical model has been previously developed to describe the system behavior with and without oxygen injection. A simple lab scale apparatus was constructed and run extensively. Only trace quantities of oxygen are needed to inhibit the reaction completely. The facile response makes this method attractive for fast temperature control. However, because of the rapid penetration of dissolved oxygen into the polymer particles, growing radical chains are terminated prematurely, lowering product molecular weights. To minimize this detrimental effect, pulsed oxygen control is used and extensive experimental work was performed to determine the effects of controller set points on molecular weight. Moderate oxygen flows and moderate set point temperatures are found to give the optimal response without significant lowering of the final molecular weight. Injected quantities agree well with the order-of-magnitude sparging calculations needed to completely stop initiation. However, complete agreement between model simulations and experimental results was not reached due to an unmeasured loss of monomer from the reactor. Chain transfer to monomer is found to be important in modeling the polymer molecular weight. It has, however, a negligible effect on the reaction rate. 相似文献
17.
地源热泵——辐射地板联供试验 总被引:3,自引:0,他引:3
通过地源热泵-辐射地板系统冬夏联供试验,讨论了该系统作为新型环保节能空调方式的可行性及优越性,并对运行中出现的问题进行分析。 相似文献
18.
Hong Jeong Jeong‐Ho Park 《International Journal of Adaptive Control and Signal Processing》2002,16(1):1-23
Tracking targets of interest is one of the major research areas in radar surveillance systems. We formulate the problem as incomplete data estimation and apply EM to the MAP estimate. The resulting filter has a recursive structure analogous to the Kalman filter. The advantage is that the measurement‐update deals with multiple measurements in parallel and the parameter‐update estimates the system parameters on the fly. Experiments tracking separate targets in parallel show that tracking maintenance ratio of the proposed system is better than that of NNF and RMS position error is smaller than that of PDAF. Also, the system parameters are correctly obtained even from incorrect initial values. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
19.
20.
Yu‐Qing Cao Zhan Zhang Yan‐Xin Guo 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(10):1441-1444
A new efficient method for synthesising nitriles, important organic reagents, is reported in this paper. In an environmentally benign solvent‐free system, aryl carboxylic acids were converted into the corresponding nitriles via one‐pot reactions, by amidation with ethyl carbamate followed by dehydration with thionyl chloride, in excellent yields. The results showed that the method has the advantages of lower cost, higher yield, less pollution and greater ease of work‐up. Copyright © 2008 Society of Chemical Industry 相似文献