用金属卟啉络合物引发合成高分子量聚醚

介绍了用四苯基卟啉铝络合物催化体系合成高分子量聚醚的方法。该聚合过程显示出一种持续特性。产物具有均一的链长和极窄的分子量分布，且数均分子量Ｍｎ可通过改变单体与引发剂的摩尔比来控制。     

煤炭漏斗车装卸载过程仿真

煤炭漏斗车端、侧墙侧压力是车体静强度校核中的重要作用载荷.运用离散单元法,建立煤炭漏斗车仿真模型,对装卸载过程中车体所受的侧压力进行了仿真分析,并对车体内部的压力场和速度场的分布情况进行了分析.仿真结果表明,装载平衡后,端、侧墙侧压力沿墙高呈非线性分布;卸载过程中,侧墙侧压力呈现明显的波动变化.研究结果说明,离散单元法用于模拟和分析漏斗车车体压力及散粒体流动规律是可行的.仿真结果对漏斗车车体结构的研发具有一定的现实指导意义.     

一种适用于智能设备的多重操作系统架构

针对智能设备,为避免引入虚拟化技术而产生的性能开销,提出并实现了MuxOS。MuxOS是一种多重操作系统架构,使得智能设备可以在非虚拟化条件下运行多个操作系统。介绍了MuxOS工作原理,描述了MuxOS运行流程。测试结果表明, MuxOS性能优于Xen等虚拟化产品,可以实现操作系统间亚秒级的快速切换。     

椭圆曲线密码中抗功耗分析攻击的标量乘改进方案

椭圆曲线标量乘法运算是椭圆曲线密码(ECC)体制中最主要的计算过程,标量乘法的效率和安全性一直是研究的热点。针对椭圆曲线标量乘运算计算量大且易受功耗分析攻击的问题,提出了一种抗功耗分析攻击的快速滑动窗口算法,在雅可比和仿射混合坐标系下采用有符号滑动窗口算法实现椭圆曲线标量乘计算,并采用随机化密钥方法抵抗功耗分析攻击。与二进制展开法、密钥分解法相比的结果表明,新设计的有符号滑动窗口标量乘算法计算效率、抗攻击性能有明显提高。     

浅谈导师制项目在毕业设计的积极作用

高校中的本科生导师制在本科生教育中起到积极作用,针对网络工程专业特点,创新地推行导师制项目制度,由学生在学习阶段直接参加导师的科研项目。在指导教师指导下设计项目方案、进行系统设计和系统编码、撰写科研报告,并探索导师制项目在毕业设计所起到的积极作用．为校内其他专业及校外推广这项制度打下良好的基础。     

Development of density distributions in injection molded amorphous engineering plastics. Part I

The gapwise density distributions of the injection molded specimens of two engineering thermoplastics, i.e., poly(phenylene ether) and poly(ether imide), were characterized employing the density gradient column technique. The samples were molded using a 40t Van Dorn injection molding machine. The effects of the thermal history on the density distribution of unconstrained quenched specimens were also investigated. In addition, various material properties, such as pressure-volume-temperature, isothermal contraction, and pressure induced densification behavior were characterized, for the two resins employed in this study. The moldings of the two resins exhibited different trends in their density distributions. These findings were explained in terms of the competing effects of cooling rate and the pressure history experienced by the engineering plastic resins during the molding cycle. The data collected were also used as input to mathematical modeling of density distributions in injection molded articles, which is reported in Part II of this article.     

模拟流程图组态软件动态部件显示开发

模拟流程图功能是核电DCS控制系统的重要组成部分,而流程图的组态则是该功能实现的基础。模拟流程图组态由静态元素和动态元素图元组成,针对模拟流程图中动态元素的实现进行分析讨论,设计模板实现动态元素图元的动态显示,并采用C语言脚本设计实现动态元素图元的显示更新和事件操作响应。最后验证模拟流程图组态软件完成的流程图在核电DCS系统二层人机显示软件运行稳定。     

Effects of metal-support interactions on the synthesis of methanol over palladium

The synthesis of methanol and other products from CO and H₂ was studied over Pd catalysts prepared by adsorption of Pd(π-C₃H₃)₂ on MgO, ZnO, La₂O₃, γ-Al₂O₃, SiO₂, TiO₂, and ZrO₂ as well as over a SiO₂-supported Pd catalyst prepared from PdCl₂ and Pd black. Both the activity and selectivity of Pd were affected strongly by the nature of the support and the composition of the Pd precursor. The specific activity for methanol synthesis decreased in the order $\text{Pd}\text{La}{}_2\text{O}{}_3$ ? $\text{Pd}\text{SiO}{}_2$ [derived from PdCl₂] > $\text{Pd}\text{ZrO}{}_2$ > $\text{Pd}\text{ZnO}\text{≈}\text{Pd}\text{MgO}$ > PdTiO₂ > $\text{Pd}\text{Al}{}_2\text{O}{}_3\text{≈}\text{Pd}\text{SiO}{}_2$ [derived from Pd(π-C₃H₅)₂] ? Pd black, while the specific activity for hydrocarbon synthesis decreased in the order $\text{Pd}\text{TiO}{}_2\text{?}\text{Pd}\text{ZrO}{}_2$ > $\text{Pd}\text{La}{}_2\text{O}{}_3$ > $\text{Pd}\text{Al}{}_2\text{O}{}_3\text{≈}\text{Pd}\text{SiO}{}_2$ [derived from PdCl₂] ? $\text{Pd}\text{SiO}{}_2$ [derived from Pd(π-C₃3H₅)₂] ≈ Pd black ? $\text{Pd}\text{MgO}\text{?}\text{Pd}\text{ZnO}$. Dimethyl ether production was observed over four of the catalysts and the activity for formation of this product decreased in the order $\text{Pd}\text{Al}{}_2\text{O}{}_3\text{?}\text{Pd}\text{TiO}{}_2\text{?}\text{Pd}\text{MgO}\text{≈}\text{Pd}\text{ZrO}{}_2$. The effects of support composition on the catalytic properties of Pd are discussed in the light of current ideas concerning metal-support interactions and the acid-base properties of the support.     

Gel chromatographic investigation of p-benzoquinone and styrene products copolymerized in the presence of BF3·OEt2

The molecular weight distribution of copolymers of p-benzoquinone and styrene was studied by g.p.c.. It was shown that the products synthesized have low molecular weights and narrow MWD. p-Benzoquinone was found to be a copolymer macromolecule regulator.     

红外吸收法测硅铁中的超低硫

应用高频红外碳硫仪,建立了硅铁合金中超低硫测定方法,对选择适当的测定条件如助熔剂、分析时间等进行了探讨,最佳测定条件:最大工作电流为400～480 mA;载气纯度为99.99%;陶瓷坩埚需经1 100℃灼烧2 h后,可使空白降至最小;硫元素最短分析时间为40 s,比较水平为5.00.