粗苯甲酸甲酯的精制

介绍用加介质减压精馏方法除掉与苯甲酸甲酯 (BE)伴生的杂质。用减压精馏可以除掉与BE沸点相差较大的组分。采用加H2 O2 和加NaHSO3反应萃取 2种方法除醛后 ,再加酸性介质减压精馏 ,可使提纯后的BE的质量分数达到 99%～ 99.9%。操作条件是精馏塔的压力为 1.3 3kPa ,温度为 90～ 95℃ ,塔顶温度为 65～ 68℃ ,理论塔板数为 5 4。     

Synthesis and light‐emitting properties of new poly(p‐phenylenevinylene) derivatives containing oxadiazole moiety

Two new poly(p‐phenylenevinylene) (PPV) derivatives containing oxadiazole moiety (OXA‐PPV1 and OXA‐PPV2) were synthesized by the Wittig condensation polymerization reaction. Their thermal and light‐emitting properties were investigated. The single‐ and triple‐layer electroluminescent (EL) devices with configurations of ITO/polymer/Al and ITO/polymer/OXD‐7/Alq₃/Al were fabricated. They exhibited blue emission at 470 nm for OXA‐PPV1 and green emission at 560 nm for OXA‐PPV2. The turn‐on voltages of triple‐layer device were 11 V for OXA‐PPV1 and 8 V for OXA‐PPV2. The triple‐layer EL devices showed much better performance than did the single‐layer devices. The spectra indicated energy transfer occurred from segments of side chain to polymer backbone. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 422–428, 2002     

基于模型参考自适应系统理论的异步电机矢量控制系统研究

采用模型参考自适应系统对系统转速进行估算,实现了异步电机的无速度传感器控制.在一个4kW的三相异步电动机上进行了实验,异步电机结果表明:该系统具有快速的动态响应能力和良好的稳定性.     

楼梯对不同刚度钢筋混凝土框架结构地震反应的影响

为研究楼梯对结构地震反应的影响,利用ETABS设计了2个不含楼梯的钢筋混凝土框架模型和2个包含楼梯的具有不同初始抗侧刚度的钢筋混凝土框架模型,采用振型分解反应谱法对模型进行了弹性地震反应对比计算分析。结果显示：楼梯参与结构整体计算后,结构的抗侧刚度、振动模态、结构基底剪力及梯间框架柱内力分配比例等均明显变化,且影响程度因原框架抗侧刚度大小不同而异。建议当前框架结构设计可以适当提高结构抗侧刚度,以减小楼梯对结构地震反应的改变程度,降低考虑楼梯参与结构整体抗震分析计算的复杂性。     

Oxidation behavior of in-situ Al2O3/TiAl composites at 900℃ in static air

In-situ Al2O3/TiAl composites were successfully synthesized from the starting powders of Ti, Al, TiO2 and Nb2O5. The oxidation behavior of the composites at 900℃ in static air was investigated. The results indicate that the composite samples present a much lower oxidation mass gain. Under long-time intensive oxidation exposure, the formed oxide scale is multi-layer. The formation of the outer TiO2 layer is fine and dense, the internal Al2O3 scale has good adhesiveness with the outer TiO2 scale, and the TiO2+Al2O3 mixed layer forming the protective oxide scale is favorable for the improvement of oxidation resistance. It is believed that the incorporation of Al2O3 particulates into the metal matrix decreases the coefficient of thermal expansion of the substrate, and forms a local three-dimensional network structure that can hold the oxide scale. The formation of the oxide scale with fmer particle size, stronger adherence, less micro-defects and slower growth rate can contribute to the improvement of oxidation resistance. Nb element plays an important role in reducing the internal oxidation action of the materials, restraining the growth of TiO2 crystals andpromoting thc stable formation of the Al 2O3-riched layer,which is benfeicial to improve the oxidation properties.     

常温高效除油清洗剂的制备与应用研究

研制出了一种去油污能力强，可室温使用，综合效果较好的新型高效常温除油清洗剂     

Broadband terahertz spectroscopy of amino acids

Broadband spectra of 20 L-amino acids were obtained at room temperature by terahertz time-domain and infrared spectroscopy. The intensity of terahertz absorption peaks varied with the concentrations of amino acids, and the optimum proportion for each amino acid was obtained. An absorption spectral database of 20 L-amino acids was established from 0 to 6 THz. The associations between terahertz absorption peaks and molecular structures of amino acids were analyzed. The terahertz spectra for L-alanine were compared with the calculated results based on density functional theory using two basis sets that were reliably consistent.     

基于通用智能卡的可信引导方案

为了解决传统的操作系统引导机制存在关键验证信息被绕过的风险和引导数据被篡改的安全隐患,基于可信计算理论,结合带光盘文件系统的智能卡技术,提出了基于通用智能卡的可信引导方案.在不改变智能卡和终端设备的硬件和固件结构的基础上,通过改造智能卡的存储数据和磁盘的引导数据,实现用户身份信息、智能卡和终端设备绑定的安全目标,将可信计算机制从开机加电扩展至应用层,确保操作系统的初始状态可信.通过安全性分析和性能分析,证明终端设备引导的安全性,并且在实际应用中得到了验证.     

某城市地铁振源系统参数影响预测

为了研究正在建设的某城市地铁振源系统,根据地铁拟采用的车型、块下胶垫和扣件等参数,建立车轨垂向耦合振动模型。计算车体、轮对和道床的垂向最大振动加速度,分析车体运行的平稳性及振源的减振效能。结果表明:该城市地铁拟采用的振源系统具有良好的减振效能;A型车车体运行平稳性优于B型车;低速时,参数的选取对振源系统的减振效能没有明显影响,随着车速的增加,减振效能呈降低趋势且不同参数间差距扩大,但当车速大于60 km/h时,减振效能趋于稳定;对减振效能的贡献,扣件最大,块下胶垫的阻尼其次,而A、B型车体和块下胶垫的刚度影响则不明显。     

老年人住区交往实证分析——以黄山市“阳光绿水”小区为例

老龄化问题一直是社会关注的热点。基于老年人交往需求差异化的角度,选取典型案例进行调查和研究,归纳分析了老年人群体住区交往的特征,整理出老年人对交往空间的行为偏好。研究成果对完善住区建设、提高住区品质,具有重要的理论和实践指导意义。