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The piece-wise parabolic method (PPM) is applied to simulations of forced isotropic turbulence with Mach numbers ∼0.1 … 1. The equation of state is dominated by the Fermi pressure of an electron-degenerate fluid. The dissipation in these simulations is of purely numerical origin. For the dimensionless mean rate of dissipation, we find values in agreement with known results from mostly incompressible turbulence simulations. The calculation of a Smagorinsky length corresponding to the rate of numerical dissipation supports the notion of the PPM supplying an implicit subgrid scale model. In the turbulence energy spectra of various flow realisations, we find the so-called bottleneck phenomenon, i.e., a flattening of the spectrum function near the wave number of maximal dissipation. The shape of the bottleneck peak in the compensated spectrum functions is comparable to what is found in turbulence simulations with hyperviscosity. Although the bottleneck effect reduces the range of nearly inertial length scales considerably, we are able to estimate the value of the Kolmogorov constant. For steady turbulence with a balance between energy injection and dissipation, it appears that C ≈ 1.7. However, a smaller value is found in the case of transonic turbulence with a large fraction of compressive components in the driving force. Moreover, we discuss length scales related to the dissipation, in particular, an effective numerical length scale Δeff, which can be regarded as the characteristic smoothing length of the implicit filter associated with the PPM.  相似文献   
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The photoelectrochemical behaviour of natural and synthetic FeS2 (pyrite) has been investigated. In all cases anodic photocurrents have been observed. From photocurrent spectra an energy band gap of 0.9 eV has been determined. The reaction of photogenerated holes produced on d-states of the Fe2+ ions with water leads to the formation of SO 4 2? as a corrosion product. This is contrary to the photoreaction of RuS2 with H2O which yields oxygen, although the crystal as well as the electronic structure of both compounds is equivalent. The differences are discussed in terms of the transition metal chemistry of iron and ruthenium, respectively. Like with other d-band semiconductors a shift of the onset of photocurrents with the redox potential of electron donors has been observed. This study is part of systematic investigations of catalytic requirements for the photoelectrolysis of water.  相似文献   
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The on-line coupling of gel electrophoresis (GE) and inductively coupled plasma-mass spectrometry (ICPMS) is described for the first time. The new method combines the separation power of GE for large biomolecules and the high sensitivity and elemental selectivity of ICPMS. This coupling has been achieved by means of gels housed in glass tubes (length 2.5-20 cm; i.d. 0.5-5 mm). The gel is fixed by glass frits permeable for the analytes. After the electrophoretic separation at voltages up to 500 V, the analytes are transferred to the nebulizer of the ICPMS by an eluent stream, which is separated from the electrode chamber by a membrane. This filter blocks molecules with molecular masses larger than 500 Da. Using double-stranded DNA fragments, commercially available standard solutions were analyzed with on-line GE-ICPMS for the first time by monitoring (31)P(+) with a double-focusing mass spectrometer at a mass resolution of 4000.  相似文献   
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Ohne ZusammenfassungInteressenkonflikt: Der Autor ist als klinisch tätiger Humangenetiker von den Regelungen des GenDG unmittelbar betroffen; gesundheitspolitische Fragen, die unmittelbar Eigeninteressen berühren würden, sind jedoch nicht Gegenstand dieses Textes.
Wolfram HennEmail:
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Die Old White Nile und die Old Blue Nile Bridge waren die ersten beiden Brücken überhaupt, die in Khartoum, der Hauptstadt des Sudan über den Nil führten. Sie wurden von der Britischen Baufirma Dorman Long Ltd. in den Jahren 1908 und 1928 gebaut und erfüllen bis heute in nahezu unveränderter Form ihren Dienst. Sie stellen damit funktionstüchtige, ingenieurtechnische Denkmale dar und zeugen von der außergewöhnlichen Ingenieurleistung, die hier unter schwierigen klimatischen und technologischen Bedingung erbracht wurde. Der folgende Beitrag befasst sich mit der Instandsetzung der Old White Nile Bridge, welche im Zeitraum von 2004 bis 2007 durchgeführt wurde. Die Schüßler‐Plan Ingenieurgesellschaft wurde von der Brückenbauverwaltung der Stadt Khartoum mit verschiedenen Untersuchungen im Zusammenhang mit dem Sanierungskonzept betraut. Der Aufsatz befasst sich neben einem historischen Rückblick mit der Entscheidung, ob ein Auswechseln der 80 Jahre alten, in ihrer Funktion stark eingeschränkten Brückenlager aus statischer Sicht notwendig ist oder diese am Bauwerk belassen werden können. Auch für die Old Blue Nile Bridge ist in den kommenden Jahren eine grundlegende Instandsetzung vorgesehen. Da die Konstruktion vergleichbar ist, können die bei der Old White Nile Bridge gewonnenen Erkenntnisse hierbei einen wertvollen Beitrag leisten. Rehabilitation of old steel bridges over the Nile in Khartoum/Sudan. The Old White Nile Bridge and the Old Blue Nile Bridge were the first bridges ever to cross the Nile at Khartoum – Capital of the Sudan. They were build In 1928 and 1908 by the British Company Dorman Long Ltd. and till today service the traffic in Khartoum in their since then unchanged form. They represent as such a functional technical monument and an attest of the unusual engineering achievement, which was realised under the most extreme climatic and technological conditions. The following report is about the rehabilitation of the Old White Nile Bridge, which was carried out from 2004 till 2007. The Schüßler‐Plan Ingenieurgesellschaft was contracted by the Bridge Department of the State of Khartoum with several analysis related with the rehabilitation concept. The report starts with an historic review of the bridge and continuous with the decision weather it is statically necessary to exchange the nearly 80 year old bearings that are strongly hindered in their function, or weather they could be left unchanged. For the Blue Nile Bridge also, a complete rehabilitation is planned in the near future. Since the two bridge structures are comparable, the knowledge collected at the Old White Nile Bridge could be of great advantage for the Blue Nile rehabilitation.  相似文献   
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