STRONG沸腾床示范装置工业应用

随着原油重质化程度的不断加深,沸腾床渣油加氢技术成为了炼厂提高渣油附加值的重要手段。抚顺石油化工研究院开发的STRONG沸腾床渣油加氢成套技术无需使用传统沸腾床技术中的高温高压循环泵及配套设备,提高了反应体系的稳定性与反应器空间利用率,降低了投资。首套采用STRONG沸腾床技术的工业化装置累计平稳运行8000 h,540℃+单程转化率达到了78%以上。     

复合酶解法提取的天然杜仲胶结构及提胶效率分析

以复合酶解处理的杜仲树叶、皮、籽为原料,石油醚为溶剂,在一定温度下进行提胶,采用偏光显微镜、核磁氢谱、凝胶渗透色谱对杜仲原丝、所提取产物的结构进行了表征,并对产物相对分子质量和提胶效率进行了研究。结果表明,提取出的杜仲胶中几乎不含有顺-1,4-聚异戊二烯,具有较大的相对分子质量,达30万~40万。     

Ge quantum dots light-emitting devices

Si photonics becomes one of the research focuses in the field of photonics.Si-based light-emitting devices are one of the most important devices in this field.In this paper,we review the Si-based light...     

一种具有微纳孔隙结构的二氧化钛多孔膜层光催化系统

采用溶胶-凝胶法配合以离子注入的方式,研制了一种具有纳米和亚微米(零点几个微米)孔隙结构的锐钛矿相二氧化钛光催化膜。首先通过常规的溶胶-凝胶法制得密实的二氧化钛膜层,然后采用具有一定动能的Fe离子轰击膜层,从而在膜层中形成大量的微纳孔隙。这些微纳孔隙明显提高了原膜层的比表面积。光催化降解甲基橙溶液的实验结果表明,无论是在紫外光下还是在可见光下,所得多孔膜层的光催化效果均优于未造孔的二氧化钛膜层。     

K型方圆相贯节点的非线性有限元分析

研究了在只有支管受轴力作用下K型方圆相贯节点非加劲与加劲节点的极限承载力,利用单参数分析的方法,分析了主管宽厚比、加劲环的宽度和厚度等对节点极限承载力的影响,得出了一些有参考价值的结论。     

聚苯胺-聚氯乙烯复合物的研究

作为导电聚合物中的一员,聚苯胺是一类非常有前景的聚合物,而聚氯乙烯是一种重要且应用很广的塑料.概述了聚苯胺与聚氯乙烯的复合方法,包括直接复合、接枝复合、增塑型复合.针对实现聚氯乙烯的可塑性加工重点介绍了增塑型复合,并展望了聚苯胺-聚氯乙烯复合物的应用.     

Kinetic model of single boron particle ignition based upon both oxygen and (BO) n diffusion mechanism

A comprehensive ignition model for single boron particles in an oxygenated environment containing O₂ and H₂O is developed. Microcharacteristics of the boron oxide layer on the surface of boron particles at elevated temperatures are studied. Two typical distributions of species inside the surface oxide layer are detected. One is composed of three layers [B₂O₃, (BO) _n , and B₂O₃], while the other is composed of two layers [(BO) _n and B₂O₃], both according to the order from the internal to external side of the layer. In the model development, two submodels, submodel I and submodel II, are developed with regard to two different observed species distributions in the surface oxide layer. For submodel I, it is assumed that both (BO) _n and O₂ are the governing species diffusing into the liquid oxide layer. For submodel II, only (BO) _n is the governing species. These two submodels are combined into a new bi-directional model consisting of four key kinetic processes: evaporation of the liquid oxide layer, global surface reaction between oxygen from the environment and boron, reaction between the inner boron core and oxygen, and global reaction of boron with water vapor. The ignition time predicted by the model is in good agreement with previous experimental data.     

基础隔震结构扭转减震评价

对不同隔震层偏心率的基础隔震结构进行了分析,提出了扭转减震系数的概念。通过对比水平减震系数与扭转减震系数,得到如下结论:隔震层偏心率在5%以下时,上部结构水平减震系数要大于扭转减震率;当隔震层偏心率大于5%时,上部结构水平减震系数要小于扭转减震系数,此时结构减震效果不能用水平减震系数来表示。     

注意准备对负相容效应的调节

负相容效应是指,在掩蔽启动范式中,当启动项和目标项的反应倾向相同,较启动项和目标项反应倾向不同时,个体的反应时更长.实验通过操纵掩蔽启动范式中启动项前注视点的呈现与否以及注视点呈现的时间长短,考察启动项前的注意准备状态是否会通过影响对阈下刺激的加工来影响负相容效应的大小.研究表明:当启动项以阈下方式呈现时产生了负相容效应,表明个体可以对阈下刺激进行加工；无注视点条件相比有注视点条件产生的负相容效应更强,且在有注视点条件下,注视点呈现时间越长,产生的负相容效应越强.表明注意准备对负相容效应的大小具有调节作用.     

Mechanical and thermo-physical properties of rapidly solidified Al−50Si−Cu(Mg) alloys for thermal management application

Al?high Si alloys were designed by the addition of Cu or Mg alloying elements to improve the mechanical properties. It is found that the addition of 1 wt.% Cu or 1 wt.% Mg as strengthening elements significantly improves the tensile strength by 27.2% and 24.5%, respectively. This phenomenon is attributed to the formation of uniformly dispersed fine particles (Al₂Cu and Mg₂Si secondary phases) in the Al matrix during hot press sintering of the rapidly solidified (gas atomization) powder. The thermal conductivity of the Al?50Si alloys is reduced with the addition of Cu or Mg, by only 7.3% and 6.8%, respectively. Therefore, the strength of the Al?50Si alloys is enhanced while maintaining their excellent thermo-physical properties by adding 1% Cu(Mg).