Dissolution mechanism of solid nickel in liquid zinc saturated with Fe

The dissolution behavior of solid nickel in static liquid zinc saturated with Fe at 723 K was studied. The results show that when immersing solid Ni in liquid Zn saturated with Fe, the intermetallic compound layers consisted of γ and δ phases are formed on nickel substrate, which is the same as that in liquid pure zinc. However, some F2 particles are formed in the liquid near the solid/liquid interface. These Г2 particles can easily heterogeneously nucleate on （particles and grow fast. The dissolution process is governed by diffusion of nickel atom across a concentration boundary layer in liquid Zn saturated with Fe, and is different from a mixed control mechanism of nickel in liquid pure zinc. The participation of Г2 particles makes the dissolution of solid Ni in the liquid accelerated.     

Cu基块状非晶晶化过程的微区变形及力学性能

在玻璃转变温度以下选择350、400、475及600 K进行1 h的等温退火,用纳米压痕仪、扫描电镜等研究Cu基块状非晶晶化过程的力学性能及变形。Cu基块状非晶在纳米压头作用下体现弹-塑性变形方式,载荷—位移曲线和压痕周边多重剪切带的特征证明了塑性变形的存在。350 K退火试样具有较大的压痕硬度HV和弹性模量E值及较小的塑性变形量dn值;400 K退火后,HV和E值显著减小,dn值明显增大;475 K退火后,有少量晶体相析出,但合金以非晶的特性为主,HV和E值继续减小,dn值继续增大;600 K退火后,晶体相进一步长大和析出,其固溶强化和弥散强化使合金的HV和E值有所增加,dn值略有减小。对塑性变形机理进行了初步分析。     

直接金属沉积成形工艺研究

针对直接金属沉积成形(DMD)的工艺特点、设计了一维、二维实验和三维成形实验，研究了成形质量与成形工艺参数的直接关系，并对其进行了优化。检验工艺优化的效果、并对成形零件的性能作了分析。实验证明该工艺可以直接生产高质量的金属零件。     

光固化成型材料中光引发剂对固化性能的影响研究

本研究选用感光度高、引发速率快的自由基型2-异丙基硫杂葸酮(ITX)作为紫外光固化引发剂,合成了可深层固化的自由基光固化树脂体系.研究了引发剂浓度对不同体系固化后的线收缩率、光固化度和体系固化后显微硬度等性能的影响.利用SEM和FTIR表征了聚合体系的固化结构和固化度;结果表明:树脂体系光固化涂膜交联密度高,层间接合均匀;光引发剂浓度为3.5%时,体系的固化度最好,双键转化率约为61.96%-66.35%;光引发剂浓度在3%.3.5%范围内,涂膜硬度达到最佳值;实验合成的树脂体系的线收缩率为2.4%.     

管材外高压成型工艺研究现状及应用

管材液压成型是一种生产中空轴类零件的成型技术,其在汽车和航空领域有广泛的应用前景.本文介绍了一种新的液压成型工艺--管材外高压成型;并综述了外高压成型(EHF)的基本原理、外高压成型优点、研究现状、应用范围、适用材料.     

脉冲换向电刷镀镍基纳米SiO2复合镀层的耐腐蚀性能研究

采用脉冲换向电刷镀方法制备了Ni/n-SiO2复合镀层,应用SEM对镀层表面形貌进行了分析,测试了镀层的孔隙率,以及镀层在海水浸泡条件下的耐腐蚀性能,讨论了镀层的耐腐蚀机理.实验结果表明:与直流工艺条件下的电刷镀镀层相比,脉冲换向电刷镀工艺得到的Ni/n-SiO2复合镀层具有致密精细的表面、较小的孔隙率和较高的耐腐蚀性能.     

乙二醇水热还原法制备纳米银

利用乙二醇在高温下的还原特性,在水热条件下制备了纳米银粒子,并通过透射电镜、X射线衍射、紫外吸收光谱对其结构进行了表征.研究结果表明:所制备的纳米银具有面心立方相的多晶结构,平均粒径在30nm左右,紫外吸收峰的位置在380 nm左右.分散剂和体系中含水量对纳米银的粒径有一定影响.     

Creep behavior and microstructure evolution of directionally solidified superalloy IC 10 at high temperature

The creep behavior of directionally solidified （DS） superalloy IC 10 was investigated under 192 MPa and 218 MPa at 980 ℃. Under the testing conditions, the marked creep characteristic of the superalloy is that the creep curve has a short primary and secondary stage and a long tertiary stage. Another creep characteristic is that the superalloy has excellent plasticity at high temperature. To study the creep behavior, the microstructure was observed by SEM and TEM. Different from other microstructure of Ni-base superalloys, superalloy IC10 forms incompletely rafted γ＇ phase during the creep processes. To understand the creep deformation mechanism of superalloy IC10, the movement of dislocations was analyzed. The results show that the dislocations moving in the γ matrix and climbing over the γ＇ precipitates is the main deformation mechanism under the experimental conditions.     

退火温度对Co-Ag颗粒膜结构及巨磁电阻效应的影响

采用磁控溅射方法在室温衬底上制备了Co30Ag70(原子百分比)颗粒膜。利用X射线衍射谱(XRD)和四探针方法研究了Co30Ag70颗粒膜沉积态及真空退火后的室温结构和室温巨磁电阻效应。结果表明：沉积态颗粒膜织构较明显，巨磁电阻效应呈现各向异性；随着退火温度的升高，Co30Ag70颗粒膜的微结构发生了演变，导致Co30Ag70颗粒膜的巨磁电阻效应呈现先降后升再降的现象，在473K达到最大值，其值约为-5．7％。     

热镀锌钢白锈产生原因分析及预防

通过扫描电镜观察及X射线衍射测试,对热镀锌钢在海洋环境下产生的白锈进行了分析,结果表明,在海洋环境下白锈由ZnCl2.4Zn(OH)2、2ZnCO3.3Zn(OH)2和ZnO组成,腐蚀产物疏松,不能阻碍腐蚀进一步进行。探讨了白锈形成机理,总结了国内外热镀锌标准有关对热镀锌钢白锈的论述,并提出了有关的防护及处理措施。