全文获取类型
收费全文 | 27391篇 |
免费 | 2580篇 |
国内免费 | 1430篇 |
专业分类
电工技术 | 1718篇 |
技术理论 | 6篇 |
综合类 | 1827篇 |
化学工业 | 4946篇 |
金属工艺 | 1597篇 |
机械仪表 | 1691篇 |
建筑科学 | 2137篇 |
矿业工程 | 850篇 |
能源动力 | 735篇 |
轻工业 | 2101篇 |
水利工程 | 509篇 |
石油天然气 | 1598篇 |
武器工业 | 171篇 |
无线电 | 3190篇 |
一般工业技术 | 3382篇 |
冶金工业 | 1372篇 |
原子能技术 | 286篇 |
自动化技术 | 3285篇 |
出版年
2024年 | 151篇 |
2023年 | 496篇 |
2022年 | 877篇 |
2021年 | 1221篇 |
2020年 | 961篇 |
2019年 | 793篇 |
2018年 | 880篇 |
2017年 | 960篇 |
2016年 | 872篇 |
2015年 | 1192篇 |
2014年 | 1442篇 |
2013年 | 1698篇 |
2012年 | 1922篇 |
2011年 | 2139篇 |
2010年 | 1561篇 |
2009年 | 1519篇 |
2008年 | 1532篇 |
2007年 | 1498篇 |
2006年 | 1449篇 |
2005年 | 1189篇 |
2004年 | 808篇 |
2003年 | 736篇 |
2002年 | 780篇 |
2001年 | 621篇 |
2000年 | 605篇 |
1999年 | 646篇 |
1998年 | 510篇 |
1997年 | 415篇 |
1996年 | 408篇 |
1995年 | 333篇 |
1994年 | 313篇 |
1993年 | 204篇 |
1992年 | 161篇 |
1991年 | 123篇 |
1990年 | 93篇 |
1989年 | 71篇 |
1988年 | 53篇 |
1987年 | 38篇 |
1986年 | 30篇 |
1985年 | 13篇 |
1984年 | 19篇 |
1983年 | 12篇 |
1982年 | 18篇 |
1981年 | 8篇 |
1980年 | 9篇 |
1978年 | 5篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 2篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
131.
报道了由邻羟基苯乙酮合成中间体二甲氨基-1-(2-羟基苯基)-1-丙烯酮,再与酸酐反应得3-酰化苯并吡喃-4-酮衍生物经元素分析,核磁共振谱等证实其分子结构。 相似文献
132.
强酸性阳离子交换树脂催化合成氯乙酸异辛酯的研究 总被引:6,自引:0,他引:6
对采用732强酸性苯乙烯系阳离子交换树脂作催化剂合成氯乙酸异辛酯进行了实验研究,提出了适宜的反应条件。实验结果表明,该法酯化率高、过程简便、产物颜色浅,优于浓硫酸作催化剂。 相似文献
133.
介绍了通径为20"(1"=25.4mm)的大口径中压球阀阀体、新型C形金属密封环组件等的结构设计;在阀座与球体之间采用整体碟形弹簧和新型阀座密封填料,以保证高压密封,提高使用寿命;阀芯采用空心球体结构和分段冲压成形加工工艺,有效地保证了球体的加工精度和质量,降低了生产成本;在结构设计中,充分考虑了球阀的密封、防火、启闭传动及制造工艺的要求;对其中结构复杂的球阀阀体和空心球形阀芯进行了强度计算和ANSYS应力、应变模拟分析计算,二者计算结果一致,并认为阀体的厚度由其大开孔处局部应力的整体补强确定。 相似文献
134.
135.
136.
LLDPE-g-GMA对PET/LLDPE性能的影响 总被引:1,自引:2,他引:1
自制了线性低密度聚乙烯与甲基丙烯酸缩水甘油酯接枝物(LLDPE-g-GMA),研究了LLDPE-g-GMA对聚对苯二甲酸乙二酯/线性低密度聚乙烯(PET/LLDPE)合金体系力学性能、结晶行为及玻璃化转变活化能的影响。结果表明,LLDPE-g-GMA有效地改善了PET/LLDPE的拉伸性能、弯曲性能及冲击性能;同时LLDPE-g-GMA的加入提高了PET的结晶速率,两者有较好的相容性;动态力学试验结果也证明了LLDPE-g-GMA与PET有较好的相容性。LLDPE-g-GMA可以作为PET/LLDPE体系的反应性增容剂。 相似文献
137.
多孔陶瓷材料的制备技术及应用 总被引:6,自引:0,他引:6
本文综述了近年来多孔陶瓷材料制备技术的研究现状及应用,多孔陶瓷性能特殊,应用广泛,并为生物医学等相关行业带来进步。 相似文献
138.
Hai‐Xia Yang Yan‐Feng Li Jin‐Gang Liu Shi‐Yong Yang Da‐Xue Yin Lincheng Zhou Lin Fan 《应用聚合物科学杂志》2004,91(6):3981-3990
A series of new polymerized monomer reactants (PMR) matrix resins of poly(pyrrolone‐benzimidazole)s containing a pyridine unit (PPBP) were synthesized by polycondensation of monoethyl ester of cis‐5‐norbornene‐endo‐2,3‐dicarboxylic acid, 2,6‐diphenyl ester pyridinedicarboxylic acid or 3,5‐diphenyl ester pyridinedicarboxylic acid, and diethyl ester of 4,4′‐oxydiphthalic acid with 3,3′‐diaminobenzidine in a mixing solution of anhydrous ethyl alcohol and N‐methylpyrrolidone under given temperature and pressure conditions. The resulting resin solutions showed good solubility in polar organic solvents and stability at room temperature. The corresponding PPBP matrix resin, molded powder, and molded plate were prepared by undergoing amidation, imidization, cyclization, and crosslinking reactions when the reaction temperature was increased from 80 to 350°C, successively; the crosslinking structure was formed by the reverse Diels–Alder reaction at 270–290°C under 50 MPa pressure (2.5–3.5 MPa displayed by the pressure meter). The chemical reactions and properties of the resulting PPBP were studied by means of FTIR, TGA, and DMA methods, and the results indicated that the kinds of PPBP materials retain excellent thermal stability and processability; when the initial decomposition temperature was above 620°C the Tg was at 413.5°C for 3,5‐PPBP‐20 molded plate. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 3981–3990, 2004 相似文献
139.
140.
In this paper, we present the systematic development of mechanically enhanced interpenetrating polymer network (IPN) hydrogels with Young's moduli rivaling those of natural load-bearing tissues. The IPNs were formed by synthesis of a crosslinked poly(acrylic acid) (PAA) network within an end-linked poly(ethylene glycol) (PEG) macromonomer network. The strain-hardening behavior of these PEG/PAA IPNs was studied through uniaxial tensile testing and swelling measurements. The interaction between the independently crosslinked networks within the IPN was varied by (1) changing the molecular weight of the PEG macromonomer, (2) controlling the degree of PAA ionization by changing pH, and (3) increasing the polymer content in the PAA network. Young's moduli and the maximum stress-at-break of the swollen hydrogels were normalized on the basis of their polymer content. Strain hardening in the IPNs exhibited a strong dependence on the molecular weight of the first network macromonomer, the pH of the swelling buffer, as well as the polymer content of the second network. The results indicate that the mechanical enhancement of these IPNs is mediated by the strain-induced intensity of physical entanglements between the two networks. The strain can be applied either by mechanical deformation or by changing the pH to modulate the swelling of the PAA network. At pHs below the pKa of PAA (4.7), entanglements between PEG and PAA are reinforced by interpolymer hydrogen bonds, yielding IPNs with high fracture strength. At pHs above 4.7, a “pre-stressed” IPN with dramatically enhanced modulus is formed due to ionization-induced swelling of the PAA network within a static PEG network. The modulus enhancement ranged from two-fold to over 10-fold depending on the synthesis conditions used. Variation of the network parameters and swelling conditions enabled “tuning” of the hydrogels' physical properties, yielding materials with water content between 58% and 90% water, tensile strength between 2.0 MPa and 12.0 MPa, and initial Young's modulus between 1.0 MPa and 19.0 MPa. Under physiologic pH and salt concentration, these materials attain “biomimetic” values for initial Young's modulus in addition to high tensile strength and water content. As such, they are promising new candidates for artificial replacement of natural tissues such as the cornea, cartilage, and other load-bearing structures. 相似文献