准噶尔盆地阜康凹陷芦草沟组烃源岩地球化学特征与生烃潜力研究

准噶尔盆地阜康凹陷作为盆地内最大的富烃凹陷,其烃源岩地球化学特征、沉积环境和生烃母质等研究不足,限制了对该区探明资源量较低问题的理解。基于阜康凹陷东斜坡新钻揭的烃源岩样品实验分析结果,对阜康凹陷芦草沟组源岩进行了地质地球化学分析研究。阜康凹陷芦草沟组烃源岩总体属于中—很好质量的烃源岩,有机质类型为Ⅱ—Ⅲ型,主体处于低熟—成熟演化阶段;生物标志物特征显示,芦草沟组烃源岩的有机质为陆源高等植物和水生菌藻类的混合,可能具有类杜氏藻的绿藻贡献,总体沉积于贫氧—次富氧、淡水—半咸水的间歇性分层水体环境中,泥岩沉积特征明显。阜康凹陷芦草沟组烃源岩平面上地球化学特征变化较大,阜中凹槽和阜北凹槽显示出更大的生烃潜力。     

Zr和V对可加工RE-Co永磁合金组织和性能的影响

研究了微量合金元素 Zr 和 V 对可加工 RE-Co 永磁合金组织和性能的影响。实验发现,联合添加微量 Zr 和 V 可使磁体在保持高 Br 的前提下具有较高的 H_(CB)。获得了(BH)_(max)(?)99kJ/m~3且可进行车削、钻孔和用内圆切割机切成厚为0.2mm 薄片的磁体。     

Microwave-Assisted Synthesis of Highly Active Single-Atom Fe/N/C Catalysts for High-Performance Aqueous and Flexible All-Solid-State Zn-Air Batteries

The development of low-cost single-atom electrocatalysts for oxygen reduction reaction (ORR) is highly desired but remains a grand challenge. Superior to the conventional techniques, a microwave-assisted strategy is reported for rapid production of high-quality Fe/N/C single-atom catalysts (SACs) with profoundly enhanced reaction rate and remarkably reduced energy consumption. The as-synthesized catalysts exhibit an excellent ORR performance with a positive half-wave potential up to 0.90 V, a high turnover frequency of 0.76 s⁻¹, as well as a satisfied stability with a lost half-wave potential of just 27 mV over 9000 cycles (much better than that of Pt/C with 107 mV lost) and good methanol resistance. The open-circuit voltages of as-constructed aqueous and flexible all-solid-state Zn-air batteries (ZABs) are 1.56 and 1.52 V, respectively, higher than those of 20% Pt/C-based ones (i.e., 1.43 and 1.38 V, respectively). Impressively, they afford a peak power density of 235 mW cm⁻², which exceeds that of Pt/C (i.e., 186 mW cm⁻²), and is comparable to the best ones of Fe/N/C-based ZABs ever reported.     

Proton conducting electrolyte membranes derived from novel branched sulfonated poly(ether ether ketone)s with benzimidazole sulfonic acid pendants via thiol-ene click chemistry

A series of novel branched sulfonated poly(ether ether ketone)s containing propenyl groups have been synthesized using a nucleophilic polycondensation reaction. Subsequently, a thiol-ene click chemistry reaction between propenyl and thiol groups results in a new series of copolymers containing benzimidazole sulfonic acid groups. The expected structures of the copolymers are confirmed by ¹H NMR and Fourier transform infrared spectroscopy. The introduction of benzimidazole sulfonic acid groups into the copolymer improves proton conductivity obviously. Compared with the linear sulfonated poly(ether ether ketone)s with the same sulfonation degree (DS), the BSPEEK-BIS membranes show lower water uptake and methanol permeability. The branching structure and the interaction between sulfonic acid and benzimidazole groups make the contribution to the improvement of the membrane's properties. Therefore, the high proton conduction, low methanol permeation, and low water uptake property of the as-prepared membranes are of significant interest for DMFCs.     

PLC在翻引钢机械手控制中的应用

介绍了翻引钢机械手PLC控制系统的结构、功能、典型程序和特点．