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991.
Some thermomechanical properties such as expansion, transition temperature and high-temperature viscosity of phosphate glasses with different P2O5 and BaO compositions have been measured. Absorption and fluorescence spectra of the phosphate glasses with different Er3+ doping have also been measured. The Er3+ doping concentration with respect to the maximal fluorescence intensity is 0.75 mol %. The attenuation of the fibre at a wavelength of 1.53 m is 12.8 db m–1. Upconversion of 1.064 m NdYAG laser pulses into intense green 547 and 667 nm light in the 0.75 mol % Er3+-doped phosphate glass fibre has been achieved. The output power of the two fluorescence signals of green 547 nm and red 667 nm are 178 and 42 W, respectively, with an upconversion efficiency of 1.78×10–2% and 4.2×10–3% respectively. 相似文献
992.
面对海量的大坝安全监测数据,快速合理地确定大坝变形预测模型的变量因子能够有效提高模型预测的效率和精度。为此,本文提出一种基于最小绝对值收缩和选择算子(least absolute shrinkage and selection operation,LASSO)变量选择和长短期记忆(long short-term memory,LSTM)网络的大坝变形预测模型。首先,通过大坝变形机理分析确定影响大坝变形的相关影响因子集。然后,通过LASSO算法剔除不显著的因子,筛选出最优影响因子作为模型输入变量,并利用LSTM网络建立大坝变形预测模型。最后,以皂市水利枢纽工程的碾压混凝土重力坝为例,对本文方法进行了验证和讨论。结果表明,本文方法具有较高的预测精度,其平均绝对误差(MAE)、均方误差(MSE)与均方根误差(RMSE)均相对较小;与常规预测模型相比,基于LASSO算法的变量选择使模型建立过程更加简单高效,有利于海量监测数据的处理分析。 相似文献
993.
994.
为了能够在复杂环境下实现风速风向的高精度和高稳定性测量,在基于声学共振原理的风传感器系统的基础上,采用闭环控制扫描技术改进了系统的性能指标。采用声学共振的方式,同时对换能器产生的信号进行频率调制和强度调制,实现对超声换能器的线型扫描。频率调制解决了在不同压力、温度等环境因素影响下导致的共振频移的问题,强度调制解决了换能器性能随时间衰减问题,极大地提高了信噪比。实验结果表明,采用闭环控制的方法可以准确测量风速风向。风速测量范围0~50 m/s,风速测量精度为±0.5 m/s(≤15m/s)/±5%(>15 m/s且<35 m/s)/±9%(>35 m/s)。改进后的系统在复杂环境下受环境变化影响小、精度高、稳定性好、抗干扰能力强。 相似文献
995.
996.
Duan Bin Yanyan Du Beibei Yang Hongbin Lu Yao Liu Yongyao Xia 《Advanced functional materials》2023,33(8):2211765
Aqueous rechargeable zinc batteries (ARZBs) are recently prevailing devices that utilize the abundant Zn resources and the merits of aqueous electrolytes to become a competitive alternative for large-scale energy storage. Benefiting from the unique inductive effect and flexible structure, the past five years have experienced a diversiform of phosphate-based polyanion materials that are used as cathodes in ARZBs. In this review, the most recent advances in the Zn2+ storage mechanisms and electrolyte optimization of the phosphate-based cathodes of ARZBs, which mainly focus on vanadium/iron-based phosphates and their derivatives are presented. Furthermore, in addition to significant progress on polyanion phosphate-based cathode materials, the design strategies both for electrode materials and compatible electrolytes are also elaborated to improve the energy density and extend the cycling life of aqueous Zn/polyanion batteries. 相似文献
997.
Ying-Xia Du Qiao Yang Wang-Ting Lu Qing-Yu Guan Fei-Fei Cao Geng Zhang 《Advanced functional materials》2023,33(27):2300895
Single metal atom isolated in nitrogen-doped carbon materials (M N C) are effective electrocatalysts for oxygen reduction reaction (ORR), which produces H2O2 or H2O via 2-electron or 4-electron process. However, most of M N C catalysts can only present high selectivity for one product, and the selectivity is usually regulated by complicated structure design. Herein, a carbon black-supported Co N C catalyst (CB@Co N C) is synthesized. Tunable 2-electron/4-electron behavior is realized on CB@Co-N-C by utilizing its H2O2 yield dependence on electrolyte pH and catalyst loading. In acidic media with low catalyst loading, CB@Co N C presents excellent mass activity and high selectivity for H2O2 production. In flow cell with gas diffusion electrode, a H2O2 production rate of 5.04 mol h−1 g−1 is achieved by CB@Co N C on electrolyte circulation mode, and a long-term H2O2 production of 200 h is demonstrated on electrolyte non-circulation mode. Meanwhile, CB@Co N C exhibits a dominant 4-electron ORR pathway with high activity and durability in pH neutral media with high catalyst loading. The microbial fuel cell using CB@Co N C as the cathode catalyst shows a peak power density close to that of benchmark Pt/C catalyst. 相似文献
998.
Chuanming Tian Bin Li Yichuan Rui Hao Xiong Yu Zhao Xuefei Han Xinliang Zhou Yu Qiu Wei An Kerui Li Chengyi Hou Yaogang Li Hongzhi Wang Qinghong Zhang 《Advanced functional materials》2023,33(41):2302270
Despite the outstanding power conversion efficiency (PCE) of perovskite solar cells (PSCs) achieved over the years, unsatisfactory stability and lead toxicity remain obstacles that limit their competitiveness and large-scale practical deployment. In this study, in situ polymerizing internal encapsulation (IPIE) is developed as a holistic approach to overcome these challenges. The uniform polymer internal package layer constructed by thermally triggered cross-linkable monomers not only solidifies the ionic perovskite crystalline by strong electron-withdrawing/donating chemical sites, but also acts as a water penetration and ion migration barrier to prolong shelf life under harsh environments. The optimized MAPbI3 and FAPbI3 devices with IPIE treatment yield impressive efficiencies of 22.29% and 24.12%, respectively, accompanied by remarkably enhanced environmental and mechanical stabilities. In addition, toxic water-soluble lead leakage is minimized by the synergetic effect of the physical encapsulation wall and chemical chelation conferred by the IPIE. Hence, this strategy provides a feasible route for preparing efficient, stable, and eco-friendly PSCs. 相似文献
999.
Chunya Du Hui Liu Zhuang Cheng Shaoqin Zhang Zexing Qu Dezhi Yang Xianfeng Qiao Zujin Zhao Ping Lu 《Advanced functional materials》2023,33(45):2304854
The pursuit for efficient deep blue material is an ever-increasing issue in organic optoelectronics field. It is a long-standing challenge to achieve high external quantum efficiency (EQE) exceed 10% at brightness of 1000 cd m−2 with a Commission International de L'Eclairage (CIEy) <0.08 in non-doped organic light-emitting diodes (OLEDs). Herein, this study reports a deep blue luminogen, PPITPh, by bonding phenanthro[9,10-d]imidazole moiety with m-terphenyl group via benzene bridge. The non-doped OLED based on PPITPh exhibits an exceptionally high EQE of 11.83% with a CIE coordinate of (0.15, 0.07). The EQE still maintains 10.17% at the brightness of 1000 cd m−2, and even at a brightness as high as 10000 cd m−2, an EQE of 7.5% is still remained, representing the record-high result among non-doped deep-blue OLEDs at 1000 cd m−2. The unprecedented device performance is attributed to the reversed intersystem crossing process through hot exciton mechanism. Besides, the maximum EQE of orange phosphorescent OLED with PPITPh as host is 32.02%, and remains 31.17% at the brightness of 1000 cd m−2. Such minimal efficiency roll-off demonstrates that PPITPh is also an excellent phosphorescent host material. The result offers a new design strategy for the enrichment of high-efficiency deep blue luminogen. 相似文献
1000.
Yanwei Zhu Wenfang Deng Yueming Tan Jianqiao Shi Jingcheng Wu Wenbo Lu Jianfeng Jia Shuangyin Wang Yuqin Zou 《Advanced functional materials》2023,33(45):2304985
Photocatalytic selective oxidation of 5-hydroxymethylfurfural (HMF) coupled H2 production offers a promising approach to producing valuable chemicals. Herein, an efficient in situ topological transformation tactic is developed for producing porous O-doped ZnIn2S4 nanosheets for HMF oxidation cooperative with H2 evolution. Aberration-corrected high-angle annular dark-field scanning TEM images show that the hierarchical porous O-ZIS-120 possesses abundant atomic scale edge steps and lattice defects, which is beneficial for electron accumulation and molecule adsorption. The optimal catalyst (O-ZIS-120) exhibits remarkable performance with 2,5-diformylfuran (DFF) yields of 1624 µmol h−1 g−1 and the selectivity of >97%, simultaneously with the H2 evolution rate of 1522 µmol h−1 g−1. Mechanistic investigations through theoretical calculations show that O in the O-ZIS-120 lattice can reduce the oxidation energy barrier of hydroxyl groups of HMF. In situ attenuated total reflection surface-enhanced infrared absorption spectroscopy (ATR-SEIRAS) results reveal that DFF* (C4H2(CHO)2O*) intermediate has a weak interaction with O-ZIS-120 and desorb as the final product. This study elucidates the topotactic structural transitions of 2D materials simultaneously with electronic structure modulation for efficient photocatalytic DFF production. 相似文献