STRUCTURE REPRESENTATION OF THE SPECIFIC FRACTIONS FROM PINGSHUO COAL

Basic data of four fractions, PM₁, PM₆, PM₇and PM₈, derived from Pingshuo bituminous coal were obtained by ultimate analyses, mean molecular weight measure, GC/MS, ¹³C-NM R, ¹H-NM R and FTIR technigues. A method of calculating the average molecular parameters of the fractions is introduced. Based on the calculated parameters, the molecular structure models of the fractions of PM₆, PM;and PM₈are constructed. Significant structural information about the saturated hydrocarbon and aromatic hydrocarbon with heteroatom groups is given also.     

倒虹吸管管径计算的迭代法

本文先将倒虹吸管的管径计算公式整理成等式左边只含管径的一次方法，右边含有管径高阶非线性的迭代函数，然后证明该迭代函数收敛，最后利用数学迭代原理给迭代函数右边赋初值，计算左边的管径。继续迭代下去，就能求出倒虹吸管的管径。     

小剂量辐照小鼠胸腺细胞膜流动性的变化

报道了以茈为荧光探针,探讨小剂量~(60)Co γ射线照射后小鼠胸腺细胞膜流动性的变化。结果表明,剂量在0.25-1.00Gy范围,胸腺细胞膜流动性降低与剂量之间呈明显线性关系。从0.50Gy起,辐照组荧光强度比值I_1/I_2与I_3/I_2与对照组的比较存有显著差异(P<0.05)。提示淋巴细胞膜流动性的变化可作为小剂量辐照早期效应的敏感指标。     

An observer-based robust adaptive controller for permanent magnet synchronous motor drive with initial rotor angle uncertainty

An observer-based robust adaptive nonlinear position and speed tracking controller is developed for a permanent magnet synchronous motor with initial rotor angle uncertainty. The unknown initial rotor position is treated as a constant motor parameter in the development of the controller. An incremental encoder, which provides relative position variation of the rotor, is used along with stator current signals to achieve stable control. However, the controller does not require the knowledge of motor parameters and it only assumes friction, external disturbances, and model uncertainties are bounded. By using state observers, the measurement of acceleration and load torque, which is required usually in the nonlinear controller design with high tracking performance, is avoided. The stability of the control system and tracking convergence are guaranteed using Lyapunov theory. Finally, the stability and efficacy of the proposed drive system are verified by experimental results.     

Growth and morphology of nanometer LiMn2O4 powder

The growth of Li_1+xMn₂O₄ via detonation reaction was investigated with respect to the presence of an energetic precursor, such as the metallic nitrate and the degree of confinement of the explosive charge. The detonation products were characterized by scanning electron microscopy. Powder X-ray diffraction and transmission electron microscopy were used to characterize the products. Li_1+xMn₂O₄ with 1-2 μm spherical morphology and more uniform secondary particles, but with smaller primary particles of diameters from 20 to 60 nm and a variety of morphologies were found. The oxides produced by this cheap method affirmed the validity of detonation synthesis of nano-size powders.     

沾化凹陷南斜坡油气运移条件及运移特征研究

油气运移的条件和油气运移的特征决定了油气藏的形成与分布。沾化凹陷南斜坡不整合面、断层以及各层系储集砂体的空间配置构成复杂的立体网络通道，决定了油气的运移，控制了油气分布。以断层为垂向运移通道的油气藏常在断层带附近多层叠置；以连通砂体为主要运移通道的油气藏常形成于距烃源层较近或相邻的层位；以不整合面作为运移通道往往可使油气长距离运移形成各种地层油气藏。沾化凹陷南斜坡的油气藏都是油气经过两种或多种输导层阶梯式运移而形成的。砂体、断层和不整合面组成的输导系统的末端和边缘是油气运移的重要指向区。     

Novel blood-compatible waterborne polyurethane using chitosan as an extender

A series of novel block polymers of polyurethane (PU) and chitosan have been prepared in two steps. The first step is the preparation of PU prepolymer, obtained from polytetramethylene oxide glycol (PTMO, M_n = 1000), isophrone diisocyanate (IPDI), and 2,2′-dimethylol propionic acid (DMPA), followed by ionizing PU prepolymer with triethylamine (TEA). The second step involves PU chain-extended by water-soluble chitosan of low molecular weight (M_n = 5000) by self-emulsion polymerization method. The sizes of the latex particles, morphology, and copolymer architecture have been characterized by dynamic light scattering (DLS), general tensile test, infrared spectroscopy (IR), surface contact angle measurement, and transmission electron microscopy (TEM). Furthermore, it shows that the addition of chitosan remarkably increases anticoagulative property of PU elastomers confirmed by the recalcification time. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Synthesis and properties of novel amphiphilic sulfated ionomers by the ring‐opening reaction of an epoxidized styrene–butadiene–styrene triblock copolymer

A method for the synthesis of novel sulfated ionomer of styrene–butadiene–styrene triblock copolymer (SBS) was developed. SBS was first epoxidized by performic acid in the presence of a phase‐transfer catalyst; this was followed by a ring‐opening reaction with an aqueous solution of alkali salt of bisulfate. The optimum conditions for the ring‐opening reaction of the epoxidized SBS with an aqueous solution of KHSO₄ were studied. During the ring‐opening reaction, both phase‐transfer catalyst and ring‐opening catalyst were necessary to enhance the conversion of epoxy groups to ionic groups. The products were characterized with Fourier transform infrared spectrophotometry and transmission electron microscopy (TEM). After the potassium ions of the ionomer were substituted with lead ions, the lead sulfated ionomer exhibited dark spots under TEM. Some properties of the sulfated ionomer were studied. With increasing ionic groups or ionic potential of the cations, the water absorbency and emulsifying volume of the ionomer and the intrinsic viscosity of the ionomer solution increased, whereas the oil absorbency decreased. The sulfated ionomer possessed excellent emulsifying properties compared with the sulfonated SBS ionomer. The sodium sulfated ionomers in the presence of 10% zinc stearate showed better mechanical properties than the original SBS. When the ionomer was blended with crystalline polypropylene, a synergistic effect occurred with respect to the tensile strength. The ionomer behaved as a compatibilizer for blending equal amounts of SBS and oil‐resistant chlorohydrin rubber. In the presence of 3% ionomer, the blend exhibited much better mechanical properties and solvent resistance than the blend without the ionomer. SEM photographs indicated improved compatibility between the two components of the blend in the presence of the ionomer. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

导向剂加入方式对Y型沸石合成的影响

以煤系高岭土为原料,采用液态补硅手段调节体系SiO2/Al2O3、导向剂两步加入法合成了Y型沸石.考察了导向剂不同加入方式对Y型沸石合成的影响.采用合理的导向剂两步加入法,特别是通过控制导向剂第二步加入的时间,可明显缩短Y型沸石的晶化时间,并有效地减少P型沸石的生成.