Fluorescence enhancement and cofluorescence in complexes of terbium(Ⅲ) with trimellitic acid

The fluorescence of terbium (Ⅲ) was enhanced by about three orders of magnitude in the presence of trimellitic acid (benzene-l, 2, 4-tricarboxylic acid (TLA)) in aqueous solution at pH 6. The fluorescence intensity could be greatly increased when the system of Tb3+-TLA was treated with La3+ (or Gd3+) and TritonX- 100. The addition of La3+ (or Gd3+) enhances the fluorescence of the system by about two orders of magnitude due to cofluorescence, and the TritonX-100 micellar medium plays an important role for stabilization of the system. Both the intermolecular energy transfer mode and intramolecular energy transfer mode are responsible for the mechanism of fluorescence enhancement. In the optimum conditions, the fluorescence intensity is a linear function of Tb3+ concentration in the range of 7.8 × 10-9-3.6 × 10-6 mol/L for the system Tb3+-La3+-TLA and 1.0 × 10-8-4.7 × 10-6 mol/L for the system Tb3+-Gd3+-TLA, and the limits of detection are 4.6 ×10-10 mol/L and 6.0 × 10-10 mol/L, respectively.     

计算机遗传病毒运作模式剖析

遗传病毒是指通过病毒自身的学习机制,反复地经选择、交叉、变异等步骤,进化出的能够适应环境的新病毒.此种病毒种类,较为复杂,且具有较高的变异能力,因此防杀也较为困难.该病毒很难依照固定特征或行为模式来侦测及清除.此类病毒的进化方式,不需创造出完整的病毒,只需是可用的新元件,再通过自身进化出新一代病毒.研究的目的,在于提出遗传病毒的进化模型,供研究人员思考对其的防治.     

一种新的IPsec VPN的实现方式研究

从VPN设备的灵活性、适应性及扩展性等方面着手,提出并设计了不同网络层次上VPN的实现方案,并在比较分析的基础上,采用一体化的设计方法,给出了一种同时支持路由和网桥两种模式的Ipsec VPN的实现方案.     

适用于Ad Hoc网络的混合认证机制

分析了Ad Hoc网络的特点及其对身份认证机制的安全需求,采用椭圆曲线和对称密钥两种认证体制并结合自证明公钥原理,提出了一种适用于Ad Hoc网络的混合认证机制.该机制中门限方案增强了系统的健壮性,基于自证明公钥的双向认证协议确保了交互节点身份的真实性,刷新认证协议保证了节点身份的持续可信,分布式自证明公钥撤销方案可将恶意节点快速从系统中分离出去.分析结果表明,该认证机制具有较高的安全性,同时对系统存储空间、网络通信量和计算开销的要求都很少,有着较高的效率.     

Feed-direction ultrasonic vibration−assisted milling surface texture formation

The formation mechanism of surface texture for feed-direction ultrasonic vibration?assisted milling (UVAM) was investigated in this study by establishing a kinematic model and a pressing model of UVAM. The kinematic model showed that the cutter tip, which was supposed to be totally sharp, produced closed scratches by crossed trajectories. The variation trends of the interval for closed textures were of sine function. A comparative experiment was carried out by UVAM and conventional milling. A dividing line close to the X coordinate divides the surface feature into two parts. The pressing model showed that the tool minor cutting edge left clear traces with certain width because of the tool minor cutting edge angle. Scratches by tool minor cutting edge were intermittent and regularly varied when feed-direction vibration was introduced. All the surface feature changes are in the radial direction and the trajectory intersections shall always be the scratch grooves or ridges. The ratio between ultrasonic vibration frequency and spindle speed, tool radius, and the located cutter rotation angle affected the changing rule of scratches by tool minor cutting edge. The analytical models and the experimental results proved to each other reasonable.     

无模板剂水热合成Bi12O17Cl2纳米带及其阻燃性能研究

以β-Bi2O3为原料,采用无模板剂水热法制备了Bi_(12)O_(17)Cl_2纳米带,利用X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)和高分辨透射电镜(HRTEM)对其形貌和结构进行了表征并作为阻燃剂添加到聚氯乙烯(PVC)中评价其阻燃性能。结果表明,适宜的Bi/Cl物质的量比对水热合成Bi_(12)O_(17)Cl_2纳米带及其化学计量比影响显著,当Bi/Cl物质的量比为1∶2.5时,可得到分散性好、形貌均匀的Bi_(12)O_(17)Cl_2纳米带;改变Bi/Cl物质的量比,纳米带中Bi/Cl化学计量比从6∶1变成2.4∶1。初步探讨了Bi_(12)O_(17)Cl_2纳米带可能的生长机理,在水热反应过程中,Bi 3+与Cl-发生络合反应形成BiCln3-n络合物,从而合成Bi_(12)O_(17)Cl_2纳米带。     

电力设施保护存在问题分析

对电力设施保护存在的问题进行了调查,从内、外部因素对电力设施保护工作存在的问题进行分析.根据分析结果,进行针对性研究并提出完善法律法规、加强运维管理、投入物防技防、加大宣传、联合协同的五个解决对策,最大限度地避免电力设施被破坏,为电网安全运行提供可靠的设备保障.     

Influence of Sn and Mo on corrosion behavior of ferrite-pearlite steel in the simulated bottom plate environment of cargo oil tank

This work investigated the influence of Sn and Mo on corrosion behavior of ferrite-pearlite steel in the simulated bottom plate environment of cargo oil tank. The results indicate that the corrosion rate of three ferrite-pearlite steels increased with extending the immersion time due to the continuous accumulation of the residual Fe_3C. However, the addition of Sn or the combined addition of Sn and Mo could reduce the corrosion rate of Sn containing steel and Sn-Mo containing steel to 37.5% and 20% of that of carbon steel, respectively. Moreover, the cathodic reaction of Sn containing steel and Sn-Mo containing steel was always controlled by the charge transfer step during the whole immersion test, while that of carbon steel was gradually transformed into the diffusion-controlled process. These results were mainly related with the deposition of metallic Sn and Mo on the steel surface. The metallic Sn and Mo with uniform distribution restrained the galvanic effect through suppressing both the anodic dissolution of ferrite and cathodic hydrogen evolution reaction on the residual Fe_3C.     

图像抽象化的实时增强型绘制

现有的图像抽象化绘制算法主要采用基于图像分割或边缘保持的平滑滤波技术,导致所生成的抽象化图像经常存在明暗对比度较低、画质昏暗模糊、画面色彩表现力不强等问题,为此提出一种增强对比度的图像抽象化绘制算法.首先利用结构张量平滑技术生成光滑连续、显著特征保持的特征流场,然后基于该流场对图像进行沿边缘切向流方向的自适应平滑和沿梯度方向的对比度增强处理,最后使用改进的基于流场的双边滤波或者Kuwahara滤波算法实现图像抽象化的实时绘制.实验结果表明,该算法可显著改善已有抽象化方法的绘制质量,抽象化图像的边界特征明显增强,画质更清晰、层次感更分明.     

Reprocessing the MODIS Leaf Area Index products for land surface and climate modelling

Land surface and climate modelling requires continuous and consistent Leaf Area Index (LAI). High spatiotemporal resolution and long-time record data are more in demand nowadays and will continue to be in the future. MODIS LAI products meet these requirements to some degree. However, due to the presence of cloud and seasonal snow cover, the instrument problems and the uncertainties of retrieval algorithm, the current MODIS LAI products are spatially and temporally discontinuous and inconsistent, which limits their application in land surface and climate modelling. To improve the MODIS LAI products on a global scale, we considered the characteristics of the MODIS LAI data and made the best use of quality control (QC) information, and developed an integrated two-step method to derive the improved MODIS LAI products effectively and efficiently on a global scale. First, we used the modified temporal spatial filter (mTSF) method taking advantage of background values and QC information at each pixel to do a simple data assimilation for relatively low quality data. Then we applied the post processing-TIMESAT (A software package to analyze time-series of satellite sensor data) Savitzky-Golay (SG) filter to get the final result. We implemented the method to 10 years of the MODIS Collection 5 LAI data. In comparison with the LAI reference maps and the MODIS LAI data, our results showed that the improved MODIS LAI data are closer to the LAI reference maps in magnitude and also more continuous and consistent in both time-series and spatial domains. In addition, simple statistics were used to evaluate the differences between the MODIS LAI and the improved MODIS LAI.